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  • Polymer and Materials Science  (2)
  • Chlorophylls
  • METEOROLOGY AND CLIMATOLOGY
  • Surface physics, nanoscale physics, low-dimensional systems
  • 1990-1994  (3)
  • 1994  (3)
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Keywords
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  • 1990-1994  (3)
Year
  • 1
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 51 (1994), S. 931-937 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The mechanical properties of network molecular systems, prepared through visible (Ar+) laser-induced polymerization of multifunctional acrylates, were studied as a function of some of the photopolymerization parameters. The properties investigated were the Young's modulus of elasticity and the stress-at-break, both derived from the stress versus strain test of dogbone-shaped photopolymerized samples. The parameters studied included the dye and co-initiator concentrations, and the laser power. We also compared the mechanical properties of samples made using different types of fluorone dyes and using two different amines as co-initiator. Better polymers are formed by the dyes with low fluorescence quantum yield. The three photopolymerization parameters modify the mechanical properties in a very similar way: they initially tend to increase both the Young's modulus and the stress-at-break but have a deleterious effect on the material strength if used in excess. N-phenylglycine, NPG, was shown to form stronger polymers (higher Young's modulus) than if N,N-dimethyl-2,6-diisopropylaniline, DIDMA, was used as co-initiator. We discuss the possible molecular mechanisms for such observations. © 1994 John Wiley & Sons, Inc.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 54 (1994), S. 1141-1159 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Binary blends of poly(caprolactone) (PCL) with cellulosic esters [cellulose diacetate (CDA), cellulose acetate-butyrate (CAB), and cellulose triacetate (CTA)] were studied by using differential scanning calorimetry (DSC), dynamic mechanical analysis (DMA), and wide-angle X-ray scattering (WAXS) techniques, and qualitative comparison was made with the results obtained by polarizing optical microscopy. The PCL-CAB system was proved to be partially miscible, whereas PCL-CDA and PCL-CTA appeared to be immiscible. A double-melting behavior was showed for PCL-CAB and PCL-CTA blends. As these peaks did not shift by varying the heating rate of DSC runs, this behavior can be due to melting of two populations of crystals of PCL, which may be different in size. On the other hand, blends of PCL containing a low amount of CAB or CDA seem to develop more crystallinity for the PCL than this polymer alone. The solvent seems to have a certain influence on the thermal and morphological behaviors of the as-cast blends of these three systems, affecting the extent of crystallinity of PCL, as well as its Tm and ΔHf. This finding is discussed in the light of WAXS and polarizing optical microscopy results. © 1994 John Wiley & Sons, Inc.
    Additional Material: 20 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Publication Date: 2019-07-13
    Description: Ozone profiles obtained at Boulder, Colorado and Wallops Island, Virginia indicate that ozone was about 25% below normal during the winter and spring of 1992-93 in the 12-22 km region. This large ozone reduction in the lower stratosphere, though sometimes partially compensated by higher than normal ozone above 24 km, was responsible for the low total column ozone values observed across the United States during this period. Normal temperatures throughout the low ozone region suggest that transport-related effects are probably not the most important cause of the ozone deficits. This region of low ozone at Boulder corresponds closely with the location of the enhanced H2SO4/H2O aerosol from the Pinatubo eruption of 1991 as measured near Boulder and at Laramie, Wyoming. Trajectory analyses suggest that except at low altitudes in spring, air parcels on the days of the ozone measurements generally arrived at Boulder from higher latitude, although seldom higher than 60 deg N, and hence may have been subjected to heterogeneous chemical processing on the surface of Pinatubo aerosol droplets resulting in chlorine-catalyzed ozone destruction, a process which is believed to be more effective under the lower winter temperatures and sunlight levels of higher latitudes.
    Keywords: METEOROLOGY AND CLIMATOLOGY
    Type: PAPER-93GL02526 , Geophysical Research Letters (ISSN 0094-8276); 21; 1; p. 65-68
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