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  • PANGAEA  (60)
  • Wiley-Blackwell  (24)
  • American Physical Society  (5)
  • Springer Nature  (3)
  • 2020-2024  (63)
  • 1990-1994  (29)
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  • 1
    ISSN: 0941-1216
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Regio- and Stereospecific Addition of Diazomethane to Gibberellic Acid: A New Effective Pathway to 1α,2α-MethylenegibberellinsA new pathway to 1α,2α-methylenegibberellines via pyrazoline intermediates is reported. In contrast to the addition of diazomethane to the Δ1-double bond of corresponding enones in the case of 1 “Umpolung” of the regioselectivity with cis-addition from the α-side to give pyrazoline ester 4 is observed. Subsequent photolysis of 4 leads to the 1,2-cyclopropyl derivative 6. The structures of the key compounds 4 and 6 are confirmed especially by n.m.r. and X-Ray analysis.
    Additional Material: 2 Ill.
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  • 2
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Angewandte Makromolekulare Chemie 206 (1993), S. 21-38 
    ISSN: 0003-3146
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: To improve materials performance like the temperature of deformation under flexural load of thermoplastic polyurethanes (TPU) blending with thermoplastics is sensible. A good compatibilization and phase adhesion of thermodynamical incompatible blend-components can be achieved by the use of the right coupling agents. In the case of blends with TPU and PA6 diisocyanate is given into the melt during the extrusion. Through the chemical reactions effects of compatibilization are achieved in the cases of blends with polyesterpolyurethanes and PA6 produced by extrusion and injection moulding and by reactions in solution, too. These could be perceived as consequence of MDI-initiated reactions within the phase boundary layer. The possible reactions with the PA6-phase will be discussed by the use of a model-system made in solution. No effects of compatibilization by MDI could be proved in the polyetherpolyurethan/PA6-system. The chemical characterization of the blends was realized by GPC and FTIR whereas the properties of the morphology are proved with the help of DSC, DMA and transmission electron microscopy (TEM).
    Notes: Zur Verbesserung der Werkstoffeigenschaften von thermoplastischen Polyurethanen (TPU), wie etwa der Wärmeformbeständigkeit, ist es sinnvoll, ein Blending mit Thermoplasten vorzunehmen. Eine gute Phasenverträglichkeit und Phasenhaftung bei thermodynamisch unverträglichen Blendkomponenten kann durch geeignete reaktive Koppler erreicht werden. Bei den Blends aus TPU and PA6 wird Diisocyanat während der Extrusion in der Schmelze eingebracht. Durch die ablaufenden chemischen Reaktionen werden bei extrudierten und verspritzten Blends und bei aus der Lösung erzeugten Systemen aus Polyesterpolyurethan und PA6 verträglichkeitsverbessernde Wirkungen erreicht. Diese wurden als Folge von mit 4,4′-Diphenylmethandiisocyanat (MDI) initiierten Reaktionen in der Grenzschicht erkannt, wobei die möglichen Reaktionen mit der PA6-Phase anhand eines Modellsystems aus der Lösung diskutiert werden. Bei Blends aus Polyetherpolyurethan und PA6 wurde keine Verträglichkeitsvermittlung durch MDI nachgewiesen. Die chemische Charakterisierung der Blends erfolgte durch GPC und FTIR, während die morphologischen Eigenschaften mittels DSC, DMA und Elektronenmikroskopie dokumentiert wurden.
    Additional Material: 10 Ill.
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  • 3
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Chemie in unserer Zeit 26 (1992), S. VI 
    ISSN: 0009-2851
    Keywords: Chemistry ; Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
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  • 4
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Chemie in unserer Zeit 25 (1991), S. viii 
    ISSN: 0009-2851
    Keywords: Chemistry ; Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
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  • 5
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Materialwissenschaft und Werkstofftechnik 23 (1992), S. 395-400 
    ISSN: 0933-5137
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: The effect of surface adsorption on the machining of brittle materialsIn the present paper is shown the importance of interfacial phenomena in the machining (grinding, cutting) of brittle materials. Especially influenced are the rate of the abrasion, the cutting forces and the roughness of the surface.
    Notes: Die vorliegende Arbeit gibt einen Überblick über die Bedeutung von Grenzflächenvorgängen beim Zerspanen (Schleifen, Trenn-schleifen) sprödharter Materialien. Dabei bestehen Einflüsse auf die Abtragrate, die wirkenden Kräfte und die Oberflächenrauhigkeit.
    Additional Material: 8 Ill.
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  • 6
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Journal für Praktische Chemie/Chemiker-Zeitung 334 (1992), S. 729-730 
    ISSN: 0941-1216
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
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  • 7
    Electronic Resource
    Electronic Resource
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 44 (1993), S. 391-397 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Electrochemical method for testing of the corrosion behaviour of austenitic CrNiMo-stainless steel weldmentsAustenitic CrNiMo stainless steel welds can be more susceptible to pitting and crevice corrosion than the base material owing to segregation and precipitation in the heat affected zone, in the high temperature zone and in the welded zone. Suitable test methods are needed to optimize welding technology.Comparison of potential curves (DIN 50919), comparison of critical pitting corrosion temperatures in FeCl3- or other model solutions, visual estimation after longterm corrosion tests with or without electrochemical load are discussed.A small measurement cell heated from the rear with circulating and temperature controlled electrolyte is shown. With its help separate areas of a weld can be electrochemically investigated.Welds of the materials X 2 CrNiMoN 17 12 2 (1.4406), X 2 CrNiMoN 17 13 5 (1.4439) and X 1 NiCrMoCu 31 27 4 (1.4563) are tested in acidic NaCl solutions in the range of 25 to 75°C.Critical pitting corrosion potentials are obtained for base materials, heat affected zone and weld material. An influence of the welding energy is probable, but cannot be proved in this case without statistical certainty.
