ISSN:
0044-2313
Keywords:
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Description / Table of Contents:
Mass Spectroscopic Observed Oxidechloride ComplexesMass spectroscopic observations have shown, that numerous molecules of oxide (and hydroxide) chlorides of aluminium are formed, when gaseous AlCl3(Al2Cl6) reacts with the quartz or glass wall.Also fragments of the molecules MAl3OCl9 (M = Ca, V, Cr, Co, Cu) and M′AlOCl6 (M′ = Nb, Ta, Mo) have been observed. Moreover other fragments can be explained by the existence of the molecules TiAl2OCl6, VAl2OCl6 and PbAl2OCl6.
Notes:
Massenspektroskopische Beobachtungen haben gezeigt, daß zahlreiche Molekeln von Oxid- (und Hydroxid-)chloriden des Aluminiums entstehen, wenn gasförmiges AlCl3(Al2Cl6) mit der Quarz- oder Glaswand reagiert.Ferner wurden Fragmente der Molekeln MAl3OCl9 (M = Ca, V, Cr, Co, Cu) und M′AlOCl6 (M′ = Nb, Ta, Mo) beobachtet. Auch deuten Fragmente auf die möglichen Molekeln TiAl2OCl6, VAl2OCl6 und PbAl2OCl6 hin.
Additional Material:
1 Tab.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/zaac.19814770604
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