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  • Articles  (59)
  • Springer  (46)
  • Wiley  (13)
  • 1990-1994  (59)
  • Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition  (44)
  • Electrical Engineering, Measurement and Control Technology  (9)
  • Geography  (7)
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  • Articles  (59)
Year
Journal
  • 1
    Electronic Resource
    Electronic Resource
    Springer
    International journal of biometeorology 37 (1993), S. 89-95 
    ISSN: 1432-1254
    Keywords: Airborne pollen ; Airborne spores ; Pollen diagrams ; Meteorological factors
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geography , Physics
    Notes: Abstract A qualitative and quantitative analysis of airborne pollen and spores was carried out over 2 years (from September 1987 to August 1989) in the city of León. Slides were prepared daily using a volumetric pollen trap, which was placed on the Faculty of Veterinary Science building (University of León) 12m above ground-level. Fifty-one pollen types were observed; the most important of these were: Cupressaceae during the winter,Pinus andQuercus in spring, and Poaceae, Leguminosae and Chenopodiaceae in the summer. The results also showed the existence of a rich mould spore assemblage in the atmosphere. The group of Amerospores (Penicillium, Aspergillus andCladosporium) as well as Dictyospores (Alternaria) were the most abundant;Puccinia was common in the air in August. Fluctuations in the total pollen and spores m3 of air were compared with meteorological parameters (temperature, relative humidity and rainfall). From the daily sampling of the atmosphere of León, considering the maximum and minimum temperature and duration of rainfall, the start of the pollen grain season was observed generally to coincide with a rise in temperature in the absence of rain.
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 1432-5225
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Summary The in vitro decay of Aextoxicon punctatum and Fagus sylvatica wood by the fungi Trametes versicolor, Ganoderma australe, Phlebia chrysocrea and Lentinus cyathiformis was studied by the agar-block method, and then the decayed woods were analyzed by chemical and spectroscopic techniques. The results demonstrated the strong resistance of the A. punctatum wood to the brown-rot fungus L. cyathiformis; the resistance might be related to the low S/G lignin ratio in this Austral hardwood. Wood decay by the Austral white-rot fungi G. australe and P. chrysocrea was rather limited, and preferential degradation of lignin was not produced although all the fungi studied increased wood digestibility. The most characteristic white and brown-rot decay patterns were observed during the in vitro decay with T. versicolor and L. cyathiformis, respectively. Trametes versicolor caused high weight losses and reduced the lignin content of the wood, whereas L. cyathiformis produced a preferential removal of xylan. No important changes in the solid-state 13C NMR spectra were observed after wood degradation by T. versicolor, but this technique evidenced an increase in aromatic carbon by L. cyathiformis. This increase was higher than that found in the Klason lignin content, suggesting the presence of altered lignin fractions in the brown-rotted wood.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Springer
    Agriculture and human values 11 (1994), S. 178-182 
    ISSN: 1572-8366
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract Farmers are experts on their natural environment and are innate experimenters. However they do not know everything. Filling in gaps of missing farmer knowledge can help them improve their experiments. The authors designed and taught a course to Honduran farmers that effectively covered a number of key points on insect ecology and biology that farmers had not understood. After receiving the course many farmers did experiments to solve pest problems without synthetic pesticides.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Springer
    Journal of applied electrochemistry 23 (1993), S. 531-546 
    ISSN: 1572-8838
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Electrical Engineering, Measurement and Control Technology
    Notes: Abstract We present a critical review on the use of STM as anin situ technique to characterize electrochemical systems based on the work performed in our laboratory. Contributions ofin situ STM studies include: (i) atomic resolution of electrodeposited lead on graphite; (ii) imaging of modifications on metallic electrode surfaces induced by electrochemical oxidation-reduction processes; (iii) imaging of corrosion process on aluminium and Al-Ta alloy electrodes in NaCl solution; (iv) characterization of semiconductor-solution interfaces. These studies allowed: (a) establishment of STM as a technique which, for some systems, yields atomic resolution of metallic surfaces in air and in solution; (b) establishment of a mechanism for the electrochemical growth of oxide films on metal electrodes; (c) establishment of a corresponding mechanism for the reduction of those electrochemically grown oxide films; (d) direct monitoring of corrosion processes on a scale of nm to μm; and (e) determination of the presence of surface states and their energy position at the semiconductor-solution interfaces.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Springer
    Journal of applied electrochemistry 23 (1993), S. 641-645 
    ISSN: 1572-8838
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Electrical Engineering, Measurement and Control Technology
    Notes: Abstract Electrodeposited Ni-Zn and Ni-S on a mild steel substrate have shown very good performance as cathode materials for the HER in alkaline media. The materials were studied previously with surface techniques and evaluated through current-potential curves and long term operation. This paper describes a detailed mechanistic study of the HER on Ni-Zn and Ni-S carried out with impedance techniques. In both cases the reaction proceeds through a Volmer-Heyrovsky mechanism. As predicted by kinetic theory, the temperature study shows that the energy of activation of the rate determining step is the same as the energy of activation of the overall reaction.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Springer
    Journal of applied electrochemistry 22 (1992), S. 888-892 
    ISSN: 1572-8838
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Electrical Engineering, Measurement and Control Technology
    Notes: Abstract The characteristics and mechanism of the hydrogen evolution reaction on a nickel sulphide electrode incorporating molybdenite particles are described. At 25°C the overpotential for the reaction is 300 mV lower than that of the mild steel cathodes used in unipolar electrolysers. The material shows good stability under long term operation.
