ISSN:
0947-3440
Keywords:
Metallotriazolehemiporphyrazines
;
Phthalocyanines
;
Hemiporphyrazines
;
Electrical conductivity measurements
;
Chemistry
;
Organic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Novel triazolehemiporphyrazines 3a, 4a, and 5a, substituted on the isoindole units and soluble in organic solvents, have been synthesized by condensation of 3,5-diamino-1,2,4-triazole with the corresponding 1,3-diiminoisoindoline. First-row transition-metal complexes 3b-e, 4b-e, and 5b-e have also been prepared by reaction of the free ligands 3a, 4a, and 5a with the appropriate metal(II) salt. A FAB mass spectrometric study of this kind of metallomacrocycles is reported. Triazolehemiporphyrazines 3-5 show electrical conductivities in the range of 10-12-10-9 Scm-1.
Additional Material:
1 Tab.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/jlac.199519950368
Permalink