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  • Gas chromatography  (5)
  • Springer  (5)
  • Wiley
  • 2020-2024
  • 1985-1989  (5)
  • 1940-1944
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Year
  • 1
    ISSN: 1612-1112
    Keywords: Gas chromatography ; Thermionic detector ; Flame-forming agents ; CO2 and water gas
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary The use of carbon monoxide were suggested as the flame-forming agent in the thermionic detector (TID). The main characteristics of this detector were studied. It was shown that the optimum flow rate of carbon monoxide is 40 ml/min at an air flow rate of 400–550 ml/min. The response increases twice with the positive potential on the collector. Molar responses of TID were compared with those obtained when using carbon monoxide and hydrogen. For instance, for phosphorus containing compounds they are approximately the same (∼102), while for nitrogen containing compounds in the case of carbon monoxide, there is a 2–5 fold increase in the response. The linear dynamic range for methaphose and azobenzene is 103.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Chromatographia 28 (1989), S. 24-26 
    ISSN: 1612-1112
    Keywords: Gas chromatography ; Anesthetics ; Pharmacokinetics
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary A sensitive capillary gas chromatographic method is described for the simultaneous determination of lidocaine, tetracaine, procaine and dibucaine. The method was applied to the determination of anesthetics in tissue homogenates incubated at 38°C at doses between 10 and 400 mg/kg. In the liver tissue thein vitro metabolization of the studied anesthetics is most rapid for tetracaine, also fast for procaine, while for lidocaine and dibucaine the metabolization is very slow. In brain tissue thein vitro metabolization of anesthetics is very slow. The method shows good analytical parameters: linearity between 5 and 40 μg/ml; day-to-day reproducibility ca. 8% for a concentration of 20 μg/ml, precision ca. 7% for a concentration of 20μg/ml. Accuracy is also very good.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Springer
    Chromatographia 28 (1989), S. 639-642 
    ISSN: 1612-1112
    Keywords: Gas chromatography ; Capillary columns ; Split injection ; Sample tailing and cold trap effects
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary Sample plug tailing together with a cold trap effect brings about discrimination against low boiling components at an initial column temperature above the boiling point of the solvent. In conventional split injection, this compensates for the opposite effects of such factors as the gas phase viscocity change and the pressure wave during the split period, and reasonable results are obtained. In stop-flow injection, however, since the influences of the opposite factors are diminished, the sample plug tailing and the cold trap effect may produce results showing lower than true concentrations for the low boiling components.
    Type of Medium: Electronic Resource
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  • 4
    ISSN: 1612-1112
    Keywords: Gas chromatography ; Liquid crystals ; Substituted benzenes and selectivity
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary The retention mechanisms of polymethylbenzenes and n-alkylbenzenes on the inert solid support Chromaton (spec-surface area: 1m2/g) and the adsorbent-support Silochrom (C-80 (80 m2/g) coated with p-n-butyl oxybenzoic acid have been investigated.
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  • 5
    Electronic Resource
    Electronic Resource
    Springer
    Chromatographia 28 (1989), S. 385-390 
    ISSN: 1612-1112
    Keywords: Gas chromatography ; Capillary column ; Split injection ; Stop-flow method
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary Major concerns in the development of the stop-flow split injection are discussed. Split ratio fluctuation caused by the pressure wave, solvent recondensation and gas viscosity change can be substantially diminished through the formation of a nearly uniform gaseous sample plug. Instrumental variables exerting influence on the accuracy of quantitation were studied. Higher injector temperature and the use of a carrier gas with higher heat conductivity benefit the quick vaporization of the sample liquid, and thus, help in the formation of a sample plug with more unformity.
    Type of Medium: Electronic Resource
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