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  • 1
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    Tidal modulation of Sr/Ca ratios in a Pacific reef coral (2010)
    American Geophysical Union
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    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2004. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geophysical Research Letters 31 (2004): L16310, doi:10.1029/2004GL020600.
    Description: The strontium-to-calcium ratio (Sr/Ca) of reef coral skeleton is an important tool for reconstructing past sea surface temperatures (SSTs). However, the accuracy of paleoSSTs derived from fossil coral Sr/Ca is challenged by evidence that physiological processes influence skeletal chemistry. Here we show that water level variations from tidal forcing are correlated with changes in coral Sr/Ca that cannot be accounted for by changes in SST. Ion microprobe measurements of Sr/Ca ratios in a Pacific Porites lutea reveal high-frequency variations at periods of ~6, ~10, and ~25 days. The relationship between Sr/Ca and temperature on these short timescales does not follow trends observed at longer periods, indicating that an additional forcing is required to explain our observations. We demonstrate that Sr/Ca is correlated with both tidal water level variations and SST, and that their contributions to the Sr/Ca content of the skeleton vary as a function of period. We propose that water level influences Sr/Ca indirectly via modulation of photosynthetically-active radiation (PAR) that drives large changes in zooxanthellate photosynthesis.
    Description: This research was supported by WHOI Ocean Life Institute grant 25051316 to ALC; NSF grants EAR-9628749 and EAR-9904400 to the WHOI Northeast National Ion Microprobe Facility; DAMD 17-93-J-3052 supported ALC’s fieldwork on JA.
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  • 2
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    Microearthquake patterns following the 1998 eruption of Axial Volcano, Juan de Fuca Ridge : mechanical relaxation and thermal strain (2010)
    American Geophysical Union
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    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2004. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research 109 (2004): B01101, doi:10.1029/2003JB002499.
    Description: Ocean bottom seismic networks deployed following the 1998 eruption of Axial seamount reveal an evolving pattern of microearthquake activity associated with subsurface magmatism and thermal strain. Seismicity rates decay steadily over 15 months of observation (February 8, 1998, to April 30, 1999), consistent with a trend toward thermal and mechanical equilibrium in the shallow crust after the magmatic event. Immediately after the eruption, seismicity rates were high for about 60 days in the southeast corner of the caldera where lava flows from the 1998 eruption were mapped. A small burst of seismic activity was observed on the southeast shoulder of the volcano from 100 to 150 days after the eruption. These events, which are characterized by slip on nearly vertical faults in the shallow crust, extend about 6 km from the southeast corner of the caldera and overlie a mid-crustal low-velocity zone. After this episode, seismicity rates remain low until the end of the observation period, 455 days after the eruption. Shallow (~0.7 km depth) events, consistent with thermal contraction and volume changes of ~2 × 10−3 m3 in ~5 m3 sources, are observed in individual clusters beneath hydrothermal vents within the 1998 lava flow at the southeast edge of the caldera. Microearthquakes observed during the last 70 days of observation are distributed around the central caldera, most likely representing small amounts of subsidence on caldera faults during the final stages of equilibration following melt withdrawal associated with the 1998 eruption.
    Description: Sohn, Webb, and the field program were supported by NSF grant OCE 97- 11700. Barclay was supported in part by the Woods Hole Oceanographic Institution.
    Keywords: Microearthquakes ; Hydrothermal ; Magmatism
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  • 3
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    Fine-scale seismic structure of the shallow volcanic crust on the East Pacific Rise at 9°50′N (2010)
    American Geophysical Union
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    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2004. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research 109 (2004): B12104, doi:10.1029/2004JB003152.
    Description: We use a combination of body wave and interface wave observations from an on-bottom seismic refraction survey to constrain the fine-scale seismic structure of the upper crust in a ∼3 × 3 km field area centered on the East Pacific Rise at 9°50′N. We detonated 18 explosive shots (18 sources) in a circular pattern (1.5 km radius) on the rise axis and recorded seismic arrivals with eight ocean bottom seismometers (eight receivers). We observed 30–40 Hz compressional body waves from all shots (144 P waves) and 1–3 Hz Stoneley (interface) waves on a subset of source-receiver pairs (58 interface waves). Using a station correction inversion, we find that roughly half of the variance in the P wave first-arrival times results from lateral variations in the thickness of the surface low-velocity layer (SLVL), a layer of extremely porous lava and basalt breccia with an average P wave velocity of 2.2 km s−1. The SLVL thickness increases from 〈20 m along the axial summit trough (AST) to ∼120 m at near-axis lava depocenters, which are not symmetric about the rise axis. Depocenters are located ∼0.5 km to the west and ∼1.5 km to the east of the rise axis. Tomographic inversion of the Stoneley wave first arrivals reveals that shear velocities in the SLVL covary with the layer thickness, exhibiting a similar asymmetric pattern, with shear velocities increasing from ∼320 m s−1 near the AST to ∼520 m s−1 at the near-axis depocenters. Our analysis demonstrates that the seismic characteristics of the extrusive layer near the rise axis are related primarily to volcanic features and processes. The thickness and velocity of the SLVL are low on the axis and within channel networks that deliver lava flows away from the axis and then increase rapidly at the distal ends of the channels where the lavas are deposited. We find that azimuthal anisotropy exerts only a weak influence on our P wave first-arrival times, which we model as weak (4%) seismic azimuthal anisotropy in the upper dikes with a fast axis oriented N23°–32°W. We find no evidence for seismic azimuthal anisotropy in the extrusive layer.
