ALBERT

Description: The presence of potential microbial trace fossils (endolithic microborings) has been well documented in oceanic basaltic pillow lavas, hyaloclastites, tuffs, and transitional subglacial marine lavas in the past 30 yr. Despite their evident abundance in oceanic to subglacial environments, they have not been observed in continental basalts that were not erupted in marine or subglacial settings. To expand the record of putative endolithic microborings in volcanic rocks to nonmarine, continental lacustrine environments, we examined hydrovolcanic pyroclastic deposits in the Fort Rock volcanic field, central Oregon. This study presents the textures, mineralogy, and geochemistry of basaltic tuffs containing possible endolithic microborings comparable in morphology, size, and distribution to those described in earlier oceanic and subglacial basalt studies. We observed a variety of tubular and granular textures that show evidence of biogenic morphologies and behavior, and a primary geological context that expresses their age and syngenicity. Petrographic relationships with secondary phases (chabazite, nontronite, calcite) indicate that the construction of microtunnels occurred in saline, alkaline fluids at temperatures of 25–80 °C. In addition, positive correlations were observed between the extent of aqueous (abiotic) alteration and both the abundance of microtunnels and morphological type. These correlations suggest that microtunnels were more readily formed where there was greater abiotic alteration-fluid flux and that the resulting change in chemical composition of those fluids may have had a direct influence on the formation process or possibly the type of constructing microbe. This work adds to understanding of factors controlling microtunnel formation and is the first account of putative endolithic microborings in a continental lacustrine setting. This new information may also have implications in the search for habitable extraterrestrial environments, such as on Mars.

Description: During opening of a new ocean, magma intrudes into the surrounding sedimentary basins. Heat provided by the intrusions matures the host rock, creating metamorphic aureoles potentially releasing large amounts of hydrocarbons. These hydrocarbons may migrate to the seafloor in hydrothermal vent complexes in sufficient volumes to trigger global warming, e.g., during the Paleocene-Eocene Thermal Maximum (PETM). Mound structures at the top of buried hydrothermal vent complexes observed in seismic data off Norway were previously interpreted as sediment volcanoes, and the amount of released hydrocarbon was estimated based on this interpretation. Here, we present new geophysical and geochemical data from the Gulf of California suggesting that such mound structures could in fact be edifices constructed by the growth of black smoker–type chimneys rather than sediment volcanoes. We have evidence for two buried and one active hydrothermal vent systems outside the rift axis. The active vent releases fluids of several hundred degrees Celsius containing abundant methane, mid-ocean ridge basalt–type helium, and precipitating solids up to 300 m high into the water column. Our observations challenge the idea that methane is emitted slowly from rift-related vents. The association of large amounts of methane with hydrothermal fluids that enter the water column at high pressure and temperature provides an efficient mechanism to transport hydrocarbons into the water column and atmosphere, lending support to the hypothesis that rapid climate change such as during the PETM can be triggered by magmatic intrusions into organic-rich sedimentary basins.

Description: We report on newly discovered mud volcanoes located at ~4500 m water depth ~90 km west of the deformation front of the accretionary wedge of the Gulf of Cadiz, and thus outside of their typical geotectonic environment. Seismic data suggest that fluid flow is mediated by a 〉400-km-long strike-slip fault marking the transcurrent plate boundary between Africa and Eurasia. Geochemical data (Cl, B, Sr, 87 Sr/ 86 Sr, 18 O, D) reveal that fluids originate in oceanic crust older than 140 Ma. On their rise to the surface, these fluids receive strong geochemical signals from recrystallization of Upper Jurassic carbonates and clay-mineral dehydration in younger terrigeneous units. At present, reports of mud volcanoes in similar deep-sea settings are rare, but given that the large area of transform-type plate boundaries has been barely investigated, such pathways of fluid discharge may provide an important, yet unappreciated link between the deeply buried oceanic crust and the deep ocean.

Description: The more than 500 fossil Ca-carbonatite occurrences on Earth are at odds with the only active East African Rift carbonatite volcano, Oldoinyo Lengai (Tanzania), which produces Na-carbonatite magmas. The volcano’s recent major explosive eruptions yielded a mix of nephelinitic and carbonatite melts, supporting the hypothesis that carbonatites and spatially associated peralkaline silicate lavas are related through liquid immiscibility. Nevertheless, previous eruption temperatures of Na-carbonatites were 490–595 °C, which is 250–450 °C lower than for any suitable conjugate silicate liquid. This study demonstrates experimentally that moderately alkaline Ca-carbonatite melts evolve to Na-carbonatites through crystal fractionation. The thermal barrier of the synthetic Na-Ca-carbonate system, held to preclude an evolution from Ca-carbonatites to Na-carbonatites, vanishes in the natural system, where continuous fractionation of calcite + apatite leads to Na-carbonatites, as observed at Oldoinyo Lengai. Furthermore, saturating the Na-carbonatite with minerals present in possible conjugate nephelinites yields a parent carbonatite with total alkali contents of 8–9 wt%, i.e., concentrations that are realistic for immiscible separation from nephelinitic liquids at 1000–1050 °C. Modeling the liquid line of descent along the calcite surface requires a total fractionation of ~48% calcite, ~12% apatite, and ~2 wt% clinopyroxene. SiO 2 solubility only increases from 0.2 to 2.9 wt% at 750–1200 °C, leaving little leeway for crystallization of silicates. The experimental results suggest a moderately alkaline parent to the Oldoinyo Lengai carbonatites and therefore a common origin for carbonatites related to alkaline magmatism.

