ALBERT

Description: Highlights • Nutrient and carbon fluxes are key processes in land-ocean interactions. • We sampled along the river-estuary-ocean system according to travel time of water. • The river was autotrophic with phytoplankton growth, high pH and oxygen concentration, and CO2 undersaturation. • Phytoplankton died off in the estuary causing low pH and oxygen concentration, CO2 supersaturation, and nutrient release. • The approach is suitable to investigate single events such as hydrological extremes. Nutrient and carbon dynamics within the river-estuary-coastal water systems are key processes in understanding the flux of matter from the terrestrial environment to the ocean. Here, we analysed those dynamics by following a sampling approach based on the travel time of water and an advanced calculation of nutrient fluxes in the tidal part. We started with a nearly Lagrangian sampling of the river (River Elbe, Germany; 580 km within 8 days). After a subsequent investigation of the estuary, we followed the plume of the river by raster sampling the German Bight (North Sea) using three ships simultaneously. In the river, we detected intensive longitudinal growth of phytoplankton connected with high oxygen saturation and pH values and an undersaturation of CO2, whereas concentrations of dissolved nutrients declined. In the estuary, the Elbe shifted from an autotrophic to a heterotrophic system: Phytoplankton died off upstream of the salinity gradient, causing minima in oxygen saturation and pH, supersaturation of CO2, and a release of nutrients. In the shelf region, phytoplankton and nutrient concentrations were low, oxygen was close to saturation, and pH was within a typical marine range. Over all sections, oxygen saturation was positively related to pH and negatively to pCO2. Corresponding to the significant particulated nutrient flux via phytoplankton, flux rates of dissolved nutrients from river into estuary were low and determined by depleted concentrations. In contrast, fluxes from the estuary to the coastal waters were higher and the pattern was determined by tidal current. Overall, the approach is appropriate to better understand land-ocean fluxes, particularly to illuminate the importance of these fluxes under different seasonal and hydrological conditions, including flood and drought events.

Description: On three transects, in October, November and December 2018 with RV Uthörn dissolved methane was determined continuously . We used a degassing unit which was using surface water from the ship's water supply in an overflowing bucket. The gas mixture was subsequently analyzed with a Greenhouse Gas Analyzer from LosGatos. Conversion to methane concentration was performed with water samples, from which the methane content was determined with gas chromatography. Atmospheric methane was measured in certain intervals, by disconnecting the degasser, and connecting the Greenhouse Gas Analyzer with a tubing attached at about 6 m above the water surface at the ships upper deck. For basic hydrographic parameters were determined with a CTD (SSDA Sea and Sun Technology, Trappenkamp, Germany ) was placed in the same bucket as described above.

Description: On 25 and 26 of June in 2019 transects between Cuxhaven and Bremerhaven towards Helgoland were performed with the RV Prandtl and Uthörn. Basic hydrographic parameters were measured with two ferry boxes using the ships water supply. Data were saved once per minute. Dissolved methane was determined continuously. We used a degassing unit which was using surface water from the ship's water supply in an overflowing bucket. The gas mixture was subsequently analyzed with a Greenhouse Gas Analyzer from LosGatos. Conversion to methane concentration was performed with water samples, from which the methane content was determined with gas chromatography.

Description: Surface water samples of the river Elbe were taken in May 2021 with the vessel Zwergseeschwalbe between Geesthacht and Neu Darchau. Connecting cruises were performed from colleagues from Geesthacht towards Hamburg and from Elster towards Dömitz.

Description: The vessel Ludwig Prandtl was anchored for 48 h off Cuxhaven at Medem Reede. Water samples were taken approx. every 2 hours during daytime, while sensors were recording continuously. Water samples were taken from ferrybox outlet from surface (1 m).

Description: The vessel Reykjanes was anchored for 48 h off Cuxhaven at Medem Reede. Water samples were taken approx. every 2 hours during daytime, while sensors were recording continuously. Water samples were taken from different sources: ship's water supply, in-situ pump and niskin bottle, from surface (1 m) and bottom water (12 m).

Description: On the MOSES cruise Sternfahrt_1 water samples were taken on 8 stations. Samples were exchanged between the institutes Alfred-Wegener-Institut Zentrum für Polar- und Meeresforschung (AWI), Helmholtz Centre for Ocean Research Kiel (Geomar) and Helmholtz-Zentrum Geesthacht Centre for Materials and Coastal Research (HZG) for later comparison of the nutrient data.

Description: In August 2020 the research vessel Albis investigated the river Elbe from Schmielka towards Geesthacht. Basic hydrographic parameters were measured continuously, with a portable ferryBox. Dissolved methane was continuously determined with a degassing unit and a Greenhouse Gas Analyzer from LosGatosResearch. Atmospheric CH4 and CO2 was determined with a Licor system.