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  • 1
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 461 (1980), S. 31-34 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: CuAl2Cl8. Preparation and Crystal Structure.Crystals of CuAl2Cl8 have been prepared. Their remission spectrum agrees with that of gaseous CuAl2Cl8. The crystal structure (P21/c;a = 6.614, b = 7.376, c = 12.319 Å; β = 94.11°) shows a molecular lattice with Cu in square planar coordination, which is completed to a stretched octahedron (as in solid CuCl2) by two Cl atoms from neighbour molecules. Al has tetrahedral coordination.
    Notes: Kristalle von CuAl2Cl8 wurden hergestellt. Ihr Remissionsspektrum entspricht dem von gasförmigem CuAl2Cl8. Die Kristallstruktur der Verbindung (Raumgruppe P21/c) führt mit den Gitterkonstanten a = 6,614, b = 7,376, c = 12,319 Å; β = 94.11° zu einem Molekelgitter mit quadratisch planar von Cl umgebenem Cu. Durch Cl von Nachbarmolekeln wird die Cu-Koordination (wie im festen CuCl2)zu einem langgestreckten Oktaeder ergänzt. Al ist tetraedrisch von Cl umgeben.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
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