ISSN:
0021-8995
Keywords:
Chemistry
;
Polymer and Materials Science
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
,
Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
,
Physics
Notes:
Telechelic prepolymers of butadiene with aliphatic isocyanate end-groups were prepared by the solution polymerization of butadiene under free radical initiation. 4,4′-Azobis (4-cyanopentanoyl azide) was used as the initiator. Liquid prepolymers were obtained with molecular weights of 1450 to 6000 and functionalities 1.9 to 2.2. The prepolymers were characterized by their number-average molecular weight, isocyanate content, functionality, infrared, and nuclear magnetic resonance spectra and microstructure. The storage stability of the prepolymers was checked and they were found to be quite stable under ambient conditions. Isocyanate-terminated polybutadienes were reacted with N,N-dimethylamino ethanol and t-butyl hydroperoxide to obtain useful dimethylamino-terminated and peroxycarbamate-terminated prepolymers, respectively.
Additional Material:
4 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/app.1988.070360613
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