ALBERT

All Library Books, journals and Electronic Records Telegrafenberg

X
feed icon rss

Your email was sent successfully. Check your inbox.

An error occurred while sending the email. Please try again.

Proceed reservation?

Export
Filter
  • Articles  (37)
  • Wiley-Blackwell  (18)
  • Oxford University Press  (10)
  • American Association for the Advancement of Science  (9)
  • American Chemical Society (ACS)
  • 1990-1994  (37)
  • 1994  (20)
  • 1993  (17)
Collection
  • Articles  (37)
Source
Keywords
Publisher
Years
  • 1990-1994  (37)
Year
Journal
Topic
  • 1
    Electronic Resource
    Electronic Resource
    An investigation of the physico-chemical basis of foaming in fungal fermentations (1994)
    New York, NY [u.a.] : Wiley-Blackwell
    Biotechnology and Bioengineering 44 (1994), S. 801-807 
    Details
    ISSN: 0006-3592
    Keywords: foaming ; fermentations ; biochemical basis ; biosurfactants ; Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A detailed physico-chemical analysis of two foaming fungal fermentations was carried out to identify that key groups of compounds responsible for foam formation. Fermentations were carried out on a 20-L scale in a stirred aerated tank, over 7 days, using a commercial, defined medium. The organisms investigated were Penicillium herqueii, a hyphomycete, and an unidentified Ingoldian fungus. Samples of broth and, where possible, foam were analyzed to determine which groups of compounds were concentrated into generated foams. Surface tension, bulk viscosity, and antifoam A concentration were additionally determined in broth samples. To date the cause of foaming in fermentations has been attributed to the surfactant properties of extracellular proteins. This assumption was tested and found to be incomplete as many additional groups of biochemicals were found to be enriched into the foam. The results of the investigation revealed the presence of proteins, carbohydrates, α-keto acids, and lipophilic biosurfactants, particularly extracellular pigments, enriched within stable foams. © 1994 John Wiley & Sons, Inc.
    Additional Material: 10 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/bit.260440705
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 2
    Electronic Resource
    Electronic Resource
    Rapid screening for metabolite overproduction in fermentor broths, using pyrolysis mass spectrometry with multivariate calibration and artificial neural networks (1994)
    New York, NY [u.a.] : Wiley-Blackwell
    Biotechnology and Bioengineering 44 (1994), S. 1205-1216 
    Details
    ISSN: 0006-3592
    Keywords: pyrolysis mass spectrometry ; artificial neural networks ; fermentor broths ; regression analysis ; chemometrics ; Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Binary mixtures of model systems consisting of the antibiotic ampicillin with either Escherichia coli or Staphylococcus auresu were subjected to pyrolysis mass spectrometry (PyMS). To deconvolute the pyrolysis mass spectra, so as to obtain quantitative information on the concentration of ampicilin in the mixtures, partial least squares regression (PLS), principal components regression (PCR), and fully interconnected feedforward artificial neural networks (ANNs) were studied. In the latter case, the weights were modified using the standard backpropagation algorithm, and the nodes used a sigmoidal squsahing funciton. It was found that each of the methods could be used to provide calibration models which gave excellent predictions for the concentrations of ampicillin in samples on which they had not been trained. Furthermore, ANNs trained to predict the amount of ampicilin in E. coli were able to generalise so as to predict the concentration of ampicillin in a S. aureus background, illustrating the robustness of ANNs to rather substantial variations in the biological background. The PyMS of the complex mixture of ampicilin in bacteria could not be expressed simply in terms of additive combinations of the spectra describing the pure components of the mixtures and their relative concentrations. Intermolecular reactions took place in the pyrolysate, leading to a lack of superposition of the spectral components and to a dependence of the normalized mass spectrum on sample size. Samples from fermentations of a single organism in a complex production medium were also analyzed quantitatively for a drug of commercial interest. The drug could also be quantified in a variety of mutant-producing strains cultivated in the same medium. The combination of PyMS and ANNs constitutes a novel, rapid, and convenient method for exploitation in strain improvement screening programs. © 1994 John Wiley & Sons, Inc.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/bit.260441008
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 3
    Electronic Resource
    Electronic Resource
    Trapping efficiencies of various collection solvents after supercritical fluid extraction (1993)
    Weinheim : Wiley-Blackwell
