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  • PANGAEA  (42)
  • Wiley  (14)
  • Copernicus Publications (EGU)  (2)
  • 2020-2024  (42)
  • 2015-2019  (16)
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  • 1
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    AGU (American Geophysical Union) | Wiley
    In:  Global Biogeochemical Cycles, 31 (5). pp. 836-849.
    Publication Date: 2020-02-06
    Description: Primary productivity is limited by the availability of nitrogen (N) in most of the coastal Arctic, as a large portion of N is released by the spring freshet and completely consumed during the following summer. Thus, understanding the fate of riverine nitrogen is critical to identify the link between dissolved nitrogen dynamic and coastal primary productivity to foresee upcoming changes in the Arctic seas, such as increase riverine discharge and permafrost thaw. Here, we provide a field-based study of nitrogen dynamic over the Laptev Sea shelf based on isotope geochemistry. We demonstrate that while most of the nitrate found under the surface fresh water layer is of remineralized origin, some of the nitrate originates from atmospheric input and was probably transported at depth by the mixing of brine-enriched denser water during sea-ice formation. Moreover, our results suggest that riverine dissolved organic nitrogen (DON) represents up to 6 times the total riverine release of nitrate and that about 62 to 76% of the DON is removed within the shelf waters. This is a crucial information regarding the near-future impact of climate change on primary productivity in the Eurasian coastal Arctic.
    Type: Article , PeerReviewed
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  • 2
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    AGU (American Geophysical Union) | Wiley
    In:  Geochemistry, Geophysics, Geosystems, 17 (1). pp. 56-64.
    Publication Date: 2019-02-01
    Description: Export of brine-enriched water from Siberian shelves is thought to be a key parameter in maintaining the Arctic Halocline, which isolates the fresh and cold surface water from the warm Atlantic water and thus prevent dramatic change in the Arctic sea-ice thermodynamic. In this study, we used five years of oxygen isotope and hydrological summer surveys to better understand the factors controlling the brine inventory and distribution over the Laptev Sea shelf. The inventory was maximal in 2011 and 2007 and minimal in 2010. The brine inventory interannual variations are coherent with the winter Arctic Oscillation index that was maximal in 2011 and 2007 and minimal in 2010, which is known to modulate Arctic winds and sea-ice export pattern. While we should remain cautious since our record is limited to 5-years, our results suggest that the combined effect of the Arctic Oscillation and of the Arctic Dipole is the main factor controlling the annual variations in the inventory of brine-enriched waters from the Laptev Sea shelf between 2007 and 2011, especially during extreme negative Arctic Oscillation and Arctic Dipole conditions as in 2010.
    Type: Article , PeerReviewed
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  • 3
    Publication Date: 2019-09-23
    Description: A multiyear mooring record (2007–2014) and satellite imagery highlight the strong temperature variability and unique hydrographic nature of the Laptev Sea. This Arctic shelf is a key region for river discharge and sea ice formation and export and includes submarine permafrost and methane deposits, which emphasizes the need to understand the thermal variability near the seafloor. Recent years were characterized by early ice retreat and a warming near-shore environment. However, warming was not observed on the deeper shelf until year-round under-ice measurements recorded unprecedented warm near-bottom waters of +0.6°C in winter 2012/2013, just after the Arctic sea ice extent featured a record minimum. In the Laptev Sea, early ice retreat in 2012 combined with Lena River heat and solar radiation produced anomalously warm summer surface waters, which were vertically mixed, trapped in the pycnocline, and subsequently transferred toward the bottom until the water column cooled when brine rejection eroded stratification.
    Type: Article , PeerReviewed
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  • 4
    Publication Date: 2019-09-23
    Description: The upper 500 m of the water column and the sediment surface along an E–W transect in the Fram Strait were sampled for recent planktic foraminifera. The δ18O and δ13C values of the tests are compared to the stable isotope composition of water samples taken from the same depths, and related to the characteristics of the water column. The polar species Neogloboquadrina pachyderma (sin.) clearly dominates the species assemblage in the Fram Strait in the early summer, while the subpolar Turborotalita quinqueloba accounts only for 5–23%. In this area the average depth of calcification of N. pachyderma (sin.) lies between 70–150m water depth, T. quinqueloba shows a similar range with 50–120 m water depth. The δ18O values of N. pachyderma (sin.) show an average vital effect of about −1.5‰ compared to calculated equilibrium calcite values. Except for the upper ~ 75 m, the vertical profiles of δ13C of the net-sampled shells are nearly parallel to the values measured in the water column with an average offset of −1.6‰ and −3.6‰ for N. pachyderma (sin.) and T. quinqueloba, respectively. The discrepancy found in the upper ~ 75 m might indicate the influence of the "carbonate ion effect" on the carbon isotope incorporation in the tests. Oxygen and carbon isotopes from the sediment surface yield higher values than those from the water column for both species. This may be because specimens from the water column reflect a modern snapshot only, while tests from surface sediments record environmental parameters from the past ~ 1000 years.
