ALBERT

Description: We have been working on the development of thin film photovoltaic solar cell materials that can be produced entirely by wet chemical methods on low-cost flexible substrates. P-type copper indium diselenide (CIS) absorber layers have been deposited via electrochemical deposition. Similar techniques have also allowed us to incorporate both Ga and S into the CIS structure, in order to increase its optical bandgap. The ability to deposit similar absorber layers with a variety of bandgaps is essential to our efforts to develop a multi-junction thin-film solar cell. Chemical bath deposition methods were used to deposit a cadmium sulfide (CdS) buffer layers on our CIS-based absorber layers. Window contacts were made to these CdS/CIS junctions by the electrodeposition of zinc oxide (ZnO). Structural and elemental determinations of the individual ZnO, CdS and CIS-based films via transmission spectroscopy, x-ray diffraction, x-ray photoelectron spectroscopy and energy dispersive spectroscopy will be presented. The electrical characterization of the resulting devices will be discussed.

Description: Separation control by means of steady suction or zero efflux oscillatory jets is known to be effective in a wide variety of flows under different flow conditions. Control is effective when applied in a nominally two-dimensional manner, for example, at the leading-edge of a wing or at the shoulder of a deflected flap. Despite intuitive understanding of the flow, at present there is no accepted theoretical model that can adequately explain or describe the observed effects of the leading parameters such as reduced suction-rate, or frequency and momentum input. This difficulty stems partly from the turbulent nature of the flows combined with superimposed coherent structures, which are usually driven by at least one instability mechanism. The ever increasing technological importance of these flows has spurned an urgent need to develop turbulence models with a predictive capability. Present attempts to develop such models are hampered in one way or another by incomplete data sets, uncertain or undocumented inflow and boundary conditions, or inadequate flow-field measurements. This paper attempts to address these issues by conducting an experimental investigation of a lowspeed separated flow over a wall-mounted hump model. The model geometry was designed by Seifert & Pack, who measured static and dynamic pressures on the model for a wide range of Reynolds and Mach numbers and control conditions. This paper describes the present experimental setup, as well as the types and range of data acquired. Sample data is presented and future work is discussed.

Description: An oscillatory jet with zero net mass flow is generated by a cavity-pumping actuator. Among the three test cases selected for the Langley CFD validation workshop to assess the current CFD capabilities to predict unsteady flow fields, this basic oscillating jet flow field is the least complex and is selected as the first test case. Increasing in complexity, two more cases studied include jet in cross flow boundary layer and unsteady flow induced by suction and oscillatory blowing with separation control geometries. In this experiment, velocity measurements from three different techniques, hot-wire anemometry, Laser Doppler Velocimetry (LDV) and Particle Image Velocimetry (PIV), documented the synthetic jet flow field. To provide boundary conditions for computations, the experiment also monitored the actuator operating parameters including diaphragm displacement, internal cavity pressure, and internal cavity temperature.

Description: Preferential oriented multiwalled carbon nanotubes were prepared by the injection chemical vapor deposition (CVD) method using either cyclopentadienyliron dicarbonyl dimer or cyclooctatetraene iron tricarbonyl as the iron catalyst source. The catalyst precursors were dissolved in toluene as the carrier solvent for the injections. The concentration of the catalyst was found to influence both the growth (i.e., MWNT orientation) of the nanotubes, as well as the amount of iron in the deposited material. As deposited, the multiwalled carbon nanotubes contained as little as 2.8% iron by weight. The material was deposited onto tantalum foil and fused silica substrates. The nanotubes were characterized by scanning electron microscopy, transmission electron microscopy, Raman spectroscopy and thermogravimetric analysis. This synthetic route provides a simple and scalable method to deposit MWNTs with a low defect density, low metal content and a preferred orientation. Subsequently, a small start-up was founded to commercialize the deposition equipment. The contrast between the research and entrepreneurial environments will be discussed.

Description: Ten dithiocarbamate complexes of indium(III) and gallium(III) have been prepared and characterized by elemental analysis, infrared spectra and melting point. Each complex was decomposed thermally and its decomposition products separated and identified with the combination of gas chromatography/mass spectrometry. Their potential utility as photovoltaic materials precursors was assessed. Bis(dibenzyldithiocarbamato)- and bis(diethyldithiocarbamato)copper(II), Cu(S2CN(CH2C6H5)2)2 and Cu(S2CN(C2H5)2)2 respectively, have also been examined for their suitability as precursors for copper sulfides for the fabrication of photovoltaic materials. Each complex was decomposed thermally and the products analyzed by GC/MS, TGA and FTIR. The dibenzyl derivative complex decomposed at a lower temperature (225-320 C) to yield CuS as the product. The diethyl derivative complex decomposed at a higher temperature (260-325 C) to yield Cu2S. No Cu containing fragments were noted in the mass spectra. Unusual recombination fragments were observed in the mass spectra of the diethyl derivative. Tris(bis(phenylmethyl)carbamodithioato-S,S'), commonly referred to as tris(N,N-dibenzyldithiocarbamato)indium(III), In(S2CNBz2)3, was synthesized and characterized by single crystal X-ray crystallography. The compound crystallizes in the triclinic space group P1(bar) with two molecules per unit cell. The material was further characterized using a novel analytical system employing the combined powers of thermogravimetric analysis, gas chromatography/mass spectrometry, and Fourier transform infrared (FT-IR) spectroscopy to investigate its potential use as a precursor for the chemical vapor deposition (CVD) of thin film materials for photovoltaic applications. Upon heating, the material thermally decomposes to release CS2 and benzyl moieties in to the gas phase, resulting in bulk In2S3. Preliminary spray CVD experiments indicate that In(S2CNBz2)3 decomposed on a Cu substrate reacts to produce stoichiometric CuInS2 films.