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  • Articles  (7)
  • Physical Chemistry  (4)
  • Cytokinesis  (3)
  • 1990-1994  (3)
  • 1985-1989  (4)
  • 1
    Electronic Resource
    Electronic Resource
    Minispindles and cytoplasmic domains in microsporogenesis of orchids (1989)
    Springer
    Protoplasma 148 (1989), S. 26-32 
    Details
    ISSN: 1615-6102
    Keywords: Cytokinesis ; Cytoplasmic domains ; Meiosis ; Microtubules ; Minispindles
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Summary Changes in the microtubular cytoskeleton during meiosis and cytokinesis in hybrid moth orchids were studied by indirect immunofluorescence. Lagging chromosomes not incorporated into telophase nuclei after first meiotic division behave as small extra nuclei. Events in the microtubular cycle associated with these micronuclei are similar to and synchronous with those of the principal nuclei. During second meiotic division the micronuclei trigger formation of minispindles which are variously oriented with respect to the two principal spindles. After meiosis, radial systems of microtubules measure cytoplasmic domains around each nucleus in the coenocyte. Cleavage planes are established in regions where opposing radial arrays interact and the cytoplasm cleaved around micronuclei is proportionately smaller than that around the four principal nuclei. These observations clearly demonstrate that nuclei in plant cells are of fundamental importance in microtubule organization and provide strong evidence in support of our recently advanced hypothesis that division planes in simultaneous cytokinesis following meiosis are determined by establishment of cytoplasmic domains via radial systems of nuclear-based microtubules rather than by division sites established before nuclear division.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF01403988
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  • 2
    Electronic Resource
    Electronic Resource
    Pollen development in orchids (1991)
    Springer
    Protoplasma 165 (1991), S. 155-166 
    Details
    ISSN: 1615-6102
    Keywords: Cytokinesis ; F-actin ; Microsporogenesis ; Microtubules ; Orchids ; Phragmoplast
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Summary Cytokinesis in microsporocytes of moth orchids is unusual in that it occurs simultaneously after meiosis, the cytoplasm does not infurrow in the division planes, and cell plates are deposited in association with centrifugal expansion of phragmoplasts. Microtubules radiating from the nuclear envelopes appear to be of fundamental importance in establishment of division planes. Primary interzonal spindles develop between sister nuclei and interaction of radial microtubules triggers development of secondary interzonal spindles between non-sister nuclei. From three to six or more phragmoplasts, depending upon the arrangement of nuclei in the coenocyte, develop from these postmeiotic arrays. The phragmoplasts consist of co-aligned microtubules and F-actin organized into bundles that are broad proximal to the mid-plane and taper distally. Ultrastructure of the phragmoplast/cell plate reveals that abundant ER is associated with vesicle aggregation and coalescence. Cell plates are deposited in association with phragmoplasts as they expand centrifugally to join the parental wall and/or fuse with one another in the interior of the cell.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF01322286
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  • 3
    Electronic Resource
    Electronic Resource
    Division polarity, development and configuration of microtubule arrays in bryophyte meiosis (1987)
    Springer
    Protoplasma 138 (1987), S. 1-10 
    Details
    ISSN: 1615-6102
    Keywords: Meiosis ; Microtubules ; Cytokinesis ; Immunofluorescence ; Bryophytes
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Summary First and second division spindles and the three cell plates of moss meiosis are oriented in accordance with polarity established during meiotic prophase. Plastids are located at the second division poles and cytoplasmic infurrowing marks the planes along which the cytoplasm will cleave into four spores. Anaphase I spindles that terminate in two focal points of microtubules straddling opposite cleavage furrows reflect the unusual tetrahedral origin of the functionally bipolar spindle. The organelles (except for the plastids which remain in the four cytoplasmic lobes) are polarized in the first division equatorial region at the time of phragmoplast microtubule assembly and remain in a distinct band after microtubule disassembly. Prophasic spindles appear to be directly transformed into metaphase II spindles in the predetermined axes between mutually perpendicular pairs of plastids. Cell plates form by vesicle coalescence in the equatorial regions of the two sets of second division phragmoplasts at approximately the same time as a cell plate belatedly forms in the organelle band. The cytoplasmic markers (plastid migration, cytoplasmic lobing and infurrowing) that predict poles and cleavage planes in free cells lacking a preprophase band strongly strengthens the concept that division sites are capable of preserving preprogrammed signals that can be triggered later in the process of cell division.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF01281179
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  • 4
    Electronic Resource
    Electronic Resource
    Hydrogen transfer from 9,10-dihydrophenanthrene to anthracene (1989)
    New York, NY : Wiley-Blackwell
    International Journal of Chemical Kinetics 21 (1989), S. 375-386 
    Details
    ISSN: 0538-8066
    Keywords: Chemistry ; Physical Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Kinetic studies of the transfer of hydrogen from 9,10-dihydrophenanthrene to anthracene were done at 350°C in the liquid phase. Principal products were phenanthrene and 9,10-dihydroanthracene. Autocatalysis occurred at low extents of reaction, where H-transfer from 9,10-dihydroanthracene to anthracene caused an increase in free radical concentrations. At higher extents of reaction, 9,10-dihydroanthracene inhibited rates by diverting intermediate 9-hydrophenanthryl radicals back to reactants. A quantitative kinetic model based on literature rate and thermodynamic data fits the observations well. A key net reaction is the transfer of an H-atom from a radical (9-hydrophenanthryl) to a molecule (anthracene). It is shown that this process does not involve a free H-atom intermediate. The derived rate constant for this exothermic process (7.5 × 103 M-1 s-1) is considerably greater than that for the related, but thermoneutral H-transfer between anthracene moieties (120 M-1 s-1).