    Keywords: Volcanic ; Seismic ; Structure
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  • 4
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    Analysis and modeling of hydrothermal plume data acquired from the 85°E segment of the Gakkel Ridge (2010)
    American Geophysical Union
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    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2010. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research 115 (2010): C06028, doi:10.1029/2009JC005776.
    Description: We use data from a CTD plume-mapping campaign conducted during the Arctic Gakkel Vents (AGAVE) expedition in 2007 to constrain the nature of hydrothermal processes on the Gakkel Ridge at 85°E. Thermal and redox potential (Eh) anomalies were detected in two discrete depth intervals: 2400–2800 m (Interval 1) and 3000–3800 m (Interval 2). The spatial and temporal patterns of the signals indicate that the Interval 1 anomalies were most likely generated by a single large, high-temperature (T 〉 100°C) vent field located on the fault terraces that form the NE axial valley wall. In contrast, the Interval 2 anomalies appear to have been generated by up to 7 spatially distinct vent fields associated with constructional volcanic features on the floor of the axial valley, many of which may be sites of diffuse, low-temperature (T 〈 10°C) discharge. Numerical simulations of turbulent plumes rising in a weakly stratified Arctic Ocean water column indicate that the high-temperature field on the axial valley wall has a thermal power of ∼1.8 GW, similar to the Trans-Atlantic Geotraverse and Rainbow fields in the Atlantic Ocean, whereas the sites on the axial valley floor have values ranging from 5 to 110 MW.
    Description: Thiswork was funded by the NSF Office of Polar Programs, Tellus—The Centre of Earth Systems Science at theUniversity of Gothenburg, and the Woods Hole Oceanographic Institution.
    Keywords: Hydrothermal plumes ; Gakkel Ridge ; Hydrothermal vents
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  • 5
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    Stochastic analysis of exit fluid temperature records from the active TAG hydrothermal mound (Mid-Atlantic Ridge, 26°N) : 2. Hidden Markov models of flow episodes (2010)
    American Geophysical Union
    Details
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2007. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research 112 (2007): B09102, doi:10.1029/2007JB004961.
    Description: I develop a stochastic signal model for episodic modes of variability in hydrothermal flow records using probabilistic functions of Markov processes (i.e., hidden Markov models, HMMs) and fit the model to exit fluid temperature time series data from diffuse flow sites on the active TAG hydrothermal mound. The flow states are modeled using Gamma densities to provide flexibility for application to a range of signal types. Between three and five flow states are needed to fit the diffuse flow temperature records from TAG, which correspond to models with between 10 and 28 degrees of freedom. The number of flow states required to fit a given record is related to the signal variance, with more variable records requiring a larger state space. HMMs thus provide an efficient signal model for episodic variability in hydrothermal flow records, suggesting that Markov processes may provide a means to generate stochastic subsurface flow models for deep-sea hydrothermal fields if the spatial flow correlations can be incorporated into a statistical framework. I also use the Viterbi algorithm to “decode” the time series data into best fitting state sequences, which can be used to classify the records into discrete flow episodes. This may provide an objective means to identify discrete events in a flow record if misclassification issues arising from nonepisodic variability (e.g., tidal forcing) can be addressed.
    Description: This work was supported by the National Science Foundation (OCE-0137329).
    Keywords: Hydrothermal flow ; Hidden Markov models
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  • 6
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    A method for inverting ratio–ratio data to estimate end-member compositions in mixing problems (2013)
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    Publication Date: 2022-05-25
    Description: Author Posting. © The Author(s), 2013. This is the author's version of the work. It is posted here by permission of Elsevier B.V. for personal use, not for redistribution. The definitive version was published in Chemical Geology 352 (2013): 63–69, doi:10.1016/j.chemgeo.2013.06.002.
