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  • 1
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    Changes in fluid geochemistry and physico-chemical conditions of geothermal systems caused by magmatic input: The recent abrupt outgassing off the island of Panarea (Aeolian Islands, Italy) (2005)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: Hydrothermal systems and related vents can exhibit dramatic changes in their physico-chemical conditions over time as a response to varying activity in the feeding magmatic systems. Massive steam condensation and gas scrubbing processes of thermal fluids during their ascent and cooling cause further compositional changes that mask information regarding the conditions evolving at depth in the hydrothermal system. Here we propose a new stability diagram based on the CO2-CH4-CO-H2 concentrations in vapor, which aims at calculating the temperatures and pressures in hydrothermal reservoirs. To filter gas scrubbing effects, we have also developed a model for selective dissolution of CO2-H2S-N2-CH4-He-Ne mixtures in fresh and/or air-saturated seawater. This methodology has been applied to the recent (November 2002) crisis that affected the geothermal field off the island of Panarea (Italy), where the fluid composition and fluxes have been monitored for the past two decades. The chemical and isotopic compositions of the gases suggest that the volatile elements originate from an active magma, which feeds a boiling saline solution having temperatures of up to 350 C and containing 12 mol CO2 in vapor. The thermal fluids undergo cooling and re-equilibration processes on account of gas-water-rock interactions during their ascent along fracture networks. Furthermore, steam condensation and removal of acidic species, partial dissolution in cold air-saturated seawater and stripping of atmospheric components, affect the composition of the geothermal gases at shallow levels. The observed geochemical variations are consistent with a new input of magmatic fluids that perturbed the geothermal system and caused the unrest event. The present-state evolution shows that this dramatic input of fluids is probably over, and that the system is now tending towards steady-state conditions on a time scale of months.
    Description: Published
    Description: 3045-3059
    Description: partially_open
    Keywords: Submarine degassing ; geothermal system ; gas-water interaction ; gas geothermometry ; 04. Solid Earth::04.01. Earth Interior::04.01.02. Geological and geophysical evidences of deep processes ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.04. Thermodynamics ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 2
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    Inferences on physico-chemical conditions and gas-water interaction by new quantitative approaches: The case of Panarea (Italy) (2008)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: We have developed two new quantitative approaches to calculate temperatures in hydrothermal reservoirs by using the CO2-CH4-CO-H2 gaseous system and to model selective dissolution of CO2-H2S-N2-CH4-He-Ne mixtures in fresh and/or air saturated seawater. The anomalous outgassing starting November 2003 from the submarine exhalative system offshore Panarea island (Italy), was the occasion to apply such approaches to the extensive collection of volcanic gases. Gas geothermometry suggest the presence of a deep geothermal system at temperature up to 350°C and about 12 mol% CO2 in the vapor, which feeds the submarine emissions. Based on the fractional dissolution model, the rising geothermal vapor interacts with air-saturated seawater at low depths, dissolving 30-40% CO2 and even more H2S, modifying the pH of the aqueous solution and stripping the dissolved atmospheric volatiles (N2, Ne). Interaction of the liquid phase of the thermal fluids with country rocks, as well extensive mixing with seawater, have been also recognized and quantified. The measured output of hydrothermal fluids from Panarea exhalative field [1] accounts for the involvement of volatiles from an active degassing magma, nonetheless the climax of the investigated phenomenon is probably overcome and the system is new tending towards a steady-state. Our quantitative approaches allow us to monitor the geochemical indicators of the geothermal physico-chemical conditions and their potential evolution towards phreatic events or massive gas releases, which certainly are the main hazards to be expected in the area. The event at Panarea has in fact highlighted how hydrothermal systems can exhibit dramatic and sudden changes of their physico-chemical conditions and rate of fluid release, as a response to variable activity of feeding magmatic systems.
