ALBERT

All Library Books, journals and Electronic Records Telegrafenberg

feed icon rss

Your email was sent successfully. Check your inbox.

An error occurred while sending the email. Please try again.

Proceed reservation?

Export
Filter
  • Polymer and Materials Science  (113)
  • Life and Medical Sciences  (16)
  • Oxide  (8)
  • 1990-1994  (137)
Collection
Publisher
Years
Year
  • 1
    ISSN: 0025-116X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The η3, η2, η2-dodeca-2(E), 6(E), 10(Z)-trien-1-yl-nickel(II) complexes [Ni(C12H19)]X (X = SbF6, O3SCF3) were treated in toluene with amorphous aluminium trifluoride (which was prepared from AlEt3 and BF3 · OEt2) in a mole ratio 1 : 10 to 20, forming a highly active catalyst for the 1,4-cis polymerization of butadiene. This catalyst is comparable in its activity and selectivity, and in the molar mass distribution of the polybutadiene, with the technical nickel catalyst Ni(O2CR)2/BF3ċOEt2/AlE3 developed by Bridgestone Tire Company thirty years ago. The existence of the C12-allynickel(II) cation [Ni(C12H19)]+ on the AlF3 support could be proved by FAB mass spectroscopic measurements. In agreement with our reaction model for the allyl nickel complex catalyzed butadiene polymerization, it is concluded that the technical nickel catalyst in its effective structure can be described as a polybutadienylnickel(II) complex co-ordinated to a polymeric fluoroaluminate anion via a fluoride bridge.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 2
    Electronic Resource
    Electronic Resource
    Basel : Wiley-Blackwell
    Die Makromolekulare Chemie, Rapid Communications 13 (1992), S. 289-298 
    ISSN: 0173-2803
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 3
    Electronic Resource
    Electronic Resource
    Springer
    Monatshefte für Chemie 122 (1991), S. 915-920 
    ISSN: 1434-4475
    Keywords: Barium ; Silver ; Mercury ; Oxide ; High-pressure synthesis
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary BaAg2Hg2O4 was prepared by an oxygen high-pressure technique. Single crystal X-ray investigations led to tetragonal symmetry, space group D 4h 3 − P4/nbm;a=6.793;c=7.086 Å;Z=2. Hg2+ and Ag+ show dumb-bell like coordination by oxygen whereas Ba2+ ions are surrounded by 8 O2− forming distorted cubes. The BaO8-polyhedra distortions are discussed in respect to the incorporation of Hg2+ ions into the BaAg2O 4 2− network.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 4
    Electronic Resource
    Electronic Resource
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 30 (1992), S. 2755-2764 
    ISSN: 0887-624X
    Keywords: acrylated silicones ; radical photocrosslinking ; polymerization kinetics ; oxygen effect ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The photoinduced radical crosslinking of silicones containing pendant acrylate and methacrylate groups has been investigated with calorimetric and ESR measurements. Oxygen very strongly influences this process, which leads to a prolonged induction period and a pseudo first-order termination reaction between polymer radicals and oxygen. Kinetically, such reaction steps are responsible for light intensity and monomer exponents, both of unity. In the absence of oxygen, second-order processes take place between polymer and primary radicals. The results of conversion-time and reaction-rate time measurements using stationary irradiations and postpolymerization experiments agree with the corresponding kinetic expressions. Long-lived polymer radicals and their decay have also been determined with ESR techniques. Long-chain spacer groups, which link the unsaturated ester moiety at the silicone backbone, increase the crosslinking rate. The final conversions of the double bonds exceed high values in each case. © 1992 John Wiley & Sons, Inc.
    Additional Material: 13 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 5
    ISSN: 0933-5137
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Additional Material: 10 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 6
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Materialwissenschaft und Werkstofftechnik 22 (1991), S. 122-127 
    ISSN: 0933-5137
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Im Rahmen von wiederkehrenden inneren Prüfungen an mit Außenkesseln versehenen Rührreaktoren, in denen Polymerisationen mit exothermer Reaktion stattfinden, erfolgten Ultraschallwanddickenmessungen an den Innenkesseln.
