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  • Polymer and Materials Science  (4)
  • Dicopper trihydroxide nitrite  (1)
  • 1990-1994  (4)
  • 1975-1979  (1)
  • 1930-1934
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  • 1
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Interactions between creep deformation and hot gas corrosionThe paper starts with a short explanation of the basic processes during the high temperature corrosion and of deformation under creep stress.Corrosion may give rise to an increase or a decrease of creep resistance, or it may result in an increase of the stress applied. The individual mechanisms are explained and, as far as possible, illustrated by examples. As a rule, however, several factors act simultaneously. The concerted actions is further complicated by back effects of a creep deformation on the corrosion processes. In the case of iron and nickel base alloys there exist obviously critical strain rates beyond which corrosion is enhanced and then proceeds more pronouncedly at the grain boundaries. It is also possible that then internal corrosion processes are triggered, in particular, in the grain boundary regions.While a qualitative assessment of the relationships between corrosion and creep deformation is possible, the feasibility of a quantitative description is still far away. As a rule, however, the aspect of a strength decrease will prevail although, in principle, corrosion may give rise to a strengthening, too.
    Notes: Einleitend werden kurz die Grundvorgänge der Heißgaskorrosion und der Verformung unter Zeitstandbeanspruchung erläutert.Die Korrosion kann den Kriechwiderstand erhöhen oder erniedrigen oder aber auch die anliegende Spannung vergrößern. Die einzelnen Mechanismen werden erläutert und - soweit möglich - durch Beispiele belegt. In der Regel wirken jedoch gleichzeitig mehrere Faktoren ein. Das Zusammenspiel wird durch Rückwirkungen der Kriechverformung auf die Korrosionsvorgänge weiter kompliziert. Für Eisen- und Nickelbasislegierungen gibt es offenbar kritische Dehngeschwindigkeiten, bei deren Überschreiten die Korrosion verstärkt und stärker korngrenzenorientiert abläuft. Auch innere Korrosionsvorgänge können dadurch besonders im Korngrenzenbereich ausgelöst werden.Während die Zusammenhänge zwischen Korrosion und Kriechverformung qualitativ überschaubar sind, liegt die Möglichkeit einer quantitativen Beschreibung noch in weiter Ferne. In der Regel werden die „Negativ-Punkte“ überwiegen, obgleich im Prinzip die Korrosion auch eine Verfestigung bewirken kann.
    Additional Material: 13 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Chemie Ingenieur Technik - CIT 66 (1994), S. 1244-1244 
    ISSN: 0009-286X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Chemie Ingenieur Technik - CIT 65 (1993), S. 1105-1105 
    ISSN: 0009-286X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 4
    ISSN: 0044-2313
    Keywords: Dicopper trihydroxide nitrite ; crystal structure ; i.r., Raman spectra ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Lattice Vibration Spectra. LXXVI. On Basic Copper Salts  -  Crystal Structure, IR and Raman Spectra of Cu2(OH)3NO2Single-crystal X-ray as well as IR and Raman data of Cu2(OH)3NO2 are presented and discussed with respect to an order-disorder (OD) phase transition and the strength of hydrogen bonds. Cu2(OH)3NO2 crystallizes pseudosymmetrically in the monoclinic space group P21/m (Z = 2, a = 562.22(4), b = 605.94(5), c = 663.55(4) pm and β = 95.415(5)°) forming a layered structure of edge-connected, elongated CuO6 octahedra (final R value 2.5% for 1047 symmetry averaged reflections with I ≥ 2.5 μ1). The NO2- ions are on a split position with dynamic disordering at ambient temperature. On temperature lowering the disorder is frozen out with a symmetry decrease to space group P21. The disorder of the NO2- ions causes four different arrangements of OH(2)- with different strengths of the H…O hydrogen bonds present OD stretching modes in the spectra of isotopically dilute samples 2628, 2535, 2435, and 2343 cm-1 at 90 K. The OH(1)- ions form weak H…N H-bonds to the lone-pair of the nitrogen atoms of the NO2- ions (vOD 2563 cm-1).
    Notes: Die Kristallstruktur sowie die IR- und Raman-Spektren von Cu2(OH)3NO2 werden mitgeteilt und im Hinblick auf eine Ordnungs-Unordnungs(OD)-Phasenumwandlung sowie die Stärke der vorhandenen Wasserstoffbrücken diskutiert. Das basische Nitrit kristallisiert pseudosymmetrisch in der monoklinen Raumgruppe P21/m (Z = 2, R = 2,5%, 1047 symmetriegemittelte Reflexe mit 1 〉 2,5 μ1). Cu2(OH)3NO2 bildet eine Schichtenstruktur kantenverknüpfter, gestreckter CuO6-Oktaeder. Die Nitritionen befinden sich auf einer Splitlage mit dynamischer Fehlordnung bei Raumtemperatur. Bei niedrigeren Temperaturen friert die Fehlordnung unter Bildung von NO2--Zick-Zack-Ketten und Symmetrieerniedrigung zu P21 aus. Aufgrund der Fehlordnung der NO2--Ionen ergeben sich für die OH(2)--Ionen vier verschiedene Anordnungen mit entsprechend unterschiedlich starken H-Brücken (H…O). Die OH(1)--Ionen bilden H…N-Wasserstoffbrücken zum freien Elektronenpaar des N-Atoms der NO2--Ionen.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Acta Polymerica 45 (1994), S. 389-391 
    ISSN: 0323-7648
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The chain stiffness of a methoxypropyl-substituted poly[1.1.1]propellane in solution is investigated by static and dynamic light scattering. The Kuhn statistical segment length is determined as lk=150Å utilizing the Kratky-Porod wormlike chain model. It is, however, not yet clear whether the derived Kuhn length characterizes the chain stiffness of a perfect polypropellane chain or rather originates from “kinks” in the polymer backbone due to the presence of possible side reactions during polymerization.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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