ISSN:
1089-7690
Source:
AIP Digital Archive
Topics:
Physics
,
Chemistry and Pharmacology
Notes:
Using laser induced fluorescence detection of metastable H2(c 3Π−u, v=0–3, N=1–4) molecules in a beam at different distances from the source, the lifetime of resolved fine structure levels was determined. It was found to be much shorter for the F2 levels (∼150–10 μs for v=0–3, respectively) than for the F1 plus F3 components (several hundred to 70 μs). This is due to a forbidden (ΔN≠0) predissociation by the b 3Σ+u state, which operates preferentially on the F2 levels. Accurate bound–free Franck–Condon factor calculations reproduce the increasing trend of the predissociation rate in going from v=0–3. The absolute predissociation rates from previous theoretical work, however, can only be brought into agreement with the experimental results if they are multiplied with a common scale factor of 38.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1063/1.466729
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