Description: Quantifying the time scales of magmatic differentiation is critical for understanding the rate at which silicic plutonic and volcanic rocks form. Directly dating this process is difficult because locations with both clear evidence for fractional crystallization and the accessory phases necessary for radiometric dating are rare. Early zircon saturation, however, appears to be characteristic of many high-K, arc-related melts due to their generally elevated initial Zr concentrations. Thus, high-K plutonic series are ideal candidates to study the time scales of magmatic differentiation using zircon U-Pb geochronology. This study focuses on the Dariv Igneous Complex in western Mongolia where early saturation of zircon in a suite of cogenetic, upper crustal (〈0.5 GPa) igneous rocks ranging from ultramafic cumulates to evolved granitoids allows us to date magmatic differentiation. Crystallization ages from six samples across the sequence indicate that magmatic fractionation from a basalt to high-silica (〉65 wt% SiO 2 ) melt occurred in ≤590 ± 350 k.y. This estimate is greater than modeled time scales of conductive cooling of a single intrusion and physical segregation of minerals from a melt, suggesting that continued influx of heat through magmatic activity in the complex may have prolonged cooling and thus time scales associated with the production of silica-enriched melts.

Description: Three years of greenhouse gases measurements, obtained using a gas chromatograph (GC) system located at the Puy de Dôme station at 1465 m a.s.l. in Central France are presented. The GC system was installed in 2010 at Puy de Dôme and was designed for automatic and accurate semi-continuous measurements of atmospheric carbon dioxide, methane, nitrous oxide and sulfur hexafluoride mole fractions. We present in detail the instrumental set up and the calibration strategy, which together allow the GC to reach repeatabilities of 0.1 μmol mol−1, 1.2, 0.3 nmol mol−1 and 0.06 pmol mol−1 for CO2, CH4, N2O and SF6, respectively. Comparisons of the atmospheric time series with those obtained using other instruments shown that the GC system meets the World Meteorological Organization recommendations. The analysis of the three-year atmospheric time series revealed how the planetary boundary layer height drives the mole fractions observed at a mountain site such as Puy de Dôme where air masses alternate between the planetary boundary layer and the free troposphere. Accurate long-lived greenhouse gases measurements collocated with 222Rn measurements as an atmospheric tracer, allowed us to determine the CO2, CH4 and N2O emissions in the catchment area of the station. The derived CO2 surface flux revealed a clear seasonal cycle with net uptake by plant assimilation in the spring and net emission caused by the biosphere and burning of fossil fuel during the remainder of the year. We calculated a mean annual CO2 flux of 1150 t(CO2) km−2. The derived CH4 and N2O emissions in the station catchment area were 5.6 t(CH4) km−2 yr−1 and 1.5 t(N2O) km−2 yr−1, respectively. Our derived annual CH4 flux is in agreement with the national French inventory, whereas our derived N2O flux is five times larger than the same inventory.

Description: This study presents two methods for estimating methane emissions from a waste water treatment plant (WWTP) along with results from a measurement campaign at a WWTP in Valence, France. These methods, chamber measurements and tracer release, rely on Fourier Transform Infrared (FTIR) spectroscopy and Cavity Ring Down Spectroscopy (CRDS) instruments. We show that the tracer release method is suitable to quantify facility- and some process-scale emissions, while the chamber measurements, provide insight into individual process emissions. Uncertainties for the two methods are described and discussed. Applying the methods to CH4 emissions of the WWTP, we confirm that the open basins are not a major source of CH4 on the WWTP (about 10% of the total emissions), but that the pretreatment and sludge treatment are the main emitters. Overall, the waste water treatment plant represents a small part (about 1.5%) of the methane emissions of the city of Valence and its surroundings, which is lower than the national inventories.

Description: This study compares actual evapotranspiration (ETa) measurements by a set of six weighable lysimeters, ETa estimates obtained with the eddy covariance (EC) method, and evapotranspiration calculated with the full-form Penman–Monteith equation (ETPM) for the Rollesbroich site in the Eifel (western Germany). The comparison of ETa measured by EC (including correction of the energy balance deficit) and by lysimeters is rarely reported in the literature and allows more insight into the performance of both methods. An evaluation of ETa for the two methods for the year 2012 shows a good agreement with a total difference of 3.8% (19 mm) between the ETa estimates. The highest agreement and smallest relative differences (〈 8%) on a monthly basis between both methods are found in summer. ETa was close to ETPM, indicating that ET was energy limited and not limited by water availability. ETa differences between lysimeter and EC were mainly related to differences in grass height caused by harvest and the EC footprint. The lysimeter data were also used to estimate precipitation amounts in combination with a filter algorithm for the high-precision lysimeters recently introduced by Peters et al. (2014). The estimated precipitation amounts from the lysimeter data differ significantly from precipitation amounts recorded with a standard rain gauge at the Rollesbroich test site. For the complete year 2012 the lysimeter records show a 16 % higher precipitation amount than the tipping bucket. After a correction of the tipping bucket measurements by the method of Richter (1995) this amount was reduced to 3%. With the help of an on-site camera the precipitation measurements of the lysimeters were analyzed in more detail. It was found that the lysimeters record more precipitation than the tipping bucket, in part related to the detection of rime and dew, which contribute 17% to the yearly difference between both methods. In addition, fog and drizzle explain an additional 5.5% of the total difference. Larger differences are also recorded for snow and sleet situations. During snowfall, the tipping bucket device underestimated precipitation severely, and these situations contributed also 7.9% to the total difference. However, 36% of the total yearly difference was associated with snow cover without apparent snowfall, and under these conditions snow bridges and snow drift seem to explain the strong overestimation of precipitation by the lysimeter. The remaining precipitation difference (about 33%) could not be explained and did not show a clear relation to wind speed. The variation of the individual lysimeters devices compared to the lysimeter mean are small, showing variations up to 3% for precipitation and 8% for evapotranspiration.