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  • critical phenomena  (4)
  • Chemistry  (1)
  • *Light
  • Electronic structure and strongly correlated systems
  • 1990-1994  (5)
  • 1993  (3)
  • 1991  (2)
Collection
Publisher
Years
  • 1990-1994  (5)
Year
  • 1
    Electronic Resource
    Electronic Resource
    Springer
    International journal of thermophysics 14 (1993), S. 1187-1200 
    ISSN: 1572-9567
    Keywords: binary mixtures ; critical phenomena ; equation of state ; ethane ; methane ; plait point ; specific heat
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract An isomorphic equation of state for near-critical binary mixtures is used to represent equation of state and specific heat data for mixtures of methane and ethane in a substantial range of densities and temperatures around the critical line.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    International journal of thermophysics 14 (1993), S. 1187-1200 
    ISSN: 1572-9567
    Keywords: binary mixtures ; critical phenomena ; equation of state ; ethane ; methane ; plait point ; specific heat
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract An isomorphic equation of state for near-critical binary mixtures is used to represent equation of state and specific heat data for mixtures of methane and ethane in a substantial range of densities and temperatures around the critical line.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Springer
    International journal of thermophysics 12 (1991), S. 877-895 
    ISSN: 1572-9567
    Keywords: critical phenomena ; crossover equation of state ; specific heat ; aqueous ionic solutions
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract A new universal scaled equation of state for one-component fluids, binary mixtures, and ionic solutions, which represents the thermodynamic behavior of fluids in a wide range of temperatures and densities including the critical region, is proposed. Near the critical point this equation reduces to a theoretically based scaled equation including the leading nonasymptotic (Wegner) correction and a correction accounting for the asymmetry of fluids with respect to the critical isochore. Far away from the critical point the new equation goes over into the classical Landau expansion (van der Waals equation). The new equation is applied to represent experimental P-V-T data for H2O and CO2, as well as to represent C v,x data for dilute aqueous solutions of NaCl. A crossover from fluctuation to mean-field behavior is observed at increased concentrations of NaCl. A universal crossover function for the heat capacity C v,x of one-component fluids and binary mixtures is presented.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Springer
    International journal of thermophysics 14 (1993), S. 1-32 
    ISSN: 1572-9567
    Keywords: critical phenomena ; equation of state ; ethane ; methane ; sound velocity ; specific heat ; thermodynamic properties
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract An improved parametric equation for the thermodynamic properties of fluids is presented that incorporates the crossover from singular thermodynamic behavior in the immediate vicinity of the critical point to regular thermodynamic behavior far away from the critical point. Based on a comparison with experimental data for ethane and methane, it is demonstrated that the crossover model is capable of representing the thermodynamic properties of fluids in a large range of temperatures and densities around the critical point.
    Type of Medium: Electronic Resource
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  • 5
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: A tool was developed for enhancement of plasmid penetration into an intact cell, based on increasing DNA hydrophobicity via inclusion into a soluble interpolyelectrolyte complex (IPC) with polycations. The characteristics of formation of DNA IPC with synthetic polycations [poly(N-ethyl-4-vinylpyridinium)bromide (PVP) and PVP modified with 3% of N-cetyl-4-vinylpyridinium units (PVP-C)] were studied using ultracentrifugation and polyacrylamide gel electrophoresis methods. The conditions were established under which the mixing of DNA and polycation aqueous solutions results in the selfassembly of soluble IPC species. Incorporation of DNA into IPC results in the enhancement of DNA binding with isolated Bacillus subtilis membranes. A considerable increase in the efficiency of transformation of B. subtilis cells with pBC16 plasmid resulted from incorporation of the plasmid into the IPC with PVP and CVP.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
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