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  • 1
    facet.materialart.
    Unbekannt
    In:  Proceedings
    Publikationsdatum: 2020-02-12
    Materialart: info:eu-repo/semantics/conferenceObject
    Standort Signatur Erwartet Verfügbarkeit
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  • 2
    facet.materialart.
    Unbekannt
    In:  EPIC318. ICP-MS-Anwendertreffen und 6. Symposium Massenspektrometrische Methoden der Elementspurenanalyse, 06-09 Okt, Berlin, Deutschland.
    Publikationsdatum: 2019-07-17
    Repository-Name: EPIC Alfred Wegener Institut
    Materialart: Conference , notRev
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  • 3
    Digitale Medien
    Digitale Medien
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 69 (1991), S. 6022-6022 
    ISSN: 1089-7550
    Quelle: AIP Digital Archive
    Thema: Physik
    Notizen: We report the first measurements on porphyrin compounds using Eu as the Mössbauer nuclide. There have been many Mössbauer studies on iron porphyrins1,2 and a few on tin.3 We have successfully prepared and made Mössbauer and magnetic susceptibility measurements on four Eu based porphyrin compounds to elucidate the relationship between magnetic properties and structure. Absorption spectra using the 21.6 keV gamma ray of 151Eu were obtained at room temperature and 80 K and yielded very broad singlets with room temperature isomer shift values between 0.20±0.02 mm/s and 0.90±0.02 mm/s with respect to EuF3. Experimental results show the Eu ion to be in the trivalent oxidation state. A discussion of the electronic properties and structure will be reported and compared with previous results found on iron and tin based porphyrins.〈ks〉
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 4
    Digitale Medien
    Digitale Medien
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 85 (1999), S. 5387-5389 
    ISSN: 1089-7550
    Quelle: AIP Digital Archive
    Thema: Physik
    Notizen: The magnetic and structural properties of the bulk manganite Eu2/3Ca1/3MnO3 are characterized using Mössbauer spectroscopy, magnetization measurements, x-ray diffraction, and resistivity measurements. Here it is demonstrated that one can investigate the magnetic properties of manganites using Mössbauer spectroscopy by doping with europium at the rare earth site and using rays from Eu151 as a probe. Mössbauer measurements were performed at several temperatures between 15 and 293 K using a 151Eu source. The spectrum at room temperature is a single line demonstrating paramagnetism with an isomer shift of 0.60±0.02 mm/s. Measurements at room temperature show the Eu to be trivalent and single phase with a linewidth of 2.933±0.004 mm/s, which is comparable to that found for the Mössbauer standard EuF3. Measurements below 100 K show a much broader linewidth which at 15 K is more than twice that found at 293 K and is associated with a magnetic phase transition. Magnetization as a function of magnetic field measurements up to 5 T show the system to be paramagnetic at 300 K and ferromagnetic-like at 50 K. Magnetic susceptibility measurements made between 300 and 4.2 K show the sample to be paramagnetic down to 100 K, where it undergoes a magnetic phase transition. Mössbauer, resistivity, and magnetic measurements all indicate a change in the paramagnetic state around 230 K. © 1999 American Institute of Physics.
    Materialart: Digitale Medien
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  • 5
    Digitale Medien
    Digitale Medien
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 75 (1999), S. 2993-2995 
    ISSN: 1077-3118
    Quelle: AIP Digital Archive
    Thema: Physik
    Notizen: Mössbauer spectroscopy with 57Fe is used to characterize pulsed-laser-deposited (PLD) Ni0.6Zny–Fe2O4 films is demonstrated. Mössbauer spectra were recorded as a function of film thickness (3–16 μm) for films deposited in background O2 pressures of 50 and 200 mTorr, and for a zinc concentration of y=0.72. A spectrum was also recorded for y=0.4 deposited in a background pressure of 200 mTorr. The site occupancy was determined for the tetrahedral (A) and octahedral (B) sites. Results obtained here show that the effect of increasing the Zn is to shift Fe(tet) to Fe(oct). When compared with previous Mössbauer measurements on the bulk NiZn ferrites, the ferrite films give spectra of similar quality with no visible evidence of clustering or multiple phases present. The same linewidth was found for a PLD processed Fe film and a Mössbauer standard 70-μm-thick α-Fe enriched foil. The Fe film had a magnetic hyperfine field of 334 kOe and no evidence of the presence of any iron oxides. Good spectra may be obtained by selecting substrates with low mass and low atomic number. We were successful in obtaining measurable Mössbauer spectra for films deposited on 0.5-mm-thick MgO, sapphire, and alumina substrates whereas films deposited on Si, GaAs, and cubic zirconia substrates did not give good spectra. © 1999 American Institute of Physics.
    Materialart: Digitale Medien
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  • 6
    Digitale Medien
    Digitale Medien
    s.l. : American Chemical Society
    Journal of the American Chemical Society 41 (1919), S. 235-247 
    ISSN: 1520-5126
    Quelle: ACS Legacy Archives
    Thema: Chemie und Pharmazie
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 7
    Digitale Medien
    Digitale Medien
    s.l. : American Chemical Society
    Journal of the American Chemical Society 41 (1919), S. 1013-1020 
    ISSN: 1520-5126
    Quelle: ACS Legacy Archives
    Thema: Chemie und Pharmazie
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 8
    Digitale Medien
    Digitale Medien
    Palo Alto, Calif. : Annual Reviews
    Annual Review of Earth and Planetary Sciences 4 (1976), S. 187-228 
    ISSN: 0084-6597
    Quelle: Annual Reviews Electronic Back Volume Collection 1932-2001ff
    Thema: Geologie und Paläontologie , Physik
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 9
    Digitale Medien
    Digitale Medien
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 81 (1997), S. 5805-5807 
    ISSN: 1089-7550
    Quelle: AIP Digital Archive
    Thema: Physik
    Notizen: Mechanical alloying of Sm and Fe with the composition of SmFe3 was studied using x-ray-diffraction (XRD), Mössbauer, and magnetization measurements. Data taken as a function of milling time for up to 20 h show significant changes occurring during ball milling. The XRD studies show that the initial crystalline Bragg reflections changed to a broad maximum, which is attributed to the formation of an amorphous phase. The initial six-line pattern in the Mössbauer spectrum, characteristic of magnetic ordering, changed to a broad singlet, characteristic of a nonmagnetic material. Magnetization measurements revealed that the coercive field was at its maximum after 5 h of milling and decreased sharply as the milling time increased. The remanent magnetization was at its maximum between 5 and 10 h of milling. The final product of the ball milling, which exhibited the characteristics of an amorphous paramagnetic material in its XRD and Mössbauer spectrum, was studied after heat treatment. The XRD and the Mössbauer spectra of the heat treated alloy show that substantial changes occurred during heat treatment in that sharp Bragg reflections, characteristic of crystalline materials, reappear and the alloy changed from a paramagnetic to a ferromagnetic state. © 1997 American Institute of Physics.
    Materialart: Digitale Medien
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  • 10
    facet.materialart.
    Unbekannt
    Canberra : Periodicals Archive Online (PAO)
    Quarterly review of the rural economy. 5:1 (1952:Jan.) 12 
    ISSN: 0156-7446
    Thema: Land- und Forstwirtschaft, Gartenbau, Fischereiwirtschaft, Hauswirtschaft , Wirtschaftswissenschaften
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