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  • Polymer and Materials Science  (2)
  • CTM2008-04517; CTM2009-06269-E; CTM2010-11955-E/MAR; DATE/TIME; EMSODEV; EMSO implementation and operation: DEVelopment of instrument module; EMSO-Link; ES5110020; Fixed Point Open Ocean Observatories Network; FixO3; Implementation of the Strategy to Ensure the EMSO ERICs Long-term Sustainability; Instalació de sensors en observatorio submari expansible OBSEA; Instalacion de equipos en superfície para la ampliación de las prestaciones del observatorio submarino obsea; Instrumentación y tecnologías aplicadas al estudio, caracterización y explotación sostenible del medio marino; Integración de sensores para monitorización submarina en una red con sincronización temporal; Interoperabilidad e instrumentación de plataformas autónomas marinas para la monitorización sísmica; Interoperabilidad en redes de sensores marinos y ambientales; Interoperabilitat en xarxes de sensors marins i ambientals; INTIMAS; INTMARSIS; JERICO-NEXT; Joint European Research Infrastructure network for Coastal Observatory – Novel European eXpertise for coastal observaTories; MarInTech; MELOA; MeteoMet2; Metrology for essential climate variables; Multi-purpose/Multi-sensor Extra Light Oceanography Apparatua; NeXOS; Next generation, Cost-effective, Compact, Multifunctional Web Enabled Ocean Sensor Systems Empowering Marine, Maritime and Fisheries Management; Nuevas tecnologías para el seguimiento de la acidificación marina en el espacio natural Costa del Garraf; OBSEA:OBSEA:2009-05; Operatividad laboratorio submarino obsea; OPOBSEA; Pressure, atmospheric; PT2009-0080; Redes de sensores submarinos acústicos aplicados al seguimiento de especies de interes comercial; Redes de sensores submarinos autónomos y cableados aplicados a la monitorización remota de indicadores biológicos; RESBAC; RESBIO; SARTI-MAR; SINEOS; Sismòmetre marí digital amb connexió per cable; Sistemas inalambricos para la extension de observatorios submarinos; Sistemes dAdquisició Remota de dades i Tractament de la Informació en el Medi Marí; Temperature, air; VALTEC09-1-0059; Weather Station, 150WX, Airmar; Wind direction; Wind speed
  • General Chemistry
  • Organic Chemistry
  • Size-at-age
  • 1990-1994  (3)
  • 1994  (3)
Collection
Keywords
  • Polymer and Materials Science  (2)
  • CTM2008-04517; CTM2009-06269-E; CTM2010-11955-E/MAR; DATE/TIME; EMSODEV; EMSO implementation and operation: DEVelopment of instrument module; EMSO-Link; ES5110020; Fixed Point Open Ocean Observatories Network; FixO3; Implementation of the Strategy to Ensure the EMSO ERICs Long-term Sustainability; Instalació de sensors en observatorio submari expansible OBSEA; Instalacion de equipos en superfície para la ampliación de las prestaciones del observatorio submarino obsea; Instrumentación y tecnologías aplicadas al estudio, caracterización y explotación sostenible del medio marino; Integración de sensores para monitorización submarina en una red con sincronización temporal; Interoperabilidad e instrumentación de plataformas autónomas marinas para la monitorización sísmica; Interoperabilidad en redes de sensores marinos y ambientales; Interoperabilitat en xarxes de sensors marins i ambientals; INTIMAS; INTMARSIS; JERICO-NEXT; Joint European Research Infrastructure network for Coastal Observatory – Novel European eXpertise for coastal observaTories; MarInTech; MELOA; MeteoMet2; Metrology for essential climate variables; Multi-purpose/Multi-sensor Extra Light Oceanography Apparatua; NeXOS; Next generation, Cost-effective, Compact, Multifunctional Web Enabled Ocean Sensor Systems Empowering Marine, Maritime and Fisheries Management; Nuevas tecnologías para el seguimiento de la acidificación marina en el espacio natural Costa del Garraf; OBSEA:OBSEA:2009-05; Operatividad laboratorio submarino obsea; OPOBSEA; Pressure, atmospheric; PT2009-0080; Redes de sensores submarinos acústicos aplicados al seguimiento de especies de interes comercial; Redes de sensores submarinos autónomos y cableados aplicados a la monitorización remota de indicadores biológicos; RESBAC; RESBIO; SARTI-MAR; SINEOS; Sismòmetre marí digital amb connexió per cable; Sistemas inalambricos para la extension de observatorios submarinos; Sistemes dAdquisició Remota de dades i Tractament de la Informació en el Medi Marí; Temperature, air; VALTEC09-1-0059; Weather Station, 150WX, Airmar; Wind direction; Wind speed
  • General Chemistry
  • Organic Chemistry
  • Size-at-age
    • +
Publisher
Years
  • 1990-1994  (3)
Year
  • 1
    Electronic Resource
    Electronic Resource
    Theoretical Calculations of β-Lactam Antibiotics. Part VI. AM1 calculations of alkaline hydrolysis of clavulanic acid (1994)