    Journal of High Resolution Chromatography 16 (1993), S. 713-716 
    Details
    ISSN: 0935-6304
    Keywords: SFE ; Supercritical carbon dioxide ; Sand ; Test mixture ; Solvent trapping ; Solvent mixtures ; Trapping efficiency ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: A polarity test mix consisting of acetophenone, N, N-dimethylaniline, naphthalene, decanoic acid, 2-naphthol, and n-tetracosane was spiked onto sand, and extracted with supercritical carbon dioxide, to evaluate the collection efficiency of various solvents and solvent mixtures. Nine single collection solvent systems and four mixed collection solvent systems were studied. When one-component collection solvents were employed, quantitative (above 90%) recovery of all analytes was not possible. With mixed collection solvents, recoveries of 90% or better with all analytes studied were possible.
    Additional Material: 4 Tab.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/jhrc.1240161208
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 4
    Electronic Resource
    Electronic Resource
    A macromolecular deformation model to estimate viscoelastic flow effects in polymer melts (1993)
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 33 (1993), S. 437-444 
    Details
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The elastic deformation of polymer macromolecules in a shear field is used as the basis for quantitative predictions of viscoelastic flow effects in a polymer melt. Non-Newtonian viscosity, capillary end correction factor, maximum die swell, and die swell profile of a polymer melt are predicted by the model. All these effects can be reduced to generic master curves, which are independent of polymer type. Macromolecular deformation also influences the brittle failure strength of a processed polymer glass. The model gives simple and accurate estimates of practically important processing effects, and uses fitting parameters with the clear physical identity of viscoelastic constants, which follow well established trends with respect to changes in polymer composition or processing conditions.
    Additional Material: 11 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pen.760330710
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 5
    Electronic Resource
    Electronic Resource
    A review on the tensile strength of polyethylene fibers (1994)
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 34 (1994), S. 266-268 
    Details
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pen.760340406
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 6
    Electronic Resource
    Electronic Resource
    Miscible blends of modified poly(aryl ether ketones) with aromatic polyimides (1993)
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part B: Polymer Physics 31 (1993), S. 821-830 
    Details
    ISSN: 0887-6266
    Keywords: blends of modified PEEK with aromatic polyimides ; miscibility of blends of modified PEEK with aromatic polyimides ; Spectra, IR and UV, of blends of modified PEEK with aromatic polyimides ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The phase behavior of binary blends of poly(ether ether ketone) (PEEK), sulfonated PEEK, and sulfamidated PEEK with aromatic polyimides is reported. PEEK was determined to be immiscible with a poly(amide imide) (TORLON 4000T). Blends of sulfonated and sulfamidated PEEK with this poly(amide imide), however, are reported here to be miscible in all proportions. Blends of sulfonated PEEK and a poly(ether imide) (ULTEM 1000) are also reported to be miscible. Spectroscopic investigations of the intermolecular interactions suggest that formation of electron donoracceptor complexes between the sulfonated/sulfamidated phenylene rings of the PEEKs and the n-phenylene units of the polyimides are responsible for this miscibility. © 1993 John Wiley & Sons, Inc.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/polb.1993.090310710
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 7
    Electronic Resource
    Electronic Resource
    Melting behavior of poly(ether ether ketone) in its blends with poly(ether imide) (1993)
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part B: Polymer Physics 31 (1993), S. 1845-1850 
    Details
    ISSN: 0887-6266
    Keywords: melting behavior of PEEK/PEI blends ; equilibrium melting point ; crystal reorganization ; interlamellar segregation ; melting point depression ; interaction parameter ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: We detail the melting behavior of poly(ether ether ketone) (PEEK) and investigate its melting behavior in miscible blends with poly(ether imide) (PEI). The determination of the equilibrium melting point (Tm0) of PEEK is discussed by considering its inhomogeneous morphology. Tm0 is obtained by a long extrapolation of a Hoffman-Weeks plot to 384°C. Hindrance of PEEK crystal reorganization induced by PEI during heating is observed over the blend composition investigated (20-75 wt % PEEK). This behavior is correlated with the incorporation of PEI in the interlamellar zones of PEEK crystals. The interaction parameter χ of PEEK/PEI blends is estimated by the equilibrium melting point depression. This gives the interaction density B = -1.2 cal/cm3, and x = -0.40 at 400°C. © 1993 John Wiley & Sons, Inc.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/polb.1993.090311217
