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  • Chemistry  (12)
  • 1990-1994  (6)
  • 1955-1959  (6)
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  • 1
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 2 Ill.
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  • 2
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 36 (1990), S. 1768-1772 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 4 Ill.
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  • 3
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 38 (1992), S. 761-770 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The extraction of caffeine from whole coffee beans with supercritical carbon dioxide was studied in a continuous-flow extraction apparatus. Decaffeination rates were determined as a function of CO2 flow rate, temperature and pressure by continuously monitoring the caffeine in the effluent with a flame ionization detector. Soaking the raw beans in water prior to decaffeination enhanced the rate of extraction, which increased markedly with water content. Using CO2 saturated with water also increased the rate of extraction. The rate of decaffeination increased with pressure and temperature and was influenced by both intraparticle diffusion in the water-soaked beans and external mass transfer. A mathematical model based on a linear-driving-force approximation of mass transfer and partitioning of caffeine between the water and the supercritical CO2 describes the time-dependent process. The partition coefficient for caffeine distributed between water and supercritical CO2, the only parameter determined from the dynamic extraction rate data, increases with temperature and pressure.
    Additional Material: 11 Ill.
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  • 4
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 2 Ill.
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  • 5
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 40 (1994), S. 131-142 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Thermolysis of coal yields a complex mixture of many extract products whose molecular-weight distribution (MWD) varies with time for continuous-flow, semi-batch experiments. A laboratory flow reactor with a differential fixed bed of coal particles contacted by supercritical tert-butanol was used to provide dynamic MWD data by means of HPLC gel permeation chromatography of the extract. The experimental results, multipeaked, time-dependent MWDs of extract molecules, are interpreted by a novel mathematical model based on continuous-mixture kinetics for thermal cleavage of chemical bonds in the coal network. The parameters for the MWDs of extractable groups in the coal and the rate constants are determined from the experimental data. The effect of temperature on the kinetics of the extraction is explained in terms of one- and two-fragment reactions of the extractable groups in the coal. At lower temperatures (613 and 633 K) single-fragment reactions dominate, but at higher temperatures (653 and 673 K) more bonds in the coal are broken and the two-fragment reactions become significant. Also, the detailed MWDs are related to conventional lumped data for the thermolytic extraction process. The results yield information about the structure of coal, as well as the kinetics and mechanism of supercritical thermolytic reactions.
    Additional Material: 10 Ill.
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  • 6
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 39 (1993), S. 1834-1846 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A structured-geometry model for dispersed and graded deposits was developed for chemical vapor infiltration of multiply-woven substrates of carbon filters. An earlier model was modified to allow for two reactants in the feed. The model predicts gas-phase concentration profiles in the voids of substrates and deposition amounts of two reactants as a function of time and location. Results are shown for feeding reactant gases simultaneously for dispersed deposition and periodically for the study of the graded deposition for a typical substrate. The variation in relative contents of reactants in the feed with time shows how the composition of the deposit varies. Porosities and changes of dimensions with time everywhere in the substrate are also predicted. This is an advantage of the structured-geometry model vs. a simplified homogeneous geometry for the substrate. Such a simplification may preclude predicting failure, such as delamination, which would require a local description of the composite structure.Sensitivity to input parameters such as temperature, pressure, and reactant feed concentration is discussed, and two substrate geometries are compared.The behavior of the system is predicted to be dominated by the times to fill gaps between filaments at the ply surfaces and the outermost space between plies. Furthermore, faster kinetics and slower reactant diffusion favor deposition of one material near the surface of a ply or the matrix and the other near the center of the ply or matrix. By manipulating feed rates of reactants, uniformity of material and overall porosity of the composites are predicted to be enhanced.
    Additional Material: 15 Ill.
