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  • permeation  (2)
  • composite  (1)
  • Atomic, Molecular, and Optical Physics
  • Composites
  • Instable interface
  • Nickel coated graphite
  • 1995-1999  (3)
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Year
  • 1
    Electronic Resource
    Electronic Resource
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part B: Polymer Physics 33 (1995), S. 1365-1370 
    ISSN: 0887-6266
    Keywords: polyketone terpolymer ; water vapor ; permeation ; clustering ; sorption ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Water transport in a polyketone terpolymer was analyzed performing both sorption and permeation experiments. Water vapor sorption tests were conducted at four temperatures (35, 45, 55, and 65°C) and at several activities. The analysis of sorption isotherms revealed the occurrence of water clustering. A reduction of the endothermicity of mixing as the amount of sorbed water increased was observed which is consistent with significant association of penetrant molecules in the polymer. Permeation experiments performed at 35°C at upstream pressures ranging from 4 to 25 Torr showed evidence of a reduction in water diffusivity as function of sorbed water concentration which is a typical indication of penetrant aggregation. © 1995 John Wiley & Sons, Inc.
    Additional Material: 11 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part B: Polymer Physics 33 (1995), S. 1269-1280 
    ISSN: 0887-6266
    Keywords: ionomer ; permeation ; diffusion ; sorption ; gas ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Transport properties of several gases in two ethylene-acrylic acid ionomers characterized by a different amount of acrylic acid groups and percentage of neutralization have been investigated. Sorption and permeation experiments have been performed with N2, O2, CO2, CH4, C2 H6, and SF6 in the 25-65°C range and with C3H8 only at 25°C. Gas permeabilities, diffusivities, and solubilities were evaluated along with activation energies and heats of solution. Data obtained in the present investigation were compared to analogous results reported in literature for polyethylene to better highlight the effect of ionic aggregates on the gas transport mechanism. © 1995 John Wiley & Sons, Inc.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    Journal of Biomedical Materials Research 42 (1998), S. 6-12 
    ISSN: 0021-9304
    Keywords: composite ; ligaments ; viscoelasticity ; mechanical properties ; hydrogels ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Medicine , Technology
    Notes: Despite the compelling need for artificial connective tissue replacements for orthopedic applications, to date, there is no material which can adequately reproduce the mechanical behavior of natural tissue with necessary long-term endurance. In this work, we introduce a novel soft composite material as a more suitable candidate for connective tissue replacement. The material proposed is based on a hydrogel-polymer matrix reinforced with poly(ethylene terephthalate) fibers wound helically to mimic the architecture of the collagen fibers in natural tissue. Macroscopic behaviors such as static stress-strain, stress relaxation, and dynamic frequency responses can be modulated with choice of the components and design of the composite structure. In doing so, the mechanical characteristics of natural ligaments can be qualitatively reproduced and sustained over time. © 1998 John Wiley & Sons, Inc. J. Biomed Mater Res, 42, 6-12, 1998.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
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