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  • Metals and Metallic Materials  (5)
  • Holocene  (1)
  • Beyond the standard model
  • E41
  • 2000-2004  (6)
  • 1
    ISSN: 1573-0417
    Keywords: saline lakes ; stable isotope ; sedimentology ; mineralogy ; paleohydrology ; Altiplano ; Holocene ; Little Ice Age
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences
    Notes: Abstract The paleohydrological evolution of several high altitude, saline lakes located in the southernmost Altiplano (El Peinado and San Francisco basins, Catamarca province, NW Argentina) was reconstructed applying sedimentological, geochemical and isotopic techniques. Several playa lakes from the San Francisco basin (26° 56′ S; 68° 08′ W, 3800-3900 m a.s.l.) show evidence of a recent raise in the watertable that led to modern deposition of carbonate and diatomaceous muds. A 2 m - long core from El Peinado Lake (26° 29′ 59′′ S, 68°05′ 32′′ W, 3820 m a.s.l.) consists of calcitic crusts (unit 3), overlaid by an alternation of macrophyte-rich and travertine clast- rich, laminated muds (unit 2), and topped by travertine facies (unit 1). This sedimentary sequence illustrates a paleohydrological evolution from a subaerial exposure (unit 3) to a high lake stand (unit 2), and a subsequent smaller decrease in lake level (unit 1). The δ13Corganic matterrecord also reflects the lake transgression between units 3 and 2. Although there is a general positive correlation between δ 18Ocarbonate and salinity proxies (Na, Li and B content), the large data dispersion indicates that other factors besides evaporation effects control chemical and isotopic composition of lakewater. Consequently, the oxygen isotopic composition cannot be interpreted exclusively as an indicator of salinity or evaporation ratio. The degassing of CO2 during groundwater discharge can explain the enriched δ13C values for primary carbonates precipitated. The carbon budget in these high altitude, saline lakes seems to be controlled by physical rather than biological processes.The Altiplano saline lakes contain records of environmental and climatic change, although accurate 14C dating of these lacustrine sediments is hindered by the scarcity of terrestrial organic material, and the large reservoir effects. Sedimentologic evidence, a 210Pb-based chronology, and a preliminary U/Th chronology indicate a very large reservoir effect in El Peinado, likely as a result of old groundwaters and large contributions of volcanic and geothermal 14C-free CO2 to the lake system. Alternative chronologies are needed to place these paleorecords in a reliable chronological framework. A period of increased water balance in the San Francisco basin ended at about 1660 ± 82 yr B.P. (calendar yr U/Th age), and would correlates with the humid phase between 3000 and 1800 yr B.P detected in other sites of the southern Altiplano. Both, 210Pb and preliminary U/Th dating favor a younger age for the paleohydrological changes in El Peinado. The arid period reflected by subaerial exposure and low lake levels in unit 3 would have ended with a large increase in effective moisture during the late 17th century. The increased lake level during deposition of unit 2 would represent the period between AD1650 - 1900, synchronous to the Little Ice Age. This chronological framework is coherent with other regional records that show an abrupt transition from more arid to more humid conditions in the early 17th century, and a change to modern conditions in the late 19th century. Although there are local differences, the Little Ice Age stands as a significant climatic event in the Andean Altiplano.
    Type of Medium: Electronic Resource
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  • 2
    Publication Date: 2018-06-05
    Description: With renewed interest in developing nuclear-powered deep space probes, attention will return to improving the metallurgical processing of potential nuclear fuels so that they remain dimensionally stable over the years required for a successful mission. Previous work on fuel alloys at the NASA Glenn Research Center was primarily empirical, with virtually no continuing research. Even when empirical studies are exacting, they often fail to provide enough insight to guide future research efforts. In addition, from a fundamental theoretical standpoint, the actinide metals (which include materials used for nuclear fuels) pose a severe challenge to modern electronic-structure theory. Recent advances in quantum approximate atomistic modeling, coupled with first-principles derivation of needed input parameters, can help researchers develop new alloys for nuclear propulsion.
    Keywords: Metals and Metallic Materials
    Type: Research and Technology 2002; NASA/TM-2003-211990
    Format: application/pdf
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  • 3
    Publication Date: 2019-07-10
    Description: The Bozzolo, Ferrante, and Smith (BFS) method for alloys is applied to the study of Pt deposition on Cu(100). The formation of a Cu-Pt surface alloy is discussed within the framework of previous results for Pd/Cu(100). In spite of the fact that both Pd and Pt share the same basic behavior when deposited on Cu, it is seen that subtle differences become responsible for the differences in growth observed at higher cover-ages. In agreement with experiment, all the main features of Pt/Cu(100) and Pd/Cu(100) are obtained by means of a simple modeling scheme, and explained in terms of a few basic ingredients that emerge from the BFS analysis.
    Keywords: Metals and Metallic Materials
    Type: E-13821
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  • 4
    Publication Date: 2019-07-10
    Description: The BFS (Bozzolo-Ferrante-Smith) method for alloys is applied to the study of the Cu-Pd system. A variety of issues are analyzed and discussed, including the properties of pure Cu or Pd crystals (surface energies, surface relaxations), Pd/Cu and Cu/Pd surface alloys, segregation of Pd (or Cu) in Cu (or Pd), concentration dependence of the lattice parameter of the high temperature fcc CuPd solid solution, the formation and properties of low temperature ordered phases, and order-disorder transition temperatures. Emphasis is made on the ability of the method to describe these properties on the basis of a minimum set of BFS universal parameters that uniquely characterize the Cu-Pd system.
    Keywords: Metals and Metallic Materials
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  • 5
    Publication Date: 2019-07-10
    Description: Ideally, computational modeling techniques for nanoscopic physics would be able to perform free of limitations on the type and number of elements, while providing comparable accuracy when dealing with bulk or surface problems. Computational efficiency is also desirable, if not mandatory, for properly dealing with the complexity of typical nano-strucured systems. A quantum approximate technique, the BFS method for alloys, which attempts to meet these demands, is introduced for the calculation of the energetics of nanostructures. The versatility of the technique is demonstrated through analysis of diverse systems, including multi-phase precipitation in a five element Ni-Al-Ti-Cr-Cu alloy and the formation of mixed composition Co-Cu islands on a metallic Cu(III) substrate.
    Keywords: Metals and Metallic Materials
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  • 6
    Publication Date: 2019-07-10
    Description: The change in site preference in NiAl(Ti,Cu) alloys with concentration is examined experimentally via ALCHEMI and theoretically using the Bozzolo-Ferrante-Smith (BFS) method for alloys. Results for the site occupancy of Ti and Cu additions as a function of concentration are determined experimentally for five alloys. These results are reproduced with large-scale BFS-based Monte Carlo atomistic simulations. The original set of five alloys is extended to 25 concentrations, which are modeled by means of the BFS method for alloys, showing in more detail the compositional range over which major changes in behavior occur. A simple but powerful approach based on the definition of atomic local environments also is introduced to describe energetically the interactions between the various elements and therefore to explain the observed behavior.
    Keywords: Metals and Metallic Materials
    Type: E-13641
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