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  • 7
    Electronic Resource
    Electronic Resource
    Springer
    Journal of applied electrochemistry 22 (1992), S. 973-977 
    ISSN: 1572-8838
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Electrical Engineering, Measurement and Control Technology
    Notes: Abstract This paper describes the preparation of Ni−Zn and Ni−Co−Zn coatings by electrodeposition on a mild steel substrate. After treatment in a KOH solution to leach out part of the zinc, the materials were evaluated as cathodes for the hydrogen evolution reaction in alkaline solutions. The materials were found to have high surface areas and low Tafel slopes. Overpotentials at current densities of technological interest are significantly lower than those of the traditional materials used in water electrolysis.
    Type of Medium: Electronic Resource
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  • 8
    ISSN: 1572-8838
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Electrical Engineering, Measurement and Control Technology
    Notes: Abstract The pitting corrosion of copper in alkaline solutions in the presence of benzotriazole (BTA) was investigated. The presence of BTA shifts the breakdown (E b) and the repassivating (E p) potentials positively with respect to the blanks. However, the shift ofE p becomes smaller than that ofE b, particularly at pH9 and 11. Pitting corrosion involves the formation of crystallographic pits. The kinetics of the process fits a nucleation and growth mechanism involving instantaneous nucleation and 3D growth under charge transfer control. The spatial distribution of pits indicates that there is no marked influence of a pit on the nucleation and growth of other pits.
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    Springer
    Journal of applied electrochemistry 24 (1994), S. 426-433 
    ISSN: 1572-8838
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Electrical Engineering, Measurement and Control Technology
    Notes: Abstract The voltammetric formation and potentiostatic growth of anodic films on Ru/Pt electrodes in HClO4 and HCl solutions were studied by single negative potential sweeps and cathodic charging curves in the potential range from −0.25 to 1.1 V vs SCE. The growth of the anodic layer proceeds through the formation of two layers of different reduction reversibility. At potentials below 500 mV, the layer more reversibly reduced, grows slowly to a maximum coverage equivalent to one oxygen monolayer. The thicker, and more stable, layer increases with holding time to a maximum of about three oxygen monolayers during the period of time studied (7 h). At holding potentials above 500 mV, the reduction charge of the anodic layer reaches a constant value after polarization for 1 h. Growth starts with formation of two layers which, with time, become a single layer which is hardly reducible. The results suggest the eventual formation of anhydrous RuO2, In HCl solutions, Cl− adsorption inhibits the formation of the anodic layer, decreasing its growth rate but reaching no limiting thickness for 7 h. At holding potentials below 650 mV vs SCE, only a single layer is formed with slight structural changes. At potentials above 650 mV, the initially homogeneous film converts with holding time into a bilayer where the outer layer becomes hardly reducible. This layer is assumed to be a stable anionic hydroxy species (RuCl5OH2−) which dissolves as Ru2O2Cl6(H2O)2−. In HClO4 and HCl the layer growth follows a direct logarithmic law.
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    Springer
    Journal of applied electrochemistry 21 (1991), S. 189-202 
    ISSN: 1572-8838
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Electrical Engineering, Measurement and Control Technology
    Notes: Abstract Current extractive metallurgy techniques for lead refining by the Betts Electrorefining Process (BEP) are reviewed. In the BEP, refined lead (〉99.99%) can be produced by the electrorefining of impure lead anodes. The process relies on the selective dissolution of lead which leaves behind a strong and adherent layer of solids (slimes) containing the noble impurities originally present in the anode. The properties of this layer are closely linked to the physical metallurgy of the lead anode. Careful control of microstructure and level of impurities in the lead anode is required, and an essential attribute of the process is the use of the H2SiF6−PbSiF6 electrolyte. This paper focuses mainly on the relationship between the anodic process and its effects. The effect of impurities and electrolysis parameters on the cathodic process are also reviewed. Descriptions of industrial operations of the BEP throughout the world are tabulated.
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