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  • Polymer and Materials Science  (23)
  • Analytical Chemistry and Spectroscopy  (7)
  • Astrophysics
  • 1985-1989  (30)
  • 1
    ISSN: 0323-7648
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: Meßergebnisse zur Adsorption von Tannin auf hydrophiler Baumwolle bei unterschiedlichen Temperaturen werden vorgestellt. Die Thermodynamik des Adsorptionsgleichgewichtes des Tannins wird untersucht. Mit zunehmender Temperatur nimmt die Menge des adsorbierten Tannins ab. Das Adsorptionsgleichgewicht des Tannins läßt sich durch eine Adsorptionsisotherme nach Freundlich beschreiben. Weiterhin wurde das Strömungspotential des Systems Cellulose/Tannin/Rhodamin-B-Lösung untersucht, und der Einfluß der Beize auf die elektrokinetischen Eigenschaften der mit einem kationischen Farbstoff gefärbten Cellulosefasern wurde analysiert. Das Verhalten des elektrokinetischen Potentials konnte im wesentlichen durch die Bildung von H-Brücken zwischen den phenolischen Hydroxylgruppen des Tannins und den Carboxygruppen der Cellulose sowie durch die elektrostatische Anziehung zwischen dem Farbstoff-Kation und der Faseroberfläche erklärt werden.
    Notes: Data on the adsorption of tannic acid on the hydrophilic cotton at different temperatures are presented. The thermodynamics of the adsorption equilibria of tannic acid is investigated, and it is established that the increase in temperature decreases the amount of tannic acid adsorbed. The adsorption equilibria of tannic acid are described by the Freundlich adsorption isotherm. Also, an experimental investigation on streaming potentials of cellulose/tannic acid/Rhodamine B solutions system is described and the effect of the mordant on the electrokinetic properties of cellulosic fibres dyed with a cationic dye is analyzed. The behaviour of the electrokinetic potential could be explained mainly by the H-bonds formed between the phenolic hydroxy groups of tannic acid and the carboxy groups of cellulose and by the electrostatic attraction between the dye cation and the surface of the fibre.
    Additional Material: 9 Ill.
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  • 2
    ISSN: 0025-116X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The apparent viscosity η of semi-dilute solutions of cellulose nitrate in ethyl acetate was measured as a function of shear rate at 20°C by rotational viscometry. The mass concentration c of the solutions was chosen such that the product between c and the intrinsic viscosity was 8 〈 c · [η] 〈 22, lying in the range of viscosity-average degrees of polymerization covered by the employed samples 550 〈 DPη 〈 7600. The experimental flow curves were interpreted in terms of Graessley's theory for non-Newtonian flow of polydisperse polymers. The polydispersities derived for five individual samples according to the theory of Graessley were used for calculating the resulting theoretical curves belonging to four binary mixtures each between two of them. The reasonable good agreement between calculated and experimental reduced flow curves of blends indicates consistency of the theory when applied to the present system of a semi-rigid polymer. This and other results point to a flow behaviour of semi-rigid cellulose nitrate being similar to that of linear flexible polymers.
    Additional Material: 3 Ill.
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  • 3
    ISSN: 0025-116X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The oligomerization of oxetane (trimethylene oxide) initiated by sulfuric acid in methylene chloride in the presence of 1,3-propanediol (trimethylene glycol) leads to the formation of α-hydro-ω-hydroxyoligo(oxytrimethylene)s. The effect of adding different amounts of trimethylene glycol was studied, and the dimer, 3,3′-oxydipropanol, could be isolated. Polymers from dimethyl terephthalate and 3,3′-oxydipropanol and copolymers from 1,3-propanediol, 3,3′-oxydipropanol and dimethyl terephthalate were synthesized. The influence of the chemical structure on their thermal transitions was analyzed.
    Additional Material: 2 Ill.
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  • 4
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 34 (1987), S. 1959-1966 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A significant reduction on the time for thermal crystallization of Bisphenol-A polycarbonate has been achieved by means of a previous crystallization step of the polymer in acetone, followed by a capillary extrusion processing at temperatures above its melting range (230-280°C). The crystallinity of PC was corroborated qualitatively by means of WAXS and quantitatively by means of DSC. The acetone-crystallized polymer showed higher values of dynamic viscosity than its amorphous counterpart. Such difference decreased with the increase of the test temperature and disappeared at 280°C. The degree of crystallinity of thermally crystallized PC increased with the decrease of the capillary extrusion temperature of the acetone-crystallized material. It is inferred that the time-temperature-dependent long range molecular diffusion necessary for the total melting of the crystal fractions could not take place entirely for the short times employed (≈ 4 min), allowing the extruded polymer to behave as a self-nucleated material.
    Additional Material: 6 Ill.
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  • 5
    Electronic Resource
    Electronic Resource
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 25 (1987), S. 1449-1450 
    ISSN: 0887-624X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
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  • 6
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Letters Edition 25 (1987), S. 431-435 
    ISSN: 0887-6258
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 5 Ill.
