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  • 2020-2023  (26)
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  • 1
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    Scaling laws of collective ride-sharing dynamics (2020)
    In:  Physical Review Letters
    Details
    Publication Date: 2022-03-21
    Description: Ride-sharing services may substantially contribute to future sustainable mobility. Their collective dynamics intricately depend on the topology of the underlying street network, the spatiotemporal demand distribution, and the dispatching algorithm. The efficiency of ride-sharing fleets is thus hard to quantify and compare in a unified way. Here, we derive an efficiency observable from the collective nonlinear dynamics and show that it exhibits a universal scaling law. For any given dispatcher, we find a common scaling that yields data collapse across qualitatively different topologies of model networks and empirical street networks from cities, islands, and rural areas. A mean-field analysis confirms this view and reveals a single scaling parameter that jointly captures the influence of network topology and demand distribution. These results further our conceptual understanding of the collective dynamics of ride-sharing fleets and support the evaluation of ride-sharing services and their transfer to previously unserviced regions or unprecedented demand patterns.
    Type: info:eu-repo/semantics/article
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  • 2
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    Climate-induced speleothem radiocarbon variability on Socotra Island from the Last Glacial Maximum to the Younger Dryas (2020)
    In:  Climate of the Past
    Details
    Publication Date: 2022-03-21
    Description: In this study, the dead carbon fraction (DCF) variations in stalagmite M1-5 from Socotra Island in the western Arabian Sea were investigated through a new set of high-precision U-series and radiocarbon (14C) dates. The data reveal an extreme case of very high and also climate-dependent DCF. For M1-5, an average DCF of 56.2±3.4 % is observed between 27 and 18 kyr BP. Such high DCF values indicate a high influence of aged soil organic matter (SOM) and nearly completely closed-system carbonate dissolution conditions. Towards the end of the last glacial period, decreasing Mg∕Ca ratios suggest an increase in precipitation which caused a marked change in the soil carbon cycling as indicated by sharply decreasing DCF. This is in contrast to the relation of soil infiltration and DCF as seen in stalagmites from temperate zones. For Socotra Island, which is influenced by the East African–Indian monsoon, we propose that more humid conditions and enhanced net infiltration after the Last Glacial Maximum (LGM) led to dense vegetation and thus lowered the DCF by increasing 14CO2 input into the soil zone. At the onset of the Younger Dryas (YD) a sudden change in DCF towards much higher, and extremely variable, values is observed. Our study highlights the dramatic variability of soil carbon cycling processes and vegetation feedback on Socotra Island manifested in stalagmite DCF on both long-term trends and sub-centennial timescales, thus providing evidence for climate influence on stalagmite radiocarbon. This is of particular relevance for speleothem studies that aim to reconstruct past atmospheric 14C (e.g., for the purposes of 14C calibration), as these would rely on largely climate-independent soil carbon cycling above the cave.
    Type: info:eu-repo/semantics/article
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  • 3
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    Climate Variability in Central Europe during the Last 2500 Years Reconstructed from Four High-Resolution Multi-Proxy Speleothem Records (2021)
    In:  Geosciences
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    Publication Date: 2022-03-21
    Description: The Late Holocene was characterized by several centennial-scale climate oscillations including the Roman Warm Period, the Dark Ages Cold Period, the Medieval Warm Period and the Little Ice Age. The detection and investigation of such climate anomalies requires paleoclimate archives with an accurate chronology as well as a high temporal resolution. Here, we present 230Th/U-dated high-resolution multi-proxy records (δ13C, δ18O and trace elements) for the last 2500 years of four speleothems from Bunker Cave and the Herbstlabyrinth cave system in Germany. The multi-proxy data of all four speleothems show evidence of two warm and two cold phases during the last 2500 years, which coincide with the Roman Warm Period and the Medieval Warm Period, as well as the Dark Ages Cold Period and the Little Ice Age, respectively. During these four cold and warm periods, the δ18O and δ13C records of all four speleothems and the Mg concentration of the speleothems Bu4 (Bunker Cave) and TV1 (Herbstlabyrinth cave system) show common features and are thus interpreted to be related to past climate variability. Comparison with other paleoclimate records suggests a strong influence of the North Atlantic Oscillation at the two caves sites, which is reflected by warm and humid conditions during the Roman Warm Period and the Medieval Warm Period, and cold and dry climate during the Dark Ages Cold period and the Little Ice Age. The Mg records of speleothems Bu1 (Bunker Cave) and NG01 (Herbstlabyrinth) as well as the inconsistent patterns of Sr, Ba and P suggests that the processes controlling the abundance of these trace elements are dominated by site-specific effects rather than being related to supra-regional climate variability.