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 8
    Electronic Resource
    Electronic Resource
    Miscibility of a polyarylate with a liquid crystalline copolyester (1993)
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part B: Polymer Physics 31 (1993), S. 1067-1073 
    Details
    ISSN: 0887-6266
    Keywords: polyarylate ; copolyester ; liquid crystal ; transesterfication ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The miscibility has been investigated for binary blends of a polyarylate (PAr) with a liquid crystalline copolyester of p-hydroxybenzoate and ethylene terephthalate units in a 6/4 molar ratio (PET/PHB). The binary blends were prepared by solution precipitation. The transitions of the PET/PHB have been measured with a rheometrics dynamic spectrometer. The phases in blends have been studied with a differential scanning calorimeter, by ther-mogravimetry and with a polarizing optical microscope. The blends exhibit two glass transitions (Tgs) over the composition range 10-90 wt %. The amorphous PET phase from the PET-PHB is found to be partially miscible with PAr, which leads to a decrease of the PAr Tg. The amount of this partially miscible portion of PET has been estimated by the Couch-man equation. On heat treatment of the blends at 250 to 300°C, transesterficiation takes place, as judged by the shift of the higher of the two Tgs. © 1993 John Wiley & Sons, Inc.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/polb.1993.090310901
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 9
    Electronic Resource
    Electronic Resource
    Equibiaxial deformation of poly(4-methyl-1-pentene) by a forging process (1994)
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part B: Polymer Physics 32 (1994), S. 535-540 
    Details
    ISSN: 0887-6266
    Keywords: poly (4-methyl-1-pentene) ; isotactic polypropylene ; biaxial deformation ; stress-strain behavior ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Poly(4-methyl-1-pentene) (PMP) has been uniaxially compressed by a forging (equibiaxial) process. The rheology of the process has been examined for this semicrystalline polyolefin, melting point about 235°C. The yield energy, area under the compressive stress-strain curve up to the yield point, as a function of temperature was found to consist of two linear components of different slope. These two linear relations arise from the glassy and crystalline phases of PMP. The intercept temperature (Ti) at zero yield energy for the glassy phase has been evaluated. The attainable maximum compression ratio without sample rupture (CRmax) increased steadily on increasing forging temperature above Ti, and below Tm. In this range, the crystalline relaxation temperature (Tc), evaluated from an Arrhenius plot of yield stress was 160°C. Above Tc, a CRmax of 240 was reached. This value is five times higher than that attained for isotactic polypropylene (i-PP). However, the draw efficiency evaluated by elastic recovery in the plane direction of PMP (0.76) is lower than for i-PP (0.97). Differential scanning calorimetry analyses showed that the melting peak became a complex doublet on increasing compression ratio ( 〉 100). The drawing and stress-strain behavior of PMP are compared with i-PP. © 1994 John Wiley & Sons, Inc.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/polb.1994.090320314
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 10
    Electronic Resource
    Electronic Resource
    Properties of oriented polyethylene bars of large cross section (1994)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 52 (1994), S. 1211-1215 
    Details
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The solid-state extrusion technique has been used to prepare uniaxially oriented polyethylene bars with rectangular end cross sections of 6 × 50 mm2. They were extruded at 110°C from billets of high density polyethylene. The tensile modulus and strength for the extrudate with a draw ratio (DR) of 14 were 17.9 and 0.32 GPa, respectively. The mechanicals were also measured in the transverse direction by means of the proportional elastic limit (PEL) bending test. The PEL results do not change after DR 14 due to the fibrillate structure formation. Crystallinity and shrinkage tests were made on samples taken over the bar cross section. They show that uniform properties were achieved across the width of the bar with proper die design. © 1994 John Wiley & Sons, Inc.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/app.1994.070520905
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
Close ⊗
This website uses cookies and the analysis tool Matomo. More information can be found here...