    Additional Material: 10 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 7
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Materialwissenschaft und Werkstofftechnik 24 (1993), S. 397-403 
    ISSN: 0933-5137
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: High temperature properties of MCrAlY(Ti, Hf) coated steel X 45 CrSi 9 3 at 600 and 700°CWithin the COST-project 501.2 WP6 several plasmasprayed MCrAlY- and Zirkonia-coatings were tested for application in diesel engines as anti corrosion coatings and as thermal barrier coatings respectively. With coated and uncoated specimens of steel X 45 CrSi 9 3, creep tests up to 1700 h at 600 and 700°C were carried out in air and under streaming hot gas simulating diesel engine exhaust gas. Under the hot gas condition a strong sulphur induced corrosion occurred at the nickel- and ironbase alloys. Silicon containing alloys exhibited the best hot gas corrosion resistance. An additional thermal barrier coating increased the corrosion resistance effectively. In all cases the coated specimens exhibited a higher creep strength in comparison to the uncoated specimens. However, no strength decrease due to the hot gas corrosion was observed.
    Notes: Im Rahmen des COST-Vorhabens 501.2 WP6 wurden eine Reihe von plasmagespritzten MCrAlY- und Zirkonoxidschichten auf ihre Eignung als Korrosionsschutz- bzw. Wärmedämmschichten für Dieselmotorventile untersucht. Dazu wurden mit beschichteten und unbeschichteten Proben des Ventilstahls X 45 CrSi 9 3 Zeitstandversuche an Luft und unter strömendem, dieseltypischen Heißgas bei 600 und 700°C durchgeführt, wobei Prüfzeiten bis zu rd. 1700 h erreicht wurden. Unter der Heißgasprüfung kam es bei den Nickel- und Eisenbasiswerkstoffen zu einer starken, durch Schwefel hervorgerufenen Korrosion. Siliziumhaltige Werkstoffe wiesen die höchste Heißgaskorrosionsbeständigkeit auf. Durch eine zusätzliche Wärmedämmschicht konnte das Korrosionsverhalten nachhaltig verbessert werden. Die beschichteten Proben wiesen in allen Fällen eine höhere Festigkeit auf als die unbeschichteten Proben. Es wurde aber in keinem Falle eine heißgaskorrosionsbedingte Festigkeitsabsenkung beobachtet.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 8
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Materialwissenschaft und Werkstofftechnik 25 (1994), S. 329-340 
    ISSN: 0933-5137
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Effect of Process Parameters in Extrusion on Fatigue BehaviourFatigue test specimens were produced by forward extrusion and subsequent heading from conventional steels, P/M steels and AlMg4.5Mn. The strain, die-opening angle, temperature and in some cases the lubricant were varied. For purpose of comparation in some cases also specimens were prepared by machining. S/N curves or cyclic deformation curves were determined mainly by stress-controlled tests.For all materials the time strength was increased by cold forming whereby the effect of strain was stronger than that of the die-opening angle. The time strength of steel is less increased by warm (semihot) forming than by cold forming. The fatigue strength, however, is not necessarily increased by cold or warm forming. After cold forming the P/M steels contrary to conventional steels revealed mainly quasielastic deformation until fracture. After warm forming, however, P/M steels, due to the decrease of porosity, behaved almost like conventional steels. For AlMg4.5Mn specimens prepared by forming - probably due to worse surface quality - revealed a lower fatigue strength than those prepared by machining. Here also a feasible effect of the choice of the lubricant was stated.
    Notes: Aus schemelzmetallurgischen und Sinterstählen sowie AlMg4,5Mn wurden durch Fließpressen und Anstauchen von Köpfen bauteilähnliche Schwingproben hergestellt. Dabei wurden Umformgrad, Schulteröffnungswinkel, Temperatur und z.T. der Schmierstoff variiert. Zu Vergleichszwecken wurden in Einzelfällen Schwingproben spannend hergestellt. Wöhlerkurven oder Wechselverformungskurven wurden zumeist in spannungskontrollierten Versuchen ermittelt. Für alle Werkstoffe wurde eine Erhöhung der Zeitfestigkeit durch eine Kaltumformung beobachtet. Der Einfluß des Schulteröffnungswinkels war schwächer als der des Umformgrades. Eine Halbwarmumformung von Stahl steigert die Zeitfestigkeit weniger als eine Kaltumformung. Die Dauerfestigkeit wird durch Kalt- oder Halbwarmumformung nicht notwendig gesteigert. Die Sinterstähle zeigten kaltfließgepreßt anders als konventionelle Stähle vornehmlich quasielastische Verformung bis zum Bruch. Halbwarmumgeformt verhalten sich Sinterstähle jedoch aufgrund der verringerten Porosität nahezu wie konventionelle. Für AlMg4,5Mn zeigten umgeformte Schwingproben im Vergleich zu spanend gefertigten - vermutlich aufgrund der schlechteren Oberfläche - eine niedrigere Dauerfestigkeit; hier wurde auch ein deutlicher Einfluß des Schmierstoffes beobachtet.
