ALBERT

Description: We examine the link between organic matter degradation, anaerobic methane oxidation (AMO), and sulfate depletion and explore how these processes potentially influence dolomitization. We determined rates and depths of AMO and dolomite formation for a variety of organic-rich sites along the west African Margin using data from Ocean Drilling Program (ODP) Leg 175. Rates of AMO are calculated from the diffusive fluxes of CH4 and SO4, and rates of dolomite formation are calculated from the diffusive flux of Mg. We find that the rates of dolomite formation are relatively constant regardless of the depth at which it is forming, indicating that the diffusive fluxes of Mg and Ca are not limiting. Based upon the calculated log IAP values, log K(sp) values for dolomite were found to narrowly range between -16.1 and -16.4. Dolomite formation is controlled in part by competition between AMO and methanogenesis, which controls the speciation of dissolved CO2. AMO increases the concentration of CO3[2-] through sulfate reduction, favoring dolomite formation, while methanogenesis increases the pCO2 of the pore waters, inhibiting dolomite formation. By regulating the pCO2 and alkalinity, methanogenesis and AMO can regulate the formation of dolomite in organic-rich marine sediments. In addition to providing a mechanistic link between AMO and dolomite formation, our findings provide a method by which the stability constant of dolomite can be calculated in modern sediments and allow prediction of regions and depth domains in which dolomite may be forming.

Description: We examine the circulation of heavy ions of planetary origin within Mercury’s magnetosphere. Using single particle trajectory calculations, we focus on the dynamics of sodium ions, one of the main species that are ejected from the planet’s surface. The numerical simulations reveal a significant population in the near-Mercury environment in the nightside sector, with energetic (several keV) Na + densities that reach several tenths cm-3 at planetary perihelion. At aphelion, a lesser (by about one order of magnitude) density contribution is obtained, due to weaker photon flux and solar wind flux. The numerical simulations also display several features of interest that follow from the small spatial scales of Mercury’s magnetosphere. First, in contrast to the situation prevailing at Earth, ions in the magnetospheric lobes are found to be relatively energetic (a few hundreds of eV), despite the low-energy character of the exospheric source. This results from enhanced centrifugal acceleration during E × B transport over the polar cap. Second, the large Larmor radii in the mid-tail result in the loss of most Na + into the dusk flank at radial distances greater than a few planetary radii. Because gyroradii are comparable to, or larger than, the magnetic field variation length scale, the Na + motion is also found to be non-adiabatic throughout most of Mercury’s equatorial magnetosphere, leading to chaotic scattering into the loss cone or meandering (Speiser-type) motion in the near-tail. As a direct consequence, a localized region of energetic Na + precipitation develops at the planet’s surface. In this region which extends over a wide range of longitudes at mid-latitudes ( ~ 30°–40°), one may expect additional sputtering of planetary material.Key words. Magnetospheric physics (planetary magnetospheres) – Space plasma physics (charged particle motion and acceleration; numerical simulation studies)

Description: In this paper, we present in-situ observations of processes occurring at the magnetopause and vicinity, including surface waves, oscillatory magnetospheric field lines, and flux transfer events, and coordinated observations at geosynchronous orbit by the GOES spacecraft, and on the ground by CANOPUS and 210° Magnetic Meridian (210MM) magnetometer arrays. On 7 February 2002, during a high-speed solar wind stream, the Polar spacecraft was skimming the magnetopause in a post-noon meridian plane for ~3h. During this interval, it made two short excursions and a few partial crossings into the magnetosheath and observed quasi-periodic cold ion bursts in the region adjacent to the magnetopause current layer. The multiple magnetopause crossings, as well as the velocity of the cold ion bursts, indicate that the magnetopause was oscillating with an ~6-min period. Simultaneous observations of Pc5 waves at geosynchronous orbit by the GOES spacecraft and on the ground by the CANOPUS magnetometer array reveal that these magnetospheric pulsations were forced oscillations of magnetic field lines directly driven by the magnetopause oscillations. The magnetospheric pulsations occurred only in a limited longitudinal region in the post-noon dayside sector, and were not a global phenomenon, as one would expect for global field line resonance. Thus, the magnetopause oscillations at the source were also limited to a localized region spanning ~4h in local time. These observations suggest that it is unlikely that the Kelvin-Helmholz instability and/or fluctuations in the solar wind dynamic pressure were the direct driving mechanisms for the observed boundary oscillations. Instead, the likely mechanism for the localized boundary oscillations was pulsed reconnection at the magnetopause occurring along the X-line extending over the same 4-h region. The Pc5 band pressure fluctuations commonly seen in high-speed solar wind streams may modulate the reconnection rate as an indirect cause of the observed Pc5 pulsations. During the same interval, two flux transfer events were also observed in the magnetosphere near the oscillating magnetopause. Their ground signatures were identified in the CANOPUS data. The time delays of the FTE signatures from the Polar spacecraft to the ground stations enable us to estimate that the longitudinal extent of the reconnection X-line at the magnetopause was ~43° or ~5.2 RE. The coordinated in-situ and ground-based observations suggest that FTEs are produced by transient reconnection taking place along a single extended X-line at the magnetopause, as suggested in the models by Scholer (1988) and Southwood et al. (1988). The observations from this study suggest that the reconnection occurred in two different forms simultaneously in the same general region at the dayside magnetopause: 1) continuous reconnection with a pulsed reconnection rate, and 2) transient reconnection as flux transfer events. Key words. Magnetospheric physics (Magnetopause, cusp and boundary layers; Magnetosphere-ionosphere interactions; MHD waves and instabilities)