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  • Organic Chemistry  (2)
  • 1990-1994  (2)
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  • 1990-1994  (2)
Year
  • 1
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Helvetica Chimica Acta 74 (1991), S. 1609-1621 
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Using a complete set of 2H-labeled isotopomers, the gas-phase reactions of Ti+ to Zn+ with butyl isothio-cyanate are studied. The main product for most of the metal ions is MHNCS+ formed by an ion/dipole mechanism. Exceptions are Cr+, which yields significant amounts of H2 and H2S loss, Mn+, which is the only ion that does not form MHNCS+ at all but produces mainly C2H4 and C3H6, and Zn+, which predominantly reacts by charge transfer.
    Additional Material: 6 Tab.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Helvetica Chimica Acta 73 (1990), S. 229-238 
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Bare Fe(I) cations act in the gas phase as dehydrosulfurization catalysts for butyl isothiocyanate by specifically coupling the S-atom with remote H-atoms from the ω and (ω - l) position of the alkyl chain. Other losses induced by Fe(I) are due to ‘remote functionalization’, the formation of ion/dipole intermediates, and insertion/β-hydrogen shift processes.
    Additional Material: 1 Tab.
    Type of Medium: Electronic Resource
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