    Type: info:eu-repo/semantics/article
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  • 4
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    Results of a temporally highly resolved litter monitoring on two morphologically distinct beaches at the Baltic Sea Coast of Schleswig-Holstein (2021)
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    Publication Date: 2022-03-25
    Type: Thesis , NonPeerReviewed
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  • 5
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    Climate and structure of the 8.2 ka event reconstructed from three speleothems from Germany (2020)
    In:  Global and Planetary Change
    Details
    Publication Date: 2022-07-13
    Description: The most pronounced climate anomaly of the Holocene was the 8.2 ka cooling event. We present new 230Th/U-ages as well as high-resolution stable isotope and trace element data from three stalagmites from two different cave systems in Germany, which provide important information about the structure and climate variability of the 8.2 ka event in central Europe. In all three speleothems, the 8.2 ka event is clearly recorded as a pronounced negative excursion of the δ18O values and can be divided into a ‘whole event’ and a ‘central event’. All stalagmites show a similar structure of the event with a short negative excursion prior to the ‘central event’, which marks the beginning of the ‘whole event’. The timing and duration of the 8.2 ka event are different for the individual records, which may, however, be related to dating uncertainties. Whereas stalagmite Bu4 from Bunker Cave also shows a negative anomaly in the δ13C values and Mg content during the event, the two speleothems from the Herbstlabyrinth cave system do not show distinct peaks in the other proxies. This may suggest that the speleothem δ18O values recorded in the three stalagmites do not primarily reflect climate change at the cave site, but rather large-scale changes in the North Atlantic. This is supported by comparison with climate modelling data, which suggest that the negative peak in the speleothem δ18O values is mainly due to lower δ18O values of precipitation above the cave and that temperature only played a minor role. Alternatively, the other proxies may not be as sensitive as δ18O values to record this centennial-scale cooling event. This may particularly be the case for speleothem δ13C values as suggested by comparison with a climate modelling study simulating vegetation changes in Europe during the 8.2 ka event. Based on our records, it is not possible to resolve which of these hypotheses is most appropriate, but our multi-proxy dataset shows that regional climate evolution during the event was probably complex, although all δ18O records show a clear negative anomaly.
    Type: info:eu-repo/semantics/article
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  • 6
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    Are oxygen isotope fractionation factors between calcite and water derived from speleothems systematically biased due to prior calcite precipitation (PCP)? (2021)
    In:  Geochimica et Cosmochimica Acta
    Details
    Publication Date: 2022-07-13
    Description: The equilibrium oxygen isotope fractionation factor between calcite and water (18αcalcite/H2O) is an important quantity in stable isotope geochemistry and allows in principle to infer temperature variations from carbonate δ18O if carbonate formation occurred in thermodynamic equilibrium. For this reason, many studies intended to determine the value of the oxygen isotope fractionation factor between calcite and water (18αcalcite/H2O) for a wide range of temperatures using modern cave calcite and the corresponding cave drip water or ancient speleothem carbonate and fluid inclusion samples. However, the picture that emerges from all of these studies indicates that speleothem calcite is not formed in thermodynamic equilibrium but under kinetic conditions, provoking a large variability of determined 18αcalcite/H2O values. Here we present a conceptual framework that can explain the variability of 18αcalcite/H2O values obtained by cave studies. Prior calcite precipitation (PCP) is calcite precipitation before cave drip water is dripping from the cave ceiling and impinges on the surface of a stalagmite or watch glass. Prior to the karst water dripping from the cave ceiling, PCP can occur in the karst above the cave as well as on the cave ceiling, the cave walls and on the surface of stalactites. We argue that PCP leads to increasing the δ18O value of the dissolved HCO3- (δ18OHCO3-), resulting in an oxygen isotope disequilibrium of the δ18OHCO3- values with respect to the δ18O value of water (δ18OH2O). The oxygen isotope disequilibrium between HCO3- and H2O is re-equilibrated by oxygen isotope exchange between H2O and HCO3. Depending on the temperature, the re-equilibration time varies from hours to days and is usually much longer than the residence time of the drip water on stalactites, but much shorter than the time required to percolate through the karst. Therefore, while the oxygen isotope equilibrium between HCO3- and H2O is very likely re-established when PCP occurred in the karst, oxygen isotope disequilibrium conditions between HCO3- and H2O still prevail when PCP occurred inside a cave, e.g., on stalactites. If the oxygen isotope disequilibrium conditions between HCO3- and H2O is not re-established, the precipitated calcite will inherit the elevated δ18O value of the HCO3- and not be in oxygen isotope equilibrium with the corresponding drip water. Consequently, if the 18αcalcite/H2O value is calculated from cave calcite samples affected by PCP, the derived value will be systematically biased.
    Type: info:eu-repo/semantics/article
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  • 7
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    The forcings of the Mediterranean Sea and the physical properties of its water masses (2023)
    Elsevier
    Details
    Publication Date: 2022-12-22
    Description: This chapter aims at introducing the reader to general concepts about the main forcings of the Mediterranean Sea, in terms of exchanges through the Strait of Gibraltar, and air-sea exchanges of heat, freshwater, and momentum. These forcings are also responsible for the peculiar characteristics of Mediterranean water masses. Therefore, the chapter continues with giving a general explanation on water mass analysis, and then it describes the properties and vertical and horizontal distributions of the main Mediterranean water masses. To conclude, the reader is introduced to the use of other (biogeochemical, and chemical) tracers of water masses, with a focus on the Mediterranean Sea.
