ISSN:
0170-2041
Keywords:
Lysoglycolipids
;
glyceryl ethers
;
Glycerol, 2-O-benzyl-1-O-hexadecyl
;
Carbohydrates
;
Chemistry
;
Organic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Stereoselective Synthesis of 2-O-Benzyl-1-O-hexadecyl-sn-glycerolDue to the versatility of 2-O-benzyl-1-O-hexadecyl-sn-glycerol (7) as building block for various alkyl ether lipids and alkyl ether lyso-lipids, 7 was prepared from D-mannit following two different strategies. The final product 7 was obtained either via the intermediate 1,2-O-isopropylidene-sn-glycerol (1) or via 3,4-O-isopropylidene-D-mannit (8) in an overall yield of 6% or 11%, respectively.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/jlac.199219920110
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