ISSN:
1608-3318
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract A series of MoO2Cl2 complexes with acetoacetanilide derivatives were synthesized and studied by IR spectroscopy. The crystal and molecular structures of the MoO2Cl2 complex with acetoacet-2-toluidine (HL) were determined by X-ray diffraction analysis. The monoclinic crystals involved are a = 7.621(7) Å, b = 9.498(3) Å, c = 19.980(9) Å, β = 95.16(7)°, V = 1440(2) Å3, Z = 4, and space group P21/n. The coordination polyhedron of the Mo atom is a distorted octahedron with two O oxoatoms in the cis-position relative to each other, two Cl atoms in the trans-positions, and two O atoms (HL) in the trans-positions to O(oxo).
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1023/A:1026679009037
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