    Additional Material: 16 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 9
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Materialwissenschaft und Werkstofftechnik 25 (1994), S. 341-348 
    ISSN: 0933-5137
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: On the quantitative valuation of thermally activated material reactionsThis paper gives an insight into the fundamentals and application of the quantitative valuation of thermally activated material reactions, especially of static softening processes. Possibilities of calculating based on diffusion and chemical kinetics are reported not only for isothermal, but also generally for thermally nonstationary conditions. The special cases of constant heating or cooling rates and of constant temperatures which nearly exclusively have been described in the literature follow automatically from these more universal equations given here. For a more precise description of softening processes it is proposed that the ARRHENIUS formula is modified and generalized by introducing a temperature threshold value, i.e., a minimum or reference temperature. This allows the material softening process that independently of time always can be observed only above a minimum temperature to be represented in this way also by the physical-mathematical model. Integrals are calculated and explizit solutions are given for characteristic temperature-time dependences. Finally, the fundamental method of determining the model parameters is described.
    Notes: Der Beitrag gibt einen Einblick in Grundlagen und Anwendung der quantitativen Bewertung thermisch aktivierter Werkstoffreaktionen, insbesondere bei statisch ablaufenden Entfestigungsvorgängen. Berechnungsmöglichkeiten werden auf der Grundlage von Diffusion und chemischer Kinetik nicht nur für isotherme, sondern allgemein für thermisch beliebig instationäre Bedingungen angegeben. Die im Fachschrifttum fast ausschließlich betrachteten Spezialfälle konstanter Erwärmungs- oder Abkühlraten und konstanter Temperaturen ergeben sich aus den hier angegebenen allgemeingültigeren Gleichungen zwanglos. Zur präziseren Beschreibung von Entfestigungsvorgängen wird vorgeschlagen, den Arrhenius-Ansatz dahingehend zu modifizieren bzw. zu verallgemeinern, daß ein Temperaturschwellenwert - eine Mindestbzw. Bezugstemperatur - in geeigneter Weise eingeführt wird. Dadurch wird erreicht, daß eine Werkstoffentfestigung, die - praktisch unabhängig von der Zeitdauer - immer erst oberhalb gewisser Mindesttemperaturen beobachtbar ist, in dieser Weise auch durch das physikalisch-mathematische Modell erfaßt und widergespiegelt wird. Für charakteristische Temperatur-Zeit-Abhängigkeiten werden die auftretenden Integrale berechnet und explizite Lösungen angegeben. Abschließend wird der prinzipielle Weg zur Bestimmung der Modellparameter skizziert.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 10
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Advanced Materials for Optics and Electronics 3 (1994), S. 131-136 
    ISSN: 1057-9257
    Keywords: II-VI compound ; SrS : Ce ; Photoluminescence ; Concentration quenching ; Phosphorescence ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Electrical Engineering, Measurement and Control Technology , Physics
    Notes: The luminescence efficiency of SrS: Ce powders in the doping range from 0.01 to 1.0 at.% was investigated by photoluminescence decay studies. The radiative decay time of Ce3+ in SrS was determined to be 27 ns. The onset of concentration quenching at concentrations higher than about 0.7 at.% has been obtained. The photoluminescence spectrum of Ce3+ exhibits two emission bands as a consequence of the ground state splitting. The Huang-Rhys factor of the 5d-4f transition was estimated to be about 6. The inhomogeneous broadening of the emission band of samples with higher doping level has been investigated by site-selective and time-resolved spectroscopy.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
Close ⊗
This website uses cookies and the analysis tool Matomo. More information can be found here...