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Gas-Phase Chemistry of Ti+ to Zn+ with Butyl Isothiocyanate (1991)

Eller, Karsten ; Akkök, Semiha ; Schwarz, Helmut

New York, NY : Wiley-Blackwell

Helvetica Chimica Acta 74 (1991), S. 1609-1621

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ISSN: 0018-019X

Keywords: Chemistry ; Organic Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: Using a complete set of 2H-labeled isotopomers, the gas-phase reactions of Ti+ to Zn+ with butyl isothio-cyanate are studied. The main product for most of the metal ions is MHNCS+ formed by an ion/dipole mechanism. Exceptions are Cr+, which yields significant amounts of H2 and H2S loss, Mn+, which is the only ion that does not form MHNCS+ at all but produces mainly C2H4 and C3H6, and Zn+, which predominantly reacts by charge transfer.

Additional Material: 6 Tab.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/hlca.19910740802

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