    Type: Article , PeerReviewed , info:eu-repo/semantics/article
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  • 5
    Publication Date: 2022-03-09
    Description: Large gradients and inter annual variations on the Laptev Sea shelf prevent the use of uniform property ranges for a classification of major water masses. The central Laptev Sea is dominated by predominantly marine waters, locally formed polynya waters and riverine summer surface waters. Marine waters enter the central Laptev Sea from the northwestern Laptev Sea shelf and originate from the Kara Sea or the Arctic Ocean halocline. Local polynya waters are formed in the Laptev Sea coastal polynyas. Riverine summer surface waters are formed from Lena river discharge and local melt. We use a principal component analysis (PCA) in order to assess the distribution and importance of water masses within the Laptev Sea. This mathematical method is applied to hydro-chemical summer datasets from the Laptev Sea from five years and allows to define water types based on objective and statistically significant criteria. We argue that the PCA derived water types are consistent with the Laptev Sea hydrography and indeed represent the major water masses on the central Laptev Sea shelf. Budgets estimated for the thus defined major Laptev Sea water masses indicate that freshwater inflow from the western Laptev Sea is about half or in the same order of magnitude as freshwater stored in locally formed polynya waters. Imported water dominates the nutrient budget in the central Laptev Sea; and only in years with enhanced local polynya activity is the nutrient budget of the locally formed water in the same order as imported nutrients.
    Type: Article , PeerReviewed
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  • 6
    Publication Date: 2023-02-08
    Description: A major surface circulation feature of the Arctic Ocean is the Transpolar Drift (TPD), a current that transports river‐influenced shelf water from the Laptev and East Siberian Seas toward the center of the basin and Fram Strait. In 2015, the international GEOTRACES program included a high‐resolution pan‐Arctic survey of carbon, nutrients, and a suite of trace elements and isotopes (TEIs). The cruises bisected the TPD at two locations in the central basin, which were defined by maxima in meteoric water and dissolved organic carbon concentrations that spanned 600 km horizontally and ~25‐50 m vertically. Dissolved TEIs such as Fe, Co, Ni, Cu, Hg, Nd, and Th, which are generally particle‐reactive but can be complexed by organic matter, were observed at concentrations much higher than expected for the open ocean setting. Other trace element concentrations such as Al, V, Ga, and Pb were lower than expected due to scavenging over the productive East Siberian and Laptev shelf seas. Using a combination of radionuclide tracers and ice drift modeling, the transport rate for the core of the TPD was estimated at 0.9 ± 0.4 Sv (106 m3 s‐1). This rate was used to derive the mass flux for TEIs that were enriched in the TPD, revealing the importance of lateral transport in supplying materials beneath the ice to the central Arctic Ocean and potentially to the North Atlantic Ocean via Fram Strait. Continued intensification of the Arctic hydrologic cycle and permafrost degradation will likely lead to an increase in the flux of TEIs into the Arctic Ocean.
    Type: Article , PeerReviewed
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  • 7
    Publication Date: 2023-02-08
    Description: Neogloboquadrina pachyderma is the dominant species of planktonic foraminifera found in polar waters and is therefore invaluable for paleoceanographic studies of the high latitudes. However, the geochemistry of this species is complicated due to the development of a thick calcite crust in its final growth stage and at greater depths within the water column. We analyzed the in situ Mg/Ca and δ18O in discrete calcite zones using LA‐ICP‐MS, EPMA and SIMS within modern N. pachyderma shells from the highly dynamic Fram Strait and the seasonally isothermal/isohaline Irminger Sea. Here we compare shell geochemistry to the measured temperature, salinity and δ18Osw in which the shells calcified to better understand the controls on N. pachyderma geochemical heterogeneity. We present a relationship between Mg/Ca and temperature in N. pachyderma lamellar calcite that is significantly different than published equations for shells that contained both crust and lamellar calcite. We also document highly variable SIMS δ18O results (up to a 3.3‰ range in single shells) on plankton tow samples which we hypothesize is due to the granular texture of shell walls. Finally, we document that the δ18O of the crust and lamellar calcite of N. pachyderma from an isothermal/isohaline environment are indistinguishable from each other, indicating that shifts in N. pachyderma δ18O are primarily controlled by changes in environmental temperature and/or salinity rather than differences in the sensitivities of the two calcite types to environmental conditions.
