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  • 1
    Publication Date: 2017-04-04
    Description: Six hundred and sixty-seven water samples were collected from public drinking water supplies in Sicily and analysed for electric conductivity and for their Cl-, Br- and F- contents. The samples were, as far as possible, collected evenly over the entire territory with an average sampling density of about one sample for every 7600 inhabitants. The contents of Cl- and Br-, ranging between 5.53 and 1302 mg/l and between 〈 0.025 and 4.76 mg/l respectively, correlated well with the electric conductivity, a parameter used as a proxy for water salinity. The highest values were found both along the NW and SE coasts, which we attributed to seawater contamination, and in the central part of Sicily, which we attributed to evaporitic rock dissolution. The fluoride concentrations ranged from 0.023 to 3.28 mg/l, while the highest values (only 3 exceeding the maximum admissible concentration of 1.5 mg/l) generally correlated either with the presence in the area of crystalline (volcanic or metamorphic) or evaporitic rocks or with contamination from hydrothermal activity. Apart from these limited cases of exceeding F- levels, the waters of public drinking water supplies in Sicily can be considered safe for human consumption for the analysed parameters. Some limited concern could arise from the intake of bromide-rich waters (about 3% exceeding 1 mg/l) because of the potential formation of dangerous disinfection by-products.
    Description: Published
    Description: 303-313
    Description: 4.4. Scenari e mitigazione del rischio ambientale
    Description: JCR Journal
    Description: reserved
    Keywords: drinking water quality ; fluoride ; bromide ; chloride ; 03. Hydrosphere::03.02. Hydrology::03.02.04. Measurements and monitoring ; 03. Hydrosphere::03.04. Chemical and biological::03.04.03. Chemistry of waters ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 2
    Publication Date: 2017-04-04
    Description: Six hundred and sixty-seven water samples were collected from public drinking water supplies in Sicily and analysed for electric conductivity and for their chloride, bromide, fluoride, sulphate and nitrate contents. The samples were, as far as possible, collected evenly over the entire territory with an average sampling density of about one sample for every 7600 inhabitants. The contents of chloride and bromide, ranging between 5.53 and 1302 mg/l and between 〈 0.025 and 4.76 mg/l respectively, correlated well with the electric conductivity, a parameter used as a proxy for water salinity. The highest values were found both along the NW and SE coasts, which we attributed to seawater contamination, and in the central part of Sicily, which we attributed to evaporitic rock dissolution. The nitrate concentrations were in the range 0.05 – 296 mg/l. Of the analysed samples about 4.4% exceeded the maximum admissible concentration (MAC) of 50 mg/l. The highest values were always measured in areas of intense agricultural exploitation. The sulphate concentrations varied between 6.03 and 516 mg/l, exceeding in about 1.2% of the cases the guideline level of 250 mg/l. The highest values were always related either to evaporitic rock dissolution or to seawater intrusion. The fluoride concentrations ranged from 0.023 to 3.28 mg/l, while the highest values (only 3 exceeding the MAC of 1.5 mg/l) generally attributed either to the leaching of crystalline (volcanic or metamorphic) or evaporitic rocks or to contamination from a hydrothermal component. Apart from these limited cases of exceeding of MACs, the waters of public drinking water supplies in Sicily can be considered safe for human consumption for the analysed parameters. Some limited concern could arise from the intake of bromide-rich waters (about 3% exceeding 1 mg/l) because of the potential formation of dangerous disinfection by-products. Also nitrate concentrations, although sometimes exceeding MAC, display generally level well suited for human consumption, the population-weighted average being about 16 mg/l for the whole Sicily. As regards geographic distribution, the best water quality was found in areas with the most humid climate and with huge aquifers in the north-eastern part of the island. On the contrary especially along the southern coasts of Sicily, arid conditions and the widespread presence of impermeable lithologies, sometimes forces the use of low quality water resources. But it is also worth to note that bad management often exacerbates water quality and quantity problems in these areas.
    Description: Unpublished
    Description: Athens, Greece
    Description: 4.4. Scenari e mitigazione del rischio ambientale
    Description: open
    Keywords: Sicily ; drinking water ; fluoride ; bromide ; chloride ; sulphate ; nitrate ; 03. Hydrosphere::03.04. Chemical and biological::03.04.03. Chemistry of waters
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: Poster session
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  • 3
    Publication Date: 2017-04-04
    Description: Hydrothermal systems and related vents can exhibit dramatic changes in their physico-chemical conditions over time as a response to varying activity in the feeding magmatic systems. Massive steam condensation and gas scrubbing processes of thermal fluids during their ascent and cooling cause further compositional changes that mask information regarding the conditions evolving at depth in the hydrothermal system. Here we propose a new stability diagram based on the CO2-CH4-CO-H2 concentrations in vapor, which aims at calculating the temperatures and pressures in hydrothermal reservoirs. To filter gas scrubbing effects, we have also developed a model for selective dissolution of CO2-H2S-N2-CH4-He-Ne mixtures in fresh and/or air-saturated seawater. This methodology has been applied to the recent (November 2002) crisis that affected the geothermal field off the island of Panarea (Italy), where the fluid composition and fluxes have been monitored for the past two decades. The chemical and isotopic compositions of the gases suggest that the volatile elements originate from an active magma, which feeds a boiling saline solution having temperatures of up to 350 C and containing 12 mol CO2 in vapor. The thermal fluids undergo cooling and re-equilibration processes on account of gas-water-rock interactions during their ascent along fracture networks. Furthermore, steam condensation and removal of acidic species, partial dissolution in cold air-saturated seawater and stripping of atmospheric components, affect the composition of the geothermal gases at shallow levels. The observed geochemical variations are consistent with a new input of magmatic fluids that perturbed the geothermal system and caused the unrest event. The present-state evolution shows that this dramatic input of fluids is probably over, and that the system is now tending towards steady-state conditions on a time scale of months.
    Description: Published
    Description: 3045-3059
    Description: partially_open
    Keywords: Submarine degassing ; geothermal system ; gas-water interaction ; gas geothermometry ; 04. Solid Earth::04.01. Earth Interior::04.01.02. Geological and geophysical evidences of deep processes ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.04. Thermodynamics ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
    Format: 539 bytes
    Format: 627284 bytes
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  • 4
    Publication Date: 2017-04-04
    Description: On 2nd/3rd November 2002, a huge amount of gas, mainly composed of CO2, was suddenly released from the sea bottom off the coast of Panarea, producing a ‘‘crater’’20 by 10 meters wide and 7 meters deep. The gas output was estimated to be 109 l/d, two orders of magnitude higher than that measured in the 1980s. The anomalous degassing rate lasted for some weeks, slowly decreasing to an almost constant rate of about 4 x 107 l/d after two months. The geothermo- barometric estimations revealed an increase of both the temperature and pressure in the geothermal system feeding the sampled vents. The 3He/4He ratios were similar to those measured in nearby Stromboli. We have monitored the area for the last two decades, and based on our intensive and extensive geochemical measurements, have ascertained that the geothermal reservoir has lost its steady state. We maintain that a new magmatic input caused these phenomena.
    Description: - Istituto Nazionale di Geofisica e Vulcanologia, Osservatorio Vesuviano, Naples, Italy. - Istituto Nazionale di Geofisica e Vulcanologia, Sezione di Palermo, Palermo, Italy. - Dipartimento Chimica e Fisica della Terra ed Applicazioni, Palermo, Italy.
    Description: Published
    Description: L07619
    Description: partially_open
    Keywords: Submarine degassing ; magmatic fluids ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.04. Thermodynamics ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
    Format: 3123251 bytes
    Format: 503 bytes
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