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  • Chemistry  (428)
  • 2020-2024  (1)
  • 2020-2022  (16)
  • 2000-2004  (1)
  • 1980-1984  (410)
  • 1
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Journal für Praktische Chemie/Chemiker-Zeitung 325 (1983), S. 685-688 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Reaktionen von 4-Arylmethylen-2-phenyl-2-oxazolin-5-onen mit o-Phenylendiamin
    Additional Material: 4 Tab.
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  • 2
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 27 (1981), S. 693-697 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 27 (1981), S. 856-859 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 29 (1984), S. 1415-1426 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Mangrove bark was extracted using either water, ethanol, acetone, or various binary mixtures of these, as solvent. With plywood panels as substrates, joints prepared with adhesives derived from these extracts were tested for strength properties. In terms of the quantity of extracts from mangrove bark, water was the most effective solvent, followed sequentially by ethanol and acetone. However, in terms of the tannin content of these extracts, the order of extraction effectiveness of these solvents was reversed. The use of solvent mixtures in tannin extraction did not produce an observable synergistic effect. The quantity of extract and its tannin content were dictated primarily by the predominant solvent in the binary mixture. The reactivity of mangrove bark extracts is influenced significantly by formaldehyde concentration, cure temperature, type, and pH of the adhesive medium. Adhesive joints of significant bond strength were obtained from mangrove tannin adhesives. Prolonged cure periods, particularly at elevated temperatures, have deleterious effects on the strength properties of these adhesive joints.
    Additional Material: 10 Ill.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Acta Polymerica 32 (1981), S. 634-636 
    ISSN: 0323-7648
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: Die Struktur von Polyethylenterephthalatfasern wurde durch Wärmebehandlung bzw. Lösungsmitteleinwirkung modifiziert. Beide Methoden bewirkten eine Erhöhung der Kristallinität der Fasern. Die Behandlung mit Dimethylformamid oder Acetonitril führte zu einer Verringerung der Reißfestigkeit.
    Notes: Two different methods of effecting modification of the fibre structure, namely, heat treatment and solvent treatment, have been investigated. Heat setting and solvent treatement led to improvement in the crystallinity of the poly(ethylene terephthalate) fibres. Pretreatment in dimethyl formamide and acetonitrile resulted in reduced tensile strength.
    Additional Material: 1 Ill.
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  • 6
    Electronic Resource
    Electronic Resource
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 17 (1982), S. 553-557 
    ISSN: 0030-493X
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The mass spectral fragmentations of methyl mono- and dichlorobutanates have been studied. Deutrium labelling and metastable ion analysis were used to elucidate the fragmentation mechanisms. The molecular ion peaks of the esters are weak and show only in the spectra of the monochloro isomers. A McLafferty rearrangement gives the base peaks in the spectra of methyl 2-chloro-, 4-chloro- and 4,4-dichlorobutanoate; α-cleavage, [COOCH3]+, in methyl 2,2- and 2,4-dichlorobutanoate; [M—Cl]+, in methyl 3-chlorobutanoate; [M—Cl—HCl]+, in methyl 3,4-dichlorobutanoate; [M—Cl—CH2CO]+, in methyl 3,3-dichlorobutanoate and [M—Cl—COOCH3]+·, in methyl erythro- and threo-2,3-dichlorobutanoate. The mass spectra of the stereoisomers are nearly identical, the loss of a chlorine atom and the McLafferty rearrangement giving the higher peaks in the spectrum of the threo form.
    Additional Material: 2 Ill.
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  • 7
    Electronic Resource
    Electronic Resource
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 18 (1983), S. 438-441 
    ISSN: 0030-493X
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: A systematic study on the electron impact mass spectra of all nine chlorinated catechols in presented. Metastable ion analysis was used to elucidate the fragmentation pathways. The influence of the position of the chloro substituents can be used to distinguish the structural isomers. In this respect the most characteristic fragment ions are [M—CHl]+·, [M—HCOOH]+·, [M—COCl]+, [M—HCl—CO]+·, [M—CHOCl]+· and [M—HCl—HCl]+·.
    Additional Material: 1 Ill.
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  • 8
    Electronic Resource
    Electronic Resource
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 19 (1984), S. 96-100 
    ISSN: 0030-493X
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The fragmentation of chlorinated guaiacols (2-methoxyphenols) on electron impact has been studied. The most common fragmentation processes are interpreted and in some cases the small differences between spectra of positional isomers are explained. In addition to the well-known alkyl-oxygen fission (loss of methyl radical), metastable ion studies and deuterium labelling have indicated several new fragmentation pathways. The most characteristic are the formation of [M—CH3—HCl]+ and [M—CH3—Cl]+· ions. In general, however, the spectra of positional isomers are shown to be very similar.
    Additional Material: 2 Ill.
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  • 9
    Electronic Resource
    Electronic Resource
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 18 (1983), S. 295-304 
    ISSN: 0030-493X
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Metastable peaks have been used to study the fragmentation pathways of the methyl and trideuteriomethyl chloropropenoates and chloromethyl propenoate. The molecular ion peaks of the unsaturated esters are more intense than those of the saturated esters, α-Cleavage, [M—OCH3]+, produces the base peak in almost all compounds, the relative abundances of the additional peaks being low for chloromethyl propenoate. The losses of H2O, CH3. and COOH. indicate the isomerization of some ionized chloro esters to the chlorinated 2-butenoic acid molecular ions. An intense loss of H2O observed for methyl 2-chloropropenoate indicates its most facile isomerization, [ester]+· → [acid]+·, whereas the isomerization in methyl trichloropropenoate could not be observed. The molecular ion of chloromethyl propenoate, however, also seems to partly rearrange to the chlorinated 3-butenoic acid ion, since the first field free region metastable peak shows a weak loss of CO. The new reaction pathways, i.e. the losses of CHO·, CH2O and CH2CO from ionized chloromethyl propenoate, were detected.
    Additional Material: 3 Ill.
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  • 10
    Electronic Resource
    Electronic Resource
    Chichester : Wiley-Blackwell
    Organic Magnetic Resonance 16 (1981), S. 322-324 
    ISSN: 0030-4921
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Proton polarization transfer has been used for the convenient observation of proton coupled natural abundance 15N NMR spectra of the E- and Z-isomers of N-methylformamide at 10.14 MHz. Second-order spectral analysis is required to determine the 15N—H coupling constants, at least for the E-isomer of secondary formamides. An useful stereospecificity is observed for both the one- and two-bond 15N—H coupling constants.
    Additional Material: 2 Ill.
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