    Description: Published
    Description: Copenhagen
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: open
    Keywords: Submarine ; geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: Extended abstract
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  • 3
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    The 2002–2003 eruption of Stromboli (Italy): Evaluation of the volcanic activity by means of continuous monitoring of soil temperature, CO2 flux, and meteorological parameters (2005)
    American Geophysical Union
    Details
    Publication Date: 2017-04-04
    Description: From December 2002 to July 2003, Stromboli volcano was characterized by a new effusive stage of eruption after a period of extraordinary strombolian activity. Signals recorded in two continuous monitoring stations during the eruption, which have already been presented in very recent papers, evidenced anomalies in the CO2 flux just before the onset of the eruption. A more detailed analysis carried out on the data subset acquired during the eruption, integrated by daily field observations of the scientific personnel working at the volcanological observatory in Stromboli, showed that CO2 flux and soil temperature are strictly related to volcanic events. Furthermore, the relative minima and maxima of the two parameters showed a strong correlation with wind speed and direction. This fact was especially true at the summit station, whereas at the coastal sites seasonal and meteorological effects masked the volcanic signal. The analysis of the wind data, particularly the relationships between wind speed and direction, air and soil temperature, and local circulation of atmospheric air masses revealed that during the eruption, in the summit area of Stromboli air movements were not only related to atmospheric circulation but were also significantly affected, and in certain cases caused, by volcanic activity. This conclusion was reached by observing several anomalies, such as the discrepancies in the wind direction between the two stations, higher air temperatures at the summit site, and inversion of direction for wind before and after the reopening of the conduit in a major explosion on 5 April 2003. The relationships found between volcanic activity, soil temperatures, CO2 fluxes, and wind speed and direction indicate that soil temperature measurements, in an open conduit volcano such as in this case, could be used to monitor the level of volcanic activity, along with CO2 flux. Furthermore, the possible volcanic origin of a peculiar type of air circulation identified in the summit area of Stromboli suggests that the separation between volcanic and atmospheric signals might not be obvious, requiring monitoring over a wide area, rather than a single location.
    Description: Published
    Description: Q12001
    Description: partially_open
    Keywords: carbon dioxide flux ; continuous monitoring ; soil temperature ; wind ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 05. General::05.02. Data dissemination::05.02.03. Volcanic eruptions ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 4
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    Geochemical precursors of the activity of an open-conduit volcano: The Stromboli 2002-2003 eruptive events (2005)
    American Geophysical Union
    Details
    Publication Date: 2017-04-04
    Description: Marked increases of CO2, H2 and He dissolved in thermal waters and changes in the dissolved carbon isotopic composition, were observed at Stromboli before the 28 December 2002 eruption and before a violent explosive paroxysm occurred on 5 April 2003. High anomalous CO2 flux values were recorded at the crater rim since a week before the eruption onset. The first anomalies in the thermal waters (dissolved CO2 amount) appeared some months before the eruption, when magma column rose at a very high level in the conduit. High peaks of dissolved H2 and He were recorded a few days before the paroxysm. Carbon isotopic composition indicates a magmatic origin of the dissolved CO2 whose increase, together with those of H2 and He, is attributed to an increasing output of deep gases likely produced by depressurization of a rising batch of a deep gas-rich magma, whose fragments have been emitted during the explosion.
    Description: Italian Civil Protection
    Description: Published
    Description: L07620
    Description: partially_open
    Keywords: Stromboli ; geochemical precursors ; CO2 flux ; pH ; 03. Hydrosphere::03.04. Chemical and biological::03.04.03. Chemistry of waters ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data ; 05. General::05.02. Data dissemination::05.02.03. Volcanic eruptions ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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    Format: 503 bytes
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  • 5
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    Geochemical evaluation of observed changes in volcanic activity during the 2007 eruption at Stromboli (Italy) (2009)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: On February 27, 2007 a new eruption started at Stromboli that lasted until April 2 and included a paroxysmal explosion on March 15. Geochemical monitoring carried out over several years revealed some appreciable variations that preceded both the eruption onset and the explosion. The carbon dioxide (CO2) flux from the soil at Pizzo Sopra La Fossa markedly increased a few days before the eruption onset, and continued during lava effusion to reach its maximum value (at 90,000 g m−2 d−1) a few days before the paroxysm. Almost contemporarily, the δ13CCO2 of the SC5 fumarole located in the summit area increased markedly, peaking just before the explosion (δ13CCO2~−1.8‰). Following the paroxysm, helium (He) isotopes measured in the gases dissolved in the basal thermal aquifer sharply increased. Almost contemporarily, the automatic station of CO2 flux recorded an anomalous degassing rate. Also temperatures and the vertical thermal gradient, which had been measured since November 2006 in the soil at Pizzo Sopra La Fossa, showed appreciable variabilities that lasted until the end of the eruption. The geochemical variations indicated the degassing of a new batch of volatile-rich magma that preceded and probably fed the paroxysm. The anomalous 3He/4He ratio suggested that the ascent of a second batch of volatile-rich magma toward the surface was probably responsible of the resumption of the ordinary activity. A comparison with the geochemical variations observed during the 2002–2003 eruption indicated that the 2007 eruption was less energetic.