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  • 7
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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  • 8
    Electronic Resource
    Electronic Resource
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 39 (1988), S. 364-369 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Repassivierungsfähigkeit von keramikbeschichteten EdelstahlprothesenDas Durchbruchs- und das Repassivierungspotential von keramikbeschichteten Prothesen aus nicht rostendem Stahl sind in Hanks-Lösung und an Implantaten an Hunden bestimmt worden. Diese Werkstoffe zeigen geringe Lochkorrosionsempfindlichkeit und starke Repassivierungsfähigkeit. Der Einfluß von Oberflächenrauhigkeit, Tauchzeit und der Homogenisierungsbehandlung auf das Lochfraßverhalten wird diskutiert.
    Notes: The breakdown and repassivation potentials of stainless steel-ceramic prostheses have been determined both in a Hanks' solution and in implants in dogs. These materials show low susceptibility to pitting corrosion as well as a high repassivation capability. The influence of surface roughness, exposure time and homogenization treatment on the pitting corrosion behaviour is studied.
    Additional Material: 8 Ill.
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  • 9
    Electronic Resource
    Electronic Resource
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 37 (1986), S. 451-456 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Zuverlässigkeit elektrochemischer Methoden bei der Untersuchung von Prothesen aus nichtrostendem Stahl mit AluminiumoxidüberzugIm vorliegenden Bericht wird die Korrosionsbeständigkeit von Prothesen aus nichtrostendem Stahl mit Aluminiumoxidüberzug erörtert; als Versuchsmaterial dienten Stahl AISI 316 L mit plasmagespritztem Aluminiumoxidüberzug (mit und ohne Nickel als Zwischenschicht).Die Nickelschicht soll die Haftung zwischen dem keramischen Material und dem Stahl gewährleisten. Als Prüfmedium diente die Hank'sche Lösung, da diese Ähnlichkeit mit organischen Flüssigkeiten aufweist. Zur Verbesserung der Aussagefähigkeit der Ergebnisse wird empfohlen, mehrere der nachstehenden elektrochemischen Methoden nebeneinander zu verwenden: Bestimmung der Zeitabhängigkeit des Korrosionspotentials; Polarisationswiderstandsmessung; coulostatische Methoden und Wechselstrommethoden. Bei der elektrochemischen Untersuchung von keramikbeschichtetem nichtrostendem Stahl im passiven Zustand ergeben sich einige spezifische Schwierigkeiten durch die Störung der Arbeitselektrode infolge der einwirkenden elektrischen Signale, wodurch die Genauigkeit der Korrosionsgeschwindigkeitsmessung beeinträchtigt wird. Diese Schwierigkeiten treten nicht auf, wenn eine Kombination mit einer aktiveren Zwischenschicht benutzt wird.
    Notes: The corrosion resistance of alumina-covered stainless steel prosthesis is discussed in this report. The test material was an AISI 316L steel with a plasma sprayed on alumina coating, applied directly or through an intermediate nickel base layer, whose mission is to guarantee a perfect adherence between the ceramic material and the steel. Use was made in the laboratory of Hank's solution as test medium since this solution is similar to organic fluids. In order to increase the reliability of the results the simultaneous use of various of the following electrochemical methods are recommended: Determination of corrosion potential with the time, polarization resistance method, coulostatic method and a.c. methods. The use of electrochemical methods to study ceramic-covered stainless steel in the passive state poses some specific difficulties accruing from the disturbance of the working electrode by the applied electrical signals which limit the accuracy of the corrosion rate measurements. These difficulties do not appear in the case of a material having a intermediate layer which is more active.
    Additional Material: 10 Ill.
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  • 10
    Electronic Resource
    Electronic Resource
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 40 (1989), S. 668-673 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Umweltfaktoren als Ursache der ungewöhnlichen Korrosion von verzinktem StahlEine ungewöhnlich starke Korrosion von feuerverzinktem Stahl in einer subtropischen Meeresatmosphäre wurde untersucht. Aufgrund der mittels Röntgenbeugungsanalyse der Korrosionsprodukte, des umgebenden Bodens und des aus der Luft abgelagerten Staubs sowie aufgrund der REM-Befunde und der EDAX-Analyse der losen Deckschicht sowie aufgrund der metallographischen Untersuchung von Schnitten durch verzinkten Stahl mit unterschiedlichem Korrosionsgrad wird ein Mechanismus für den Angriff vorgeschlagen, der die außerordentlich hohe Korrosionsgeschwindigkeit des verzinkten Stahls auf die dort herrschenden speziellen atmosphärischen Verhältnisse zurückführt.
    Notes: A phenomenon of unusual heavy corrosion of hot dip galvanized structural steelwork in a subtropical severe marine atmosphere has been studied. Through the data optained from X-ray diffraction analysis of corrosion products, surrounding soil samples and environmental dust samples, and from SEM observations and EDAX analysis of loose corrosion scale, as well as from the information provided by the metallographic study of galvanized steel sections with different degree of corrosion, a mechanism of attack has been proposed, which accounts for the special environmental factors prevailing on the place.
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