    Description: I discuss the general problem of fitting mixing models to ratio-ratio data, and derive formulae for applying non-linear Maximum Likelihood methods for parameter estimation. To estimate mixing model parameters in the under-determined inversion it is necessary to introduce prior constraints, which I implement by penalizing the likelihood function for variations from a starting model. I illustrate practical aspects of the inverse problem by applying the method to synthetic data for a ternary system of putative mantle reservoirs using Sr, Nd, and Pb isotope ratios. I fit the synthetic data using two different starting models to demonstrate the sensitivity of the gradient method used to solve the non-linear inverse to the starting model and the necessity of inspecting the final model to avoid spurious results. I include Matlab scripts to facilitate starting model selection and to perform binary and ternary ratio-ratio inversions as an Electronic Appendix.
    Repository Name: Woods Hole Open Access Server
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  • 7
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    Crustal structure of the Trans-Atlantic Geotraverse (TAG) segment (Mid-Atlantic Ridge, 26°10′N) : implications for the nature of hydrothermal circulation and detachment faulting at slow spreading ridges (2010)
    American Geophysical Union
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    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2007. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geochemistry Geophysics Geosystems 8 (2007): Q08004, doi:10.1029/2007GC001629.
    Description: New seismic refraction data reveal that hydrothermal circulation at the Trans-Atlantic Geotraverse (TAG) hydrothermal field on the Mid-Atlantic Ridge at 26°10′N is not driven by energy extracted from shallow or mid-crustal magmatic intrusions. Our results show that the TAG hydrothermal field is underlain by rocks with high seismic velocities typical of lower crustal gabbros and partially serpentinized peridotites at depth as shallow as 1 km, and we find no evidence for low seismic velocities associated with mid-crustal magma chambers. Our tomographic images support the hypothesis of Tivey et al. (2003) that the TAG field is located on the hanging wall of a detachment fault, and constrain the complex, dome-shaped subsurface geometry of the fault system. Modeling of our seismic velocity profiles indicates that the porosity of the detachment footwall increases after rotation during exhumation, which may enhance footwall cooling. However, heat extracted from the footwall is insufficient for sustaining long-term, high-temperature, hydrothermal circulation at TAG. These constraints indicate that the primary heat source for the TAG hydrothermal system must be a deep magma reservoir at or below the base of the crust.
    Description: This research was supported by NSF grant OCE-0137329.
    Keywords: TAG hydrothermal field ; Crustal structure ; Detachment faulting ; Mid-Atlantic Ridge ; Slow spreading ridge
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  • 8
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    238U-Th-230-Ra-226-Pb-210-Po-210, Th-232-Ra-228, and U-235-Pa-231 constraints on the ages and petrogenesis of Vailulu'u and Malumalu Lavas, Samoa (2010)
    American Geophysical Union
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    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2008. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geochemistry Geophysics Geosystems 9 (2008): Q04003, doi:10.1029/2007GC001651.
    Description: We report 238U-230Th-226Ra-210Pb-210Po, 232Th-228Ra and 235U-231Pa measurements for a suite of 14 geologically and geochemically well-characterized basaltic samples from the Samoan volcanoes Vailulu'u, Malumalu, and Savai'i. Maximum eruption ages based on the presence of parent-daughter disequilibria indicate that Vailulu'u is magmatically productive with young lavas (〈8 Ka) resurfacing both its summit crater and lower flanks. 210Pb and 210Po measurements indicate that several flows have erupted within its summit crater in the past 100 years, with the newest observed flow being erupted in November of 2004. For lavas which have eruption ages that are demonstrably young, relative to the half-lives of 230Th, 231Pa, and 226Ra, we interpret their 238U -230Th, 235U-231Pa and 230Th - 226Ra disequilibria in terms of the magmatic processes occurring beneath the Samoan Islands. (230Th/238U) 〉 1 indicates that garnet is required as a residual phase in the magma sources for all these lavas. The large range of (238U/232Th) and (230Th/232Th) is attributed to long-term source variation. The Samoan basalts are all alkaline basalts and show significant 230Th and 231Pa excesses but limited variability, indicating that they have been derived by small but similar extents of melting. Their (230Th/238U), (231Pa/235U) and Sm/Nd fractionation are consistent with correlations among other ocean island basalt suites (particularly Hawaii) which show that (230Th/238U) and (231Pa/235U) of many OIBS can be explained by simple time-independent models. Interpretation of the 226Ra data requires time-dependent melting models. Both chromatographic porous flow and dynamic melting of a garnet peridotite source can adequately explain the combined U-Th-Ra and U-Pa data for these Samoan basalts. Several young samples from the Vailulu'u summit crater also exhibit significant 210Pb deficits that reflect either shallow magmatic processes or continuous magma degassing. In both cases, decadal residence times are inferred from these 210Pb deficits. The young coeval volcanism on Malumalu and Vailulu'u suggests the Samoa hot spot is currently migrating to the northeast due to dynamic interaction with the Tonga slab.