    Description: Published
    Description: 246-254
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: JCR Journal
    Description: reserved
    Keywords: geochemistry ; eruption ; dissolved gases ; Stromboli ; volcanic activity ; 03. Hydrosphere::03.02. Hydrology::03.02.03. Groundwater processes ; 03. Hydrosphere::03.04. Chemical and biological::03.04.03. Chemistry of waters ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data ; 05. General::05.02. Data dissemination::05.02.03. Volcanic eruptions
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 6
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    Evidence of a recent input of magmatic gases into the quiescent volcanic edifice of Panarea, Aeolian Islands, Italy (2005)
    American Geophysical Union
    Details
    Publication Date: 2017-04-04
    Description: On 2nd/3rd November 2002, a huge amount of gas, mainly composed of CO2, was suddenly released from the sea bottom off the coast of Panarea, producing a ‘‘crater’’20 by 10 meters wide and 7 meters deep. The gas output was estimated to be 109 l/d, two orders of magnitude higher than that measured in the 1980s. The anomalous degassing rate lasted for some weeks, slowly decreasing to an almost constant rate of about 4 x 107 l/d after two months. The geothermo- barometric estimations revealed an increase of both the temperature and pressure in the geothermal system feeding the sampled vents. The 3He/4He ratios were similar to those measured in nearby Stromboli. We have monitored the area for the last two decades, and based on our intensive and extensive geochemical measurements, have ascertained that the geothermal reservoir has lost its steady state. We maintain that a new magmatic input caused these phenomena.
    Description: - Istituto Nazionale di Geofisica e Vulcanologia, Osservatorio Vesuviano, Naples, Italy. - Istituto Nazionale di Geofisica e Vulcanologia, Sezione di Palermo, Palermo, Italy. - Dipartimento Chimica e Fisica della Terra ed Applicazioni, Palermo, Italy.
    Description: Published
    Description: L07619
    Description: partially_open
    Keywords: Submarine degassing ; magmatic fluids ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.04. Thermodynamics ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 7
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    Major-ion bulk deposition around an active volcano (Mt. Etna, Italy) (2007)
    Springer
    Details
    Publication Date: 2017-04-04
    Description: Bulk atmospheric deposition of major cations (Na, K, Ca, Mg) and anions (Cl, F, SO4) were measured at 15 sites around an active volcano, Mount Etna, from 2001 to 2003. Their composition indicates several natural sources, among which deposition of plume-derived volcanogenic gas compounds is prevalent for F, Cl and S. Plume-derived acidic compounds are also responsible for the prevailing acidic composition of the samples collected on the summit of the volcano (pH in the 2.45–5.57 range). Cation species have complex origin, including deposition of plume volcanogenic ash and aerosols and soil-dust wind re-suspension of either volcanic or carbonate sedimentary rocks. Variation of the deposition rates during the March 2001– March 2003 period, coupled with previous measurements from 1997 to 2000 (Appl Geochem 16:985–1000, 2001), were compared with the variation of SO2 flux, volcanic activity and rainfall. The deposition rate was mainly controlled by rainfall. Commonly, about 0.1–0.9% of HF, HCl and SO2 emitted by the summit crater’s plume were deposited around the volcano. We estimate that ∼2 Gg of volcanogenic sulphur were deposited over the Etnean area during the 2002–2003 flank eruption, at an average rate of ∼24 Mg day−1 which is two orders of magnitude higher than that typical of quiescent degassing phases.
    Description: Published
    Description: 255-265
    Description: JCR Journal
    Description: open
    Keywords: Volcanic degassing ; Etna volcano ; Impact of volcanic eruptions ; S deposition rates ; Halogen deposition rates ; Bulk deposition chemistry ; Environmental volcanology ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 8
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    The 5 April 2003 paroxysm at Stromboli: a review of geochemical observations (2008)
    American Geophysical Union
    Details
    Publication Date: 2018-02-01
    Description: This paper reviews the published geochemical variations observed during the 2002–2003 eruption at Stromboli volcano. At the end of 2002, a new eruption began at Stromboli with a lava flow that lasted until the end of July 2003. On 5 April 2003 an explosive paroxysm occurred with the ejection of bombs that reached the village of Ginostra, about 4 km from the craters. During the eruption, specific variations in chemical composition of ground waters and summit fumaroles were recorded before the explosion, most of them for the first time. The water pH decreased significantly (0.5 units) and the dissolved CO2 increased in two thermal wells (Cusolito and Zurro) located near Stromboli harbor from March until 5 April. Peaks in the dissolved He were also observed at all the sampling sites. All of these changes in the thermal aquifer suggested a pressurization of the system due to the degassing of a volatile-rich magma at depth. In the summit area the SO2/HCl and SO2/HF ratios in the plume increased suddenly between 1 and 3 April due to the degassing of an S-rich magma that was approaching the shallow levels of the plumbing system, and this was involved in the explosion that occurred a few days later. This eruption was the first at Stromboli to be analyzed using geochemical models. The variations observed in the basal aquifer and in the summit area occurred on very different timescales: a few weeks and few days, respectively.
    Description: Published
    Description: 347-358
    Description: 2V. Struttura e sistema di alimentazione dei vulcani
    Description: open
    Keywords: paroxysm ; geochemical observations ; monitoring ; plume ; thermal aquifer ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: book chapter
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