    Type: Article , PeerReviewed
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  • 8
    Publication Date: 2023-05-04
    Description: The first full transarctic section of 228Ra in surface waters measured during GEOTRACES cruises PS94 and HLY1502 (2015) shows a consistent distribution with maximum activities in the Transpolar Drift. Activities in the central Arctic have increased from 2007 through 2011 to 2015. The increased 228Ra input is attributed to stronger wave action on shelves resulting from a longer ice‐free season. A concomitant decrease in the 228Th/228Ra ratio likely results from more rapid transit of surface waters depleted in 228Th by scavenging over the shelf. The 228Ra activities observed in intermediate waters (〈 1500m) in the Amundsen Basin are explained by ventilation with shelf water on a time scale of about 15‐18 years, in good agreement with estimates based on SF6 and 129I/236U. The 228Th excess below the mixed layer up to 1500m depth can complement 234Th and 210Po as tracers of export production, after correction for the inherent excess resulting from the similarity of 228Ra and 228Th decay times. We show with a Th/Ra profile model that the 228Th/228Ra ratio below 1500m is inappropriate for this purpose because it is a delicate balance between horizontal supply of 228Ra and vertical flux of particulate 228Th. The accumulation of 226Ra in the deep Makarov Basin is not associated with an accumulation of Ba and can therefore be attributed to supply from decay of 230Th in the bottom sediment. We estimate a ventilation time of 480 years for the deep Makarov‐Canada Basin, in good agreement with previous estimates using other tracers.
    Type: Article , PeerReviewed
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  • 9
    Publication Date: 2024-02-07
    Description: The Arctic Ocean receives a large supply of dissolved organic matter (DOM) from its catchment and shelf sediments, which can be traced across much of the basin’s upper waters. This signature can potentially be used as a tracer. On the shelf, the combination of river discharge and sea-ice formation, modifies water densities and mixing considerably. These waters are a source of the halocline layer that covers much of the Arctic Ocean, but also contain elevated levels of DOM. Here we demonstrate how this can be used as a supplementary tracer and contribute to evaluating ocean circulation in the Arctic. A fraction of the organic compounds that DOM consists of fluoresce and can be measured using in-situ fluorometers. When deployed on autonomous platforms these provide high temporal and spatial resolution measurements over long periods. The results of an analysis of data derived from several Ice Tethered Profilers (ITPs) offer a unique spatial coverage of the distribution of DOM in the surface 800m below Arctic sea-ice. Water mass analysis using temperature, salinity and DOM fluorescence, can clearly distinguish between the contribution of Siberian terrestrial DOM and marine DOM from the Chukchi shelf to the waters of the halocline. The findings offer a new approach to trace the distribution of Pacific waters and its export from the Arctic Ocean. Our results indicate the potential to extend the approach to separate freshwater contributions from, sea-ice melt, riverine discharge and the Pacific Ocean. Key Points: Arctic surface waters with comparable temperature and salinity have contrasting in situ dissolved organic matter fluorescence. Organic matter fluorescence can tracklow salinity waters feeding into the Transpolar Drift and haloclinelayers. Siberian and Chukchishelf waters can be separated based on their fluorescence to salinity relationship
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  • 10
    Publication Date: 2024-02-07
    Description: Permafrost degradation in the catchment of major Siberian rivers, combined with higher precipitation in a warming climate, could increase the flux of terrestrially derived dissolved organic matter (tDOM) into the Arctic Ocean (AO). Each year, ∼ 7.9 Tg of dissolved organic carbon (DOC) is discharged into the AO via the three largest rivers that flow into the Laptev Sea (LS) and East Siberian Sea (ESS). A significant proportion of this tDOM-rich river water undergoes at least one freeze–melt cycle in the land-fast ice that forms along the coast of the Laptev and East Siberian seas in winter. To better understand how growth and melting of land-fast ice affect dissolved organic matter (DOM) dynamics in the LS and ESS, we determined DOC concentrations and the optical properties of coloured dissolved organic matter (CDOM) in sea ice, river water and seawater. The data set, covering different seasons over a 9-year period (2010–2019), was complemented by oceanographic measurements (T, S) and determination of the oxygen isotope composition of the seawater. Although removal of tDOM cannot be ruled out, our study suggests that conservative mixing of high-tDOM river water and sea-ice meltwater with low-tDOM seawater is the major factor controlling the surface distribution of tDOM in the LS and ESS. A case study based on data from winter 2012 and spring 2014 reveals that the mixing of about 273 km3 of low-tDOM land-fast-ice meltwater (containing ∼ 0.3 Tg DOC) with more than 200 km3 of high-tDOM Lena River water discharged during the spring freshet (∼ 2.8 Tg DOC yr−1) plays a dominant role in this respect. The mixing of the two low-salinity surface water masses is possible because the meltwater and the river water of the spring freshet flow into the southeastern LS at the same time every year (May–July). In addition, budget calculations indicate that in the course of the growth of land-fast ice in the southeastern LS, ∼ 1.2 Tg DOC yr−1 (± 0.54 Tg) can be expelled from the growing ice in winter, together with brines. These DOC-rich brines can then be transported across the shelves into the Arctic halocline and the Transpolar Drift Current flowing from the Siberian Shelf towards Greenland. The study of dissolved organic matter dynamics in the AO is important not only to decipher the Arctic carbon cycle but also because CDOM regulates physical processes such as radiative forcing in the upper ocean, which has important effects on sea surface temperature, water column stratification, biological productivity and UV penetration.
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