    New York, NY : Wiley-Blackwell
    Helvetica Chimica Acta 77 (1994), S. 1557-1569 
    Details
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The gas-phase basic hydrolysis of clavulanic acid (a) was studied by using the AM1 semi-empirical method. The results obtained show that the hydroxyethylidene side chain at C(2) is pivotal to the stability of the different reaction products involved. The products with an open oxazolidine ring are more stable than those with a closed ring fused to the β-lactam ring. This behaviour differs from that of penicillins and cephalosporins where the most stable degradation products are those with an intact thiazolidine or dihydrothiazine ring, respectively, fused to the β-lactam ring. The different chemical reactivity of clavulanic acid relative to penicillins and cephalosporins could explain the disparate behaviour of the latter two types of compound towards β-lactamases. Once the acyl-enzyme intermediate of clavulanic acid has been formed, it can evolve with cleavage of the oxazolidine ring to form a difficult to deacylate compound.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/hlca.19940770611
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  • 2
    Electronic Resource
    Electronic Resource
    The interaction of poly(methacrylate) radicals with diphenyldiacetylenes (1994)
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 32 (1994), S. 3147-3151 
    Details
    ISSN: 0887-624X
    Keywords: polymerization of methyl methacrylate ; diphenylbutadiynes ; ESR spectra ; radical stabilization ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The free radical polymerization of methyl methacrylate (MMA) in the presence of p,p′- disubstituted diphenylbutadiynes was studied. Both the rate and degree of polymerization are somewhat lowered by the presence of the diynes, but the propagating radicals were stabilized giving clear ESR signals of the interacted polyMMA radicals at the polymerization temperature of 70°C. The magnitude of the interaction depended on the electron density of the diynes; in the cases of diphenylbutadiyne and dimethoxycarbonyldiphenylbutadiyne, the intoraction was more enhanced showing ESR signals with smaller spectra widths and increasing the number of radicals with the polymerization time, while in the cases of electron donor-substituted diynes the interaction was weaker and the radical concentration remained constant during the polymerization. These systems are considered to be examples of the stabilization of transient radicals by the direct interaction of radicals with additives without formation or breaking of chemical bonds. No diacetylenic group was found in the polyMMA obtained. © 1994 John Wiley & Sons, Inc.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pola.1994.080321615
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  • 3
    Electronic Resource
    Electronic Resource
    Improvement of the properties of polyarylate reinforced with liquid crystalline polymers (1994)
    New York, NY : Wiley-Blackwell
    Polymers for Advanced Technologies 5 (1994), S. 423-427 
    Details
    ISSN: 1042-7147
    Keywords: Liquid crystalline polymers ; Blends ; Viscosity reduction ; Reinforcing action ; Microfibrillar morphology ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Blends of polyarylate of bisphenol A, PAr, with two commercial main chain liquid crystalline polymers, Vectra A950 and Vectra B950, are studied. From dynamic viscoelastic measurements it is deduced that both systems (PAr/Vectra A950 and PAr/Vectra B950) are immiscible and scanning electron microscopy (SEM) micrographs show the presence of spherical domains of the liquid crystalline polymer when PAr constitutes the matrix. Extrusion capillary measurements reveal that, under conditions of temperature and shear rate similar to those of processing, the viscosity is reduced to approximately 10% of its value when the content of liquid crystalline polymer is only 20%. This great improvement of the rheological properties is observed in both PAr/Vectra A950 and PAr/Vectra B950 blends. The effect of draw ratio on Young's modulus for different compositions is also analyzed, pointing out the reinforcing action of both liquid crystalline polymers on polyarylate: for instance, 20% of Vectra B950 in the blend gives rise to a 700% increase of the modulus of fibres prepared at a draw ratio of 50. SEM of the extrudates reveals that the spherical domains are elongated at the entrance of the capillary giving rise to a microfibrillar morphology which is related to the excellent rheological and mechanical properties of the blends.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pat.1994.220050804
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