Publication Date:
2012-04-15
Description:
A chiral helical coordination polymer [Ag(pmta)] n ( 1 ) was prepared by the reaction of the asymmetric organic spacer 2-pyrimidylthioacetic acid (Hpmta) with silver(I) acetate. Complex 1 has a hetero-chiral coaxial helical structure, which is further extended into a 2D network structure by various supramolecular interactions. Furthermore, complex 1 exhibits strong fluorescence emission in the solid state and modest power second-harmonic-generation (SHG) efficiency at room temperature.
Print ISSN:
0044-2313
Electronic ISSN:
1521-3749
Topics:
Chemistry and Pharmacology
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