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  • Springer  (25)
  • American Institute of Physics (AIP)  (7)
  • Amsterdam : Elsevier
  • Emerald
  • Geological Society of America (GSA)
  • Geological Society of London
  • 2000-2004
  • 1995-1999  (32)
  • 1995  (32)
  • 1
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 78 (1995), S. 5143-5154 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: A scanning tunneling microscope in ultrahigh vacuum has been used to investigate the growth, morphology, and surface atomic structure of ultrathin titanium silicide films on Si(111) substrates. Microstructural considerations have been used to identify various stages of the silicide growth. Atomic resolution images of a titanium silicide crystallite facet, formed at 850 °C, have been identified as a 2×2 silicon termination of a C54-TiSi2(010) surface. Possible epitaxial silicide/silicon relationships are provided. Theoretical consideration has been given to the interatomic bonding in the C54-TiSi2 lattice and the dangling bond density of ideally terminated silicide planes has been calculated. The highly reconstructed atomically flat surface of a large crystallite, formed at 1200 °C, has been assigned as a C54-TiSi2(311) plane giving the epitaxial relation C54-TiSi2(311)(parallel)Si(111). The presence of pairs and linear chains of defects, with common orientations, is attributed to the decomposition of a diatomic gas on the facet, producing sites of preferential adsorption on the silicide surface. © 1995 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 77 (1995), S. 563-571 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: A scanning tunneling microscope (STM) in ultrahigh vacuum has been used to investigate the growth, morphology, and surface atomic structure of ultrathin titanium silicide films on Si(100) substrates. Microstructural considerations have been used to identify various stages of the silicide growth. Methods for STM crystallography have been developed and used to identify possible epitaxial silicide/silicon relationships based on morphological considerations. Atomic resolution images of a titanium silicide crystallite have identified a 2×2 silicon termination of a C54-TiSi2(111) surface. It is shown that unambiguous identification of epitaxial relationships requires images of the atomic structure of the silicide crystallite surfaces in addition to morphological information. © 1995 American Institute of Physics.
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  • 3
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 102 (1995), S. 6946-6948 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: Subpicosecond lasers measured the appearance rate of OH X(v=0) following 267 nm photolysis of the CH4⋅O3 van der Waals complex. The rise of the OH A←OH X laser-induced fluorescence with respect to the photolysis/probe delay time, tD, was LIF(tD)=1−exp(−tD/τ) with τ approximately 3 ps, indicating that the reaction CH4+O(1D2)→CH3+OH involves a CH3OH* intermediate with that lifetime. No prompt OH(v=0) from a direct or fast reaction was observed. © 1995 American Institute of Physics.
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  • 4
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Review of Scientific Instruments 66 (1995), S. 3083-3083 
    ISSN: 1089-7623
    Source: AIP Digital Archive
    Topics: Physics , Electrical Engineering, Measurement and Control Technology
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  • 5
    ISSN: 1089-7623
    Source: AIP Digital Archive
    Topics: Physics , Electrical Engineering, Measurement and Control Technology
    Notes: Asymmetrically cut perfect crystals, in both the Laue and Bragg geometries, are examined as single crystal monochromators for x-ray beams that are collimated to a small fraction of the Darwin width, as is typical in experiments with coherent x rays. Both the Laue and asymmetric Bragg geometries are plagued by an inherent chromatic aberration that increases the beam divergence much beyond that of the symmetric Bragg geometry. Measurements from a recent experiment at the ESRF are presented to compare Si(220) (symmetric Bragg), diamond(111) (asymmetric Laue), and diamond(111) (symmetric Bragg inclined) geometries. © 1995 American Institute of Physics.
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  • 6
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The transformation of titanium silicide from the C49 to the C54 structure was studied using x-ray diffraction of samples containing arrays of narrow lines of preformed C49 TiSi2. Using a synchrotron x-ray source, diffraction patterns were collected at 1.5–2 °C intervals during sample heating at rates of 3 or 20 °C/s to temperatures of 1000–1100 °C. The results show a monotonic increase in the C54 transition temperature by as much as 180 °C with a decreasing linewidth from 1.0 to 0.1 μm. Also observed is a monotonic increase in (040) preferred orientation of the C54 phase with decreasing linewidth. The results demonstrate the power of in situ x-ray diffraction of narrow line arrays as a tool to study finite size effects in thin-film reactions. © 1995 American Institute of Physics.
