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  • 1
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 41 (1995), S. 445-445 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 41 (1995), S. 2274-2281 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: In this work the experimental observations are explained with the aid of a simple air-entrapment model based on the concept of two levels of porosity of fiber mats. A simple model that includes liquid bypassing with initial air trapping, subsequent capillary invasion of regular fiber bundles with air compression, and finally mobilization is proposed to explain air-entrapment phenomena. The simple model successfully rationalizes the observed air trapping and compression during initial liquid-fiber contact. An empirical equation for the mobilization efficiency is adapted to the model to estimate void content. The velocity dependence of the trapped void content predicted by the model is in good agreement with observations.
    Additional Material: 13 Ill.
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  • 3
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 41 (1995), S. 2327-2332 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 5 Ill.
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  • 4
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 41 (1995), S. 2261-2273 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Wetting of glass fibers was visualized using an oil with the same refractive index. With both a video-enhanced microscope and a high-magnification video camera we followed the flow front and qualitatively measured the entrapped air bubbles by image analysis. Due to different permeabilities between the fiber mats and bundles, air bubbles are entrapped. Two major kinds of air bubbles are observed: small cylindrical micro voids between fiber filaments (inside fiber bundles) and spherical macro voids outside fiber bundles. These air bubbles can be described by three major mechanisms initial liquid bypassing/air trapping, later capillary invasion of disordered fiber bundles, and air bubble mobilization. Both random and unidirectional fiber mats were used in this study. Vacuum as well as different fluid viscosities and surface tensions were also investigated, which led us to guidelines of optimum processing parameters of fiber wetting for resin transfer molding and structural reaction injection molding. They are low viscosity, vacuum, high mold temperature, and high pressure.
    Additional Material: 17 Ill.
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  • 5
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 41 (1995), S. 501-508 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A primary method of reducing membrane fouling during cross-flow microfiltration is periodic reverse filtration. This in situ method of cleaning the membrane forces clear fluid in the reverse direction through the membrane and readjusts the particle or solute accumulation on the retentate side of the membrane. This work focuses on the design of a high-frequency, reverse-filtration strategy to maximize the flux for washed yeast suspensions through 0.2- μm cellulose acetate flat sheet membranes. Several experiments were conducted with reverse-filtration times ranging from 0.5-4 s and forward-filtration times ranging from 1-40 s. For every back-filtration time, there exists an optimum forward-filtration time that gives the maximum global average flux. The optimum average flux increases with decreasing back filtration times and feed concentrations, but shows little dependence on cross-flow velocity and reverse filtration transmembrane pressure. The optimum flux with rapid backflushing is 20 to 30 times higher than the long-term flux in the absence of backflushing. A theory presented assumes that cake formation during forward filtration follows dead-end filtration theory and the cake is instantly removed during reverse filtration. The measured average flux per cycle follows the trends predicted by the theory, but the measured values exceed the predictions, presumably due to brief delays in cake removal and cake formation at the start of reverse and forward filtration, respectively, during each cycle.
    Additional Material: 9 Ill.
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  • 6
    ISSN: 0899-0042
    Keywords: chiral separation ; molecular modeling ; inclusion complexes ; Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The enantiomers of 1,1′-bi-2-naphthol, 1,1′-binaphthyl diyl hydrogen phosphate, and 1,1′-binaphthyldicarboxylic acid are separated using capillary electrophoresis with cyclodextrins added to the running buffer. It is demonstrated that the type and concentration of cyclodextrin employed are critical for maximum enantiomeric resolution. A modified version of a previously described model of enantiomeric separations in capillary electrophoresis is shown to support the observed separation behavior. Molecular modeling is employed to calculate interaction energies between the various enantiomers and cyclodextrins. A reasonable correlation between these computationally derived interaction energies and separation behavior resulted from a statistical mechanical treatment of the molecular modeling data. The importance of hydrogen bonding in inclusion complex formation was probed and the effects of minimization and solvation in molecular modeling calculations are also discussed. © 1995 Wiley-Liss, Inc.
    Additional Material: 2 Ill.
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  • 7
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Biotechnology and Bioengineering 47 (1995), S. 155-164 
    ISSN: 0006-3592
    Keywords: cell debris ; protein recovery ; membranes ; microfiltration ; bacterial lysate ; Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Protein recovery from a bacterial lysate was accomplished using microfiltration membranes in a flat crossflow filter and in a cylindrical rotary filter. Severe membrane fouling yielded relatively low long-term permeate flux values of 10-4-10-3 cm/s (where I cm/s = 3.6 × 104 L/m2 - h). The permeate flux was found to be nearly independent of transmembrane pressure and to increase with increasing shear rate and decreasing solids concentration. The flux increased with shear to approximately the one-third power or greater for the flat filter and the one-half power or greater for the rotary filter; the stronger dependence for the rotary filter is thought to result from Taylor vortices enhancing the back transport of debris carried to the membrane surface by the permeate flow. The average protein transmission or sieving coefficient was measured at approximately 0.6, but considerable scatter in the transmission data was observed. The largest sieving coefficients were obtained for dilute suspensions at high shear rate. The rotary filter provided higher fluxes than did the flat filter for dilute suspensions, but not for concentrated suspensions. © 1995 John Wiley & Sons, Inc.
    Additional Material: 11 Ill.
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  • 8
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Macromolecular Rapid Communications 16 (1995), S. 207-210 
    ISSN: 1022-1336
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Extension of the Mayo-Lewis Model of copolymerization concerning solvent effects in free-radical polymerization is discussed on the basis of the bootstrap and penultimate unit effects.
    Additional Material: 1 Tab.
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  • 9
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Macromolecular Theory and Simulations 4 (1995), S. 195-208 
    ISSN: 1022-1344
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Free radical addition reactions in the presence of cobaloximes and related compounds have been modelled. Several mechanisms are presented and similarities with the “persistent radical effect” noted by Daikh and Finke are discussed. Cobaloximes and salophenSystem. name: N-acetyl-p-aminophenyl salicylate. derivatives are widely used in organic synthesis to build carbon-carbon bonds, whereas in polymer synthesis they are used as catalytic chain transfer agents in the production of oligomers. This work shows that these reactions are closely related and also demonstrates the influence that an external radical source has on the overall reaction kinetics.
    Additional Material: 8 Ill.
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  • 10
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Nanocomposites were produced via sol-gel reactions for tetraethylorthosilicate within the cluster morphology of perfluorosulfonic acid films. Small-angle x-ray scattering revealed that the polar/nonpolar nanophase-separated morphological template persists despite invasion by the silicon oxide phase. Scanning electron microscopy (ESEM-EDAX) studies have indicated that the greatest silicon oxide concentration occurs near the surface and decreases to a minimum in the middle. Optical and ESEM micrographs revealed a brittle, surface-attached silica layer at high silicon oxide contents. © 1995 John Wiley & Sons, Inc.
    Additional Material: 8 Ill.
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