    Notes: Schweißverbindungen von austenitischen CrNiMo-Stählen können durch Seigerungen und Ausscheidungen in der Wärmeeinfluß-, Hochtemperaturzone und im Schweißgut gegenüber dem Grundwerkstoff loch- und spaltkorrosionsanfälliger sein.Geeignete Prüfmethoden sind zur Optimierung von Schweißtechnologien notwendig. Eingeführt sind Potentialvergleiche aus Potential-Weg-Kurven (DIN 50 919), Vergleich kritischer Lochkorrosionstemperaturen in FeCl3- oder anderen Modelllösungen, visuelle Beurteilung nach Dauerbelastungstest mit oder ohne elektrochemischer Belastung.Vorgestellt wird eine kleine Aufsatzmeßzelle mit Rückseitenheizung und zirkulierendem und temperierbarem Elektrolyten, mit Hilfe derer einzelne Bereiche einer Schweißnaht elektrochemisch belastet werden können.Getestet werden Schweißverbindungen von Werkstoffen X2CrNiMoN 17 12 2 (1.4406), X2CrNiMoN 17 13 5 (1.4439) und X1NiCrMoCu 31 27 4 (2.4563) in sauren NaCl-Lösungen im Bereich 25-75°C. Grenzpotentiale der Lochkorrosion werden abgestuft für Grundwerkstoff, Wärmeeinflußzone und Schweißgut erhalten. Ein Einfluß der Streckenenergie ist angedeutet, statistisch aber nicht gesichert.
    Additional Material: 8 Ill.
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  • 8
    Electronic Resource
    Electronic Resource
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 43 (1992), S. 206-214 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Production and properties of nitrogen alloyed, corrosion resistant steels and special steels with low carbon contentsAlloying with nitrogen has favourable influence in particular on the mechanical properties of CrNiMo steels (X 2 CrNiMoN 17 12, materials No. 1.4406, X 2 CrNiMoN 17 13 5, materials No. 1.4439 und X 2 CrNiMoN 22 5, materials No. W.-Nr. 1.4462). This comes to bear when ambient temperature and low temperature strength and toughness are concerned. With respect to the corrosion behaviour the data concerning the effect of nitrogen are contradictory. It has become clear that nitrogen improves pitting corrosion resistance; this applies, however, only to pit initiation but not to pit growth. Stress corrosion cracking is not delayed by nitrogen but different results have been obtained with different media: while the duplex steel X 2 CrNiMoN 22 5 is attacked considerably faster than the corresponding nitrogen-free steel in 42% boiling magnesium chloride solution the time-to-failure of both steels are comparable in 30% boiling MgCl2-solution. The nitrogen alloyed steels can be welded by all known welding procedures, provided fully austenitic welding rods are used.
    Notes: Durch Zusatz von Stickstoff werden vor allem die mechanischen Eigenschaften von CrNiMo-Stählen (X 2 CrNiMoN 17 12, W.-Nr. 1.4406, X 2 CrNiMoN 17 13 5, W.-Nr. 1.4439 und X 2 CrNiMoN 22 5, W.-Nr. 1.4462) günstig beeinflußt. Das gilt hinsichtlich der Festigkeit bei Raumtemperatur und der Tieftemperaturzähigkeit, die deutlich verbessert werden. Im Hinblick auf das Korrosionsverhalten sind die Aussagen über die Wirkung von Stickstoffzusätzen widersprüchlich. Eindeutig steht fest, daß durch den Stickstoff die Widerstandsfähigkeit gegen Lochkorrosion verbessert wird; das gilt jedoch nur für die Lochkeimbildung, nicht hingegen für das Lochwachstum. Die Spannungsrißkorrosion wird durch Stickstoff nicht verzögert, doch gibt es dabei Unterschiede je nach Prüfmedium: So wird der zweiphasige Stahl X 2 CrNiMoN 22 5 in 42%iger siedender MgCl2-Lösung deutlich schneller angegriffen als der entsprechende stickstofffreie Stahl, während in 30%iger siedender MgCl2-Lösung die Standzeiten beider Stähle vergleichbar sind. Die stickstofflegierten Stähle sind mit allen bekannten Verfahren schweißbar, wobei vollaustentitische Zusatzwerkstoffe zu empfehlen sind.
    Additional Material: 3 Ill.
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  • 9
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Macromolecular Theory and Simulations 3 (1994), S. 639-647 
    ISSN: 1022-1344
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: In the present paper we define a quantity which describes how strong a polymer system is entangled. In MD computer simulations we apply this definition to samples of polymer melts which were generated with a specific large-scale structure, as characterized by their radius of gyration, end-to-end distance and the “degree” of mutual entanglement of the chains. The quantities mentioned above are monitored over the relaxation of the samples towards equilibrium.
    Additional Material: 8 Ill.
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  • 10
    ISSN: 1022-1352
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The paper describes the synthesis of thermotropic elastomers from trimellitimide-terminated poly(oxy-1,4-butanediyl) [synonyms: poly(tetramethylene ether glycol), PTMG; poly(tetrahydrofuran), poly(THF)] and acetoxy group-terminated rigid blocks. Copolyester imides are formed by transesterification polycondensation in the melt. According to 13C NMR investigations, their chain sequence distribution is characterized by a block-like structure in which the preformed rigid units are partially exchanged by transesterification reactions during the melt polycondensation. The degree of transesterification depends on the reaction time. The influence of the length of the flexible PTMG units and of the concentration of rigid units on the phase behaviour as well as on the thermal behaviour and the dynamic-mechanical behaviour of the block copolymers is discussed with respect to aromatic model compounds.
    Additional Material: 16 Ill.
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