    Description: Support for this research was provided by NSF grants EAR-9909473 (KWWS), EAR-0509891 (SRH), EAR- 0609670 (MKR) and EAR-0504362 (MKR).
    Keywords: U-series disequilibria ; Samoa ; Eruption ages
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  • 9
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    Stochastic analysis of exit fluid temperature records from the active TAG hydrothermal mound (Mid-Atlantic Ridge, 26°N) : 1. Modes of variability and implications for subsurface flow (2010)
    American Geophysical Union
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    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2007. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research 112 (2007): B07101, doi:10.1029/2006JB004435.
    Description: Yearlong time series records of exit fluid temperature from the active TAG hydrothermal mound (Mid-Atlantic Ridge, 26°N) reveal a complex space-time pattern of flow variability within the mineral deposit. Exit fluid temperatures were measured every 8–10 min from 17 sites distributed across the upper terrace of the mound from June 2003 to June 2004. High-temperature records were obtained using Deep Sea Power and Light SeaLogger® probes deployed in fractures discharging ∼360°C black smoker fluids, and low-temperature records were obtained using VEMCO Ltd. Minilog probes deployed in cracks discharging ∼20°C diffuse flow fluids. The temperature records are considerably more variable than those acquired from vent fields on the fast spreading East Pacific Rise and exhibit a complex mix of both episodic and periodic variability. The diffuse flow records alternate between periods of discharge and periods of what I infer to be recharge when fluid temperatures are equal to background water column levels (∼2.7°C) as ambient seawater is drawn into the seafloor. The space-time patterns of these episodic variations suggest that they represent reorganizations of the secondary circulation system driving diffuse discharge on the upper terrace of the mound on timescales from a few hours to a few days, most likely in response to permeability perturbations. Harmonic temperature oscillations were observed over a range of periods, with the principal lunar semidiurnal tidal period (M2) being most dominant. During certain times, exit fluid temperatures at diffuse sites pulse at diurnal and semidiurnal tidal periods when they are hovering near background water column levels, which I interpret as flow reversals associated with the vertical displacement of a fluid boundary layer at the seafloor interface when the local net flux is near zero. The pulsing behavior is predicted by poroelastic models of tidal loading but is not consistent with effects from tidal currents, which demonstrates that poroelastic effects from tidal loading modulate shallow subsurface flow at the active TAG mound.
    Description: This work was supported by the National Science Foundation (OCE-0137329).
    Keywords: Hydrothermal flow ; Stochastic analysis ; TAG mound
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  • 10
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    Recent volcanic accretion at 9°N–10°N East Pacific Rise as resolved by combined geochemical and geological observations (2013)
    John Wiley & Sons
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    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2013. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geochemistry, Geophysics, Geosystems 14 (2013): 2547–2574, doi:10.1002/ggge.20134.
    Description: The ridge crest at 9°N–10°N East Pacific Rise (EPR) is dominated by overlapping lava flows that have overflowed the axial summit trough and flowed off-axis, forming a shingle-patterned terrain up to ∼2–4 km on either side of the axial summit trough. In this study, we employ 230Th-226Ra dating methods, in conjunction with geochemistry and seafloor geological observations, in an effort to discern the stratigraphic relationships between adjacent flows. We measured major and trace elements and 87Sr/86Sr, 143Nd/144Nd, 176Hf/177Hf, and 238U-230Th-226Ra for lava glass samples collected from several flow units up to ∼2 km away from the axial summit trough on the ridge crest at 9°50′N EPR. Statistical analysis of the 238U-230Th-226Ra data indicates that all but one measured sample from these flows cannot be resolved from the zero-age population; thus, we cannot confidently assign model ages to samples for discerning stratigraphic relationships among flows. However, because groups of samples can be distinguished based on similarities in geochemical compositions, particularly incompatible element abundances with high precision-normalized variability such as U and Th, and because the range of compositions is much greater than that represented by samples from the 1991–1992 and 2005–2006 eruptions, we suggest that the dive samples represent 6–10 eruptive units despite indistinguishable model ages. Geochemical variability between individual flows with similar ages requires relatively rapid changes in parental melt composition over the past ∼2 ka, and this likely reflects variations in the relative mixing proportions of depleted and enriched melts derived from a heterogeneous mantle source.
    Description: This study was funded by NSF OCE-0623838 to K.W.W. Sims and S.A. Soule and NSF OCE-0527053 to K.W.W. Sims. J. Blichert-Toft acknowledges financial support from the French Agence Nationale de la Recherche (grant M&Ms – Mantle Melting – Measurements, Models, Mechanisms).
    Description: 2014-02-01
    Keywords: U-series ; Geochemistry ; Geochronology ; East Pacific Rise
    Repository Name: Woods Hole Open Access Server
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