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  • 7
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 103 (1995), S. 3272-3272 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
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  • 8
    ISSN: 1432-1416
    Keywords: Turing patterns ; CIMA/starch ; Brussellator/immobilizer ; Schnackenberg/immobilizer model systems ; One-dimensional nonlinear stability analyses
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Mathematics
    Notes: Abstract The development of one-dimensional Turing patterns characteristic of the chlorite-iodide-malonic acid/starch reaction as well as analogous Brussellator/immobilizer and Schnackenberg/immobilizer model systems is investigated by means of a weakly nonlinear stability analysis applied to the appropriately scaled governing equations. Then the theoretical predictions deduced from these pattern formation studies are compared with experimental evidence relevant to the Turing diffusive instabilities under examination in order to explain more fully the transition to such stationary symmetry-breaking spatial structures when the temperature or pool species concentrations vary.
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  • 9
    Electronic Resource
    Electronic Resource
    Springer
    Climate dynamics 11 (1995), S. 115-128 
    ISSN: 1432-0894
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract The Southern Oscillation (SO) is examined in three 10 year AMIP-type integrations of a 30-level GCM having prescribed monthly mean observed sea surface temperatures for the period January 1979 to December 1988. Three horizontal spectral resolutions of T21, T42 and T79 are investigated and the results are compared with the low-frequency variability, having periods longer than 8 months, in the observed Darwin and Tahiti sea level pressures (SLP) and in the T106 ECMWF analyses from May 1985 to April 1991. Both the ECMWF analyses and the GCM results give unrealistic SLP variability at Tahiti resulting in low Darwin-Tahiti SLP correlations and low S/N ratios for the Tahiti-Darwin SO index. The ECMWF analyses are in particularly poor agreement with the observations during 1987 with anomalously high SLP at Tahiti. Examination of the ECMWF assimilated SSTs, reveals that this may be related to the assimilated SSTs being too cold in the central and eastern equatorial Pacific during mid-1987. The GCM results show the familiar SLP dipole in the tropical Pacific albeit displaced eastwards compared to previous observational studies especially at T42 resolution, thus accounting for the problems at Tahiti which lies near strong gradients in the correlation pattern. Time-longitude diagrams of low-level convergence and correlation maps of upper-level streamfunction suggest that the model is reproducing the SO divergence anomalies although too weakly at T21 resolution and at different longitudinal locations at T42 and T79 resolutions. The time-mean low-level convergences in the GCM simulations give ITCZs and SPCZs in qualitative agreement with the observations with a tendency for increased convergence in the eastern Pacific ITCZ at higher resolution. Longitudinal shifts are not apparent in the time-mean convergence when comparing the GCM results at different resolutions.
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  • 10
    Electronic Resource
    Electronic Resource
    Springer
    Climate dynamics 11 (1995), S. 115-128 
    ISSN: 1432-0894
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract. The Southern Oscillation (SO) is examined in three 10 year AMIP-type integrations of a 30-level GCM having prescribed monthly mean observed sea surface temperatures for the period January 1979 to December 1988. Three horizontal spectral resolutions of T21, T42 and T79 are investigated and the results are compared with the low-frequency variability, having periods longer than 8 months, in the observed Darwin and Tahiti sea level pressures (SLP) and in the T106 ECMWF analyses from May 1985 to April 1991. Both the ECMWF analyses and the GCM results give unrealistic SLP variability at Tahiti resulting in low Darwin-Tahiti SLP correlations and low S/N ratios for the Tahiti-Darwin SO index. The ECMWF analyses are in particularly poor agreement with the observations during 1987 with anomalously high SLP at Tahiti. Examination of the ECMWF assimilated SSTs, reveals that this may be related to the assimilated SSTs being too cold in the central and eastern equatorial Pacific during mid-1987. The GCM results show the familiar SLP dipole in the tropical Pacific albeit displaced eastwards compared to previous observational studies especially at T42 resolution, thus accounting for the problems at Tahiti which lies near strong gradients in the correlation pattern. Time-longitude diagrams of low-level convergence and correlation maps of upper-level streamfunction suggest that the model is reproducing the SO divergence anomalies although too weakly at T21 resolution and at different longitudinal locations at T42 and T79 resolutions. The time-mean low-level convergences in the GCM simulations give ITCZs and SPCZs in qualitative agreement with the observations with a tendency for increased convergence in the eastern Pacific ITCZ at higher resolution. Longitudinal shifts are not apparent in the time-mean convergence when comparing the GCM results at different resolutions.
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