ALBERT

Description: FTIR spectral identification is today’s gold standard analytical procedure for plastic pollution material characterization. High-throughput FTIR techniques have been advanced for small microplastics (10–500 µm) but less so for large microplastics (500–5 mm) and macroplastics (〉 5 mm). These larger plastics are typically analyzed using ATR, which is highly manual and can sometimes destroy particles of interest. Furthermore, spectral libraries are often inadequate due to the limited variety of reference materials and spectral collection modes, resulting from expensive spectral data collection. We advance a new high-throughput technique to remedy these problems using FTIR microplate readers for measuring large particles (〉 500 µm). We created a new reference database of over 6000 spectra for transmission, ATR, and reflection spectral collection modes with over 600 plastic, organic, and mineral reference materials relevant to plastic pollution research. We also streamline future analysis in microplate readers by creating a new particle holder for transmission measurements using off-the-shelf parts and fabricating a nonplastic 96-well microplate for storing particles. We determined that particles should be presented to microplate readers as thin as possible due to thick particles causing poor-quality spectra and identifications. We validated the new database using Open Specy and demonstrated that additional transmission and reflection spectra reference data were needed in spectral libraries.

Description: Background: Northern ecosystems are strongly influenced by herbivores that differ in their impacts on the ecosystem. Yet the role of herbivore diversity in shaping the structure and functioning of tundra ecosystems has been overlooked. With climate and land-use changes causing rapid shifts in Arctic species assemblages, a better understanding of the consequences of herbivore diversity changes for tundra ecosystem functioning is urgently needed. This systematic review synthesizes available evidence on the effects of herbivore diversity on different processes, functions, and properties of tundra ecosystems. Methods: Following a published protocol, our systematic review combined primary field studies retrieved from bibliographic databases, search engines and specialist websites that compared tundra ecosystem responses to different levels of vertebrate and invertebrate herbivore diversity. We used the number of functional groups of herbivores (i.e., functional group richness) as a measure of the diversity of the herbivore assemblage. We screened titles, abstracts, and full texts of studies using pre-defined eligibility criteria. We critically appraised the validity of the studies, tested the influence of different moderators, and conducted sensitivity analyses. Quantitative synthesis (i.e., calculation of effect sizes) was performed for ecosystem responses reported by at least five articles and meta-regressions including the effects of potential modifiers for those reported by at least 10 articles. Review findings: The literature searches retrieved 5944 articles. After screening titles, abstracts, and full texts, 201 articles including 3713 studies (i.e., individual comparisons) were deemed relevant for the systematic review, with 2844 of these studies included in quantitative syntheses. The available evidence base on the effects of herbivore diversity on tundra ecosystems is concentrated around well-established research locations and focuses mainly on the impacts of vertebrate herbivores on vegetation. Overall, greater herbivore diversity led to increased abundance of feeding marks by herbivores and soil temperature, and to reduced total abundance of plants, graminoids, forbs, and litter, plant leaf size, plant height, and moss depth, but the effects of herbivore diversity were difficult to tease apart from those of excluding vertebrate herbivores. The effects of different functional groups of herbivores on graminoid and lichen abundance compensated each other, leading to no net effects when herbivore effects were combined. In turn, smaller herbivores and large-bodied herbivores only reduced plant height when occurring together but not when occurring separately. Greater herbivore diversity increased plant diversity in graminoid tundra but not in other habitat types. Conclusions: This systematic review underscores the importance of herbivore diversity in shaping the structure and function of Arctic ecosystems, with different functional groups of herbivores exerting additive or compensatory effects that can be modulated by environmental conditions. Still, many challenges remain to fully understand the complex impacts of herbivore diversity on tundra ecosystems. Future studies should explicitly address the role of herbivore diversity beyond presence-absence, targeting a broader range of ecosystem responses and explicitly including invertebrate herbivores. A better understanding of the role of herbivore diversity will enhance our ability to predict whether and where shifts in herbivore assemblages might mitigate or further amplify the impacts of environmental change on Arctic ecosystems.

Description: All datasets provided in the operational dataset (Heubeck et al., 2024) of the ICDP project BASE (ICDP 5069) consist of metadata, data and/or images. Here, a summary of explanations of the tables, data and images exported from the database of the project (mDIS BASE) are given and are complimented by additional information on data from measurements done in the laboratory prior to the sampling party. Finally, the sampling data from the first two sam-pling parties are added. Some basic definitions of identifiers used in ICDP, depths corrections and measurements are also introduced.

Description: The BASE (Barberton Archean Surface Environments) scientific drilling project focused on recovering unweathered continuous core through strata of the Paleoarchean Moodies Group (ca. 3.2 Ga), central Barberton Greenstone Belt (BGB), South Africa. They comprise some of the oldest well-preserved sedimentary strata on Earth, deposited within only a few million years in alluvial, fluvial, coastal-deltaic, tidal, and prodeltaic settings and represent a very-high-resolution record of Paleoarchean surface conditions and processes. Moodies Group strata consist of polymict conglomerates, widespread quartzose, lithic and arkosic sand-stones, siltstones, shales, and rare BIFs and jaspilites, interbedded with tuffs and several thin lavas. This report describes operations from preparations to the sampling workshop and complements the related scientific report. Eight inclined boreholes between 280 and 495 m length, drilled during November 2021 through July 2022, obtained a total of 2903 m of curated core of variable quality through steeply to subvertically dipping, in part overturned stratigraphic sections. All drilling objec-tives were reached. Boreholes encountered a variety of conglomerates, diverse and abun-dant, mostly tuffaceous sandstones, rhythmically laminated shale-siltstone and banded-iron formations, and several horizons of early-diagenetic sulfate concretions. Oxidative weather-ing reached far deeper than expected; fracturing was more intense, and BIFs and jaspilites were thicker than anticipated. Two km-long mine adits and a water tunnel, traversing four thick stratigraphic sections within the upper Moodies Group in the central BGB, were also sampled. All boreholes were logged by geophysical instruments. Core was processed (ori-ented, slabbed, photographed, described, and archived) in a large, publicly accessible hall in downtown Barberton. An exhibition provided background explanations for visitors and relat-ed the drilling objectives to the recently established Barberton-Makhonjwa Mountains World Heritage Site. A substantial education, outreach and publicity program addressed the information needs of the local population and of local and regional stakeholders.