    Type: Book chapter , PeerReviewed
    Format: text
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  • 8
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    The Eco‐Exposome Concept: Supporting an Integrated Assessment of Mixtures of Environmental Chemicals (2021)
    Details
    Publication Date: 2022-04-04
    Description: Organisms are exposed to ever‐changing complex mixtures of chemicals over the course of their lifetime. The need to more comprehensively describe this exposure and relate it to adverse health effects has led to formulation of the exposome concept in human toxicology. Whether this concept has utility in the context of environmental hazard and risk assessment has not been discussed in detail. In this Critical Perspective, we propose—by analogy to the human exposome—to define the eco‐exposome as the totality of the internal exposure (anthropogenic and natural chemicals, their biotransformation products or adducts, and endogenous signaling molecules that may be sensitive to an anthropogenic chemical exposure) over the lifetime of an ecologically relevant organism. We describe how targeted and nontargeted chemical analyses and bioassays can be employed to characterize this exposure and discuss how the adverse outcome pathway concept could be used to link this exposure to adverse effects. Available methods, their limitations, and/or requirement for improvements for practical application of the eco‐exposome concept are discussed. Even though analysis of the eco‐exposome can be resource‐intensive and challenging, new approaches and technologies make this assessment increasingly feasible. Furthermore, an improved understanding of mechanistic relationships between external chemical exposure(s), internal chemical exposure(s), and biological effects could result in the development of proxies, that is, relatively simple chemical and biological measurements that could be used to complement internal exposure assessment or infer the internal exposure when it is difficult to measure. Environ Toxicol Chem 2022;41:30–45. © 2021 The Authors. Environmental Toxicology and Chemistry published by Wiley Periodicals LLC on behalf of SETAC.
    Description: Illustration of the eco‐exposome assessment and how chemical analysis and bioassays could be used to estimate internal exposure. MIE = molecular initiation event; KE = key event; AO = adverse outcome.
    Description: DAAD German academic exchange service
    Keywords: ddc:577.14
    Language: English
    Type: doc-type:article
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  • 9
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    Living coccolithophore communities in the central Mediterranean Sea (Summer 2016): Relations between ecology and oceanography (2022)
    Elsevier
    Details
    Publication Date: 2022-03-17
    Description: Coccolithophores were collected at 21 stations during summer 2016, from coastal and offshore areas of the Central Mediterranean Sea, to describe the ecology of the coccolithophore community integrating information on their abundance, environmental parameters (salinity, temperature, dissolved oxygen, and fluorescence) and oceanographic data. Emiliania huxleyi dominated the assemblage from surface to intermediate layers, while Florisphaera profunda was more abundant in the deep photic zone. Principal Component Analysis revealed that the distribution of coccolithophore taxa was influenced by environmental parameters: K-strategist taxa were related to warm surface waters, whereas lower photic zone taxa were influenced by the development of a Deep Chlorophyll Maximum and high salinity values, well below the thermocline. These results confirmed that a vertical species zonation, as a typical feature of low-middle latitude, characterizes the Central Mediterranean during summer. The distribution of F. profunda once again confirmed its use as a proxy of Deep Chlorophyll Maximum development and paleoproductivity estimates. Gephyrocapsa spp. (=total Gephyrocapsa), and in particular G. oceanica, were more abundant along the Atlantic Water pathway. Finally, the high concentration value of Helicosphaera carteri, recorded in the Ligurian Sea at an offshore station, suggested an expansion of the opportunist nature of this taxon from coastal environments to the offshore areas characterized by high turbidity and high productivity.
    Description: Published
    Description: 101995
    Description: 4A. Oceanografia e clima
    Description: JCR Journal
    Keywords: Living coccolithophores ; Helicosphaera carteri ; Oceanography ; Ecology ; Central Mediterranean Sea ; coccolithophore ecology and oceanography
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 10
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    Breakthrough strategies for climate-neutral industry in Europe : policy and technology pathways for raising EU climate ambition ; study (2021)
    Berlin : Agora Energiewende
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    Publication Date: 2022-02-18
    Description: The basic materials industries are a cornerstone of Europe's economic prosperity, increasing gross value added and providing around 2 million high-quality jobs. But they are also a major source of greenhouse gas emissions. Despite efficiency improvements, emissions from these industries were mostly constant for several years prior to the Covid-19 crisis and today account for 20 per cent of the EU's total greenhouse gas emissions. A central question is therefore: How can the basic material industries in the EU become climate-neutral by 2050 while maintaining a strong position in a highly competitive global market? And how can these industries help the EU reach the higher 2030 climate target - a reduction of greenhouse gas emissions of at least 55 per cent relative to 1990 levels? In the EU policy debate on the European Green Deal, many suppose that the basic materials industries can do little to achieve deep cuts in emissions by 2030. Beyond improvements to the efficiency of existing technologies, they assume that no further innovations will be feasible within that period. This study takes a different view. It shows that a more ambitious approach involving the early implementation of key low-carbon technologies and a Clean Industry Package is not just possible, but in fact necessary to safeguard global competitiveness.
    Keywords: ddc:600
    Repository Name: Wuppertal Institut für Klima, Umwelt, Energie
    Language: English
    Type: report , doc-type:report
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