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  • 7
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 5 (1959), S. 361-366 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The reaction rate of gaseous acetylene and hydrogen chloride was studied experimentally on a mercuric chloride-activated carbon catalyst at pressures from 1 to 4 atm. and temperatures of 167°, 212°, and 257°F. The measurements were made in a differential reactor packed with mercuric chloride impregnated on activated carbon, the data being taken to obtain the separate effect of the partial pressure of each of the components on the rate.The results indicated that hydrogen chloride was strongly adsorbed on the catalyst and that vinyl chloride was also adsorbed to a significant extent. A rate equation, which well represented the data, was developed from the following postulates: (a) acetylene is adsorbed on the catalyst on one type of site, (b) hydrogen chloride and vinyl chloride are adsorbed on a different kind of site, (c) the formation of vinyl chloride occurs by reaction of adsorbed acetylene and adsorbed hydrogen chloride, and (d) the rates of adsorption and desorption are fast compared with the formation rate of vinyl chloride.
    Additional Material: 6 Ill.
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  • 8
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 1 (1955), S. 28-37 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Although considerable work has been done on the problem of heat transfer radially in fixed beds through which gases are flowing, the data available for mass transfer are limited to one pipe size and one packing size and refer to average diffusivities for the entire bed. The present study was undertaken to determine: (1) diffusivities over a range of pipe and packing sizes and (2) the effect of radial position in the bed.The measurements were made by introducing carbon dioxide into an air stream and analyzing the resultant mixture at various positions in the bed downstream from the point of injection. Pipe sizes of 2, 3, and 4 in. were packed with spherical particles of 5/32-, 1/4-, 3/8-, and 1/2-in. nominal diameter.The differential equation describing the concentration in a packed bed when diffusivity E and the velocity u are permitted to vary with radial position was solved by use of an I.B.M. card-programmed calculator for the computations.The results show that the Peclet number Dpu/E increases from the center towards the wall of the pipe and that the increase is significant when Dp/Dt is greater than 0.05. Empirical correlations are then presented for both point Peclet numbers, which vary with radial position, and average Peclet numbers for the entire bed.The variations in Peclet number with radius can be explained in terms of the corresponding variation in void fraction for 81% of the radius of the bed. At modified Reynolds numbers above 40 to 100 the equation Pe = 8.0 + 100 (δ  -  δ0) correlates the effects of pipe and packing size and radial position. At radial positions greater than 0.81 wall friction influences turbulence conditions and the Peclet number.
    Additional Material: 21 Ill.
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  • 9
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 3 (1957), S. 49-55 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Heat transfer coefficients were measured experimentally for carbon dioxide in turbulent flow in an 0.18-in. I.D. pipe. The pressure was 1,200 lb./sq. in. abs. and the bulk temperature varied from 70° to 120°F. In this critical region the coefficients between fluid and tube wall ranged from 300 to 2,600 B.t.u./(hr.)(sq. ft./°F.) over a Reynolds number interval of 30,000 to 300,000.Existing empirical and semitheoretical correlations were found inadequate in this region, where the thermal conductivity, viscosity, density, and specific heat are all varying rapidly and nonuniformly with temperature. A method of integrating the heat and momentum transfer equations with variable physical properties, recently proposed by Deissler, was applied to the experimental data and found to fit well. The application required extensive calculations, which were carried out with an Electrodata digital computer.A simplified procedure was proposed for estimating heat transfer coefficients in the critical region by using a semitheoretical equation developed for zero heat flow. Simple rules were suggested for estimating the temperature at which to evaluate the physical properties when this equation is applied to the realt case of finite heat transfer. The method worked well when compared with the computed heat transfer coefficients of Deissler for supercritical wate but showed about 30% deviation when compared with the carbon dioxide results. This discrepancy is believed due to the fact that the carbon dioxide was very close to the critical point (reduced pressure = 1.1) but the water was somewhat further removed (reduced pressure = 1.6).
    Additional Material: 15 Ill.
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  • 10
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 3 (1957), S. 147-152 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Experimental data are presented for the heats of mixing of liquids at 25°C. and 1 atm. pressure for ten binary and five ternary systems. For nonpolar binary systems a two-constant equation has been developed which correlates the data within experimental accuracy. Several equations which have been proposed for the calculation of ternary heats of mixing from binary data are tested for the systems studied. The method of Jost and Röck (4) for determining the constants in power-series functions from experimental data is considered.
    Additional Material: 8 Ill.
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