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/kin.550210602
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  • 5
    Electronic Resource
    Electronic Resource
    Rate constants for hydrogen abstraction by resonance stabilized radicals in high temperature liquids (1987)
    New York, NY : Wiley-Blackwell
    International Journal of Chemical Kinetics 19 (1987), S. 943-957 
    Details
    ISSN: 0538-8066
    Keywords: Chemistry ; Physical Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Benzylic H-atom abstraction rates by diphenylmethyl radicals from a series of donors were determined in nonpolar liquids at elevated temperatures. Relative rates were converted to absolute rates via available equilibrium constant data for the dimerization of diphenylmethyl radicals. Abstraction by diphenylmethyl from 1, 2, 3, 4-tetrahydronaphthalene (tetralin) was studied over the temperature range 489-573 K. Its Arrhenius expression is 109.9±0.3 exp{-(10183 ± 373)/T} M-1 s-1. Abstraction from other donors was studied at 548 K. Rate constant values ranged from a low of 3.6 M-1 s-1 for toluene to a high of 3000 M-1 s-1 for 9, 10-dihydroanthracene. Similar reactions with the fluorenyl radical were also studied. In this case, relative rates were converted to absolute rates with an equilibrium constant for fluorenyl dimerization determined from the observed homolysis rate of the dimer and an assumed recombination rate. In addition, forward and reverse rate measurements yielded the equilibrium constant for hydrogen transfer between fluorenyl and diphenylmethyl. At 548 K, fluorenyl is favored by a factor of 13 over diphenylmethyl.
    Additional Material: 5 Tab.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/kin.550191006
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  • 6
    Electronic Resource
    Electronic Resource
    Kinetic model of liquid B2O3 gasification in a hydrocarbon combustion environment: I. Heterogeneous surface reactions (1991)
    New York, NY : Wiley-Blackwell
    International Journal of Chemical Kinetics 23 (1991), S. 957-970 
    Details
    ISSN: 0538-8066
    Keywords: Chemistry ; Physical Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: As part of an ongoing program to model hydrocarbon assisted boron combustion, a kinetic model has been developed to describe gasification of the ubiquitous boron oxide coating that inhibits particulate boron ignition. This model includes homogeneous gas phase oxidation reactions, multi-component gas phase diffusion, heterogeneous surface reactions, and oxide vaporization. The kinetic processes are treated using a generalized kinetics code, with embeded sensitivity analysis, for the combustion of a one-dimensional (particle radius), spherical particle.This article presents the heterogeneous surface reactions used to describe oxide gasification and presents selected model results for a spherical boron oxide droplet which illustrate the dependence of the oxide gasification rates on the ambient temperature and particle diameter.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/kin.550231102
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  • 7
    Electronic Resource
    Electronic Resource
    Kinetic model for hydrocarbon-assisted particulate boron combustion (1994)
    New York, NY : Wiley-Blackwell
    International Journal of Chemical Kinetics 26 (1994), S. 319-332 
    Details
    ISSN: 0538-8066
    Keywords: Chemistry ; Physical Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: A kinetic model is presented to describe the high temperature (1800 K 〈 T 〈 3000 K) surface oxidation of particulate boron in a hydrocarbon combustion environment. The model includes a homogeneous gas-phase B/O/H/C oxidation mechanism consisting of 19 chemical species and 58 forward and reverse elementary reactions, multi-component gas-phase diffusion, and a heterogeneous surface oxidation mechanism consisting of ‘elementary’ adsorption and desorption reaction steps. Thermochemical and kinetic parameters for the surface reactions are estimated from available experimental data and/or elementary transition state arguments. The kinetic processes are treated using a generalized kinetics code, with embedded sensitivity analysis, for the combustion of a one-dimensional (particle radius), spherical particle. Model results are presented for the oxidation of a 200 μm boron particle in a JP-4/air mixture at ambient temperatures of 1400 K and 2000 K. These results include temperature and gas-phase species profiles as a function of radial distance and particle burning rates. © 1994 John Wiley & Sons, Inc.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/kin.550260302
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