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  • American Institute of Physics (AIP)  (2)
  • Wiley-Blackwell  (1)
  • 2005-2009
  • 1990-1994  (3)
  • 1935-1939
  • 1991  (1)
  • 1990  (2)
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  • 2005-2009
  • 1990-1994  (3)
  • 1935-1939
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  • 1
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Review of Scientific Instruments 61 (1990), S. 493-495 
    ISSN: 1089-7623
    Source: AIP Digital Archive
    Topics: Physics , Electrical Engineering, Measurement and Control Technology
    Notes: The energy distributions of ions and electrons extracted from a duoplasmatron ion source have been measured by a 127° cylinder spectrometer, providing information on the axial potential distribution in the source. The energy resolution of the spectrometer was about ±1 eV. Compared to measurements with Langmuir probes, this method has the advantage that the plasma potential is not disturbed. The energy spectrum of the extracted ions shows up to three peaks, which are related to different places of ionization in the source. The total energy spread is up to 100 eV. This energy spread can be influenced (down to 6 eV) by the potential of the expansion cup. Surprisingly, 90% of the extracted electrons are not created at the cathode but in the plasma of the intermediate electrode. This knowedge allows a better optimization of the source by independent regulation of gas pressure, intermediate electrode potential, and cathode potential. For optimum ionization of the working gas the potential of the intermediate electrode can be regulated so that the electron energy reaches the optimum value for the ionization in front of the anode and the energy and the intensity of the electron current is regulated by means of the potential of the expansion cup. These parameters strongly influence the beam quality.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Review of Scientific Instruments 61 (1990), S. 327-329 
    ISSN: 1089-7623
    Source: AIP Digital Archive
    Topics: Physics , Electrical Engineering, Measurement and Control Technology
    Notes: The small multicusp ion source developed at Lawrence Berkeley Laboratory (LBL) has been equipped with a low voltage ratio, single aperture extraction system. The influence of the potential of the plasma electrode and of a dipole filter field on the beam emittance are measured. A simple method to reduce hash is suggested. The aim of these investigations is to produce nitrogen ion beams with a high atomic ion fraction and a low emittance as required for a RFQ-accelerator, which will be built for ion implantation.
    Type of Medium: Electronic Resource
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  • 3
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Substituted Alkinyles as Axial Ligands at Hemine Like Bound Iron(III) - Incorporation into a Spectrochemical Series.Substituted lithium alkynyles Li—C≡C—R (R = tBu, Ph, p-Cl—C6H4, Me3Si, iPr3Si, Ph3Si) react with the hemine like macrocyclic iron(III) complex 6,13-di(ethoxycarbonyl)-5, 14-dimethyl-1, 4, 8, 11-tetraazatetradeca-4,6,12,14-tetraenato[2-]iron(III)-iodide (formula 2;) in tetrahydrofuran to form anionic low-spin di-adducts [fe(C≡C—R)2]-. The incorporation of the alkynyles into a spectrochemical series of the axial ligands (studied by the sharp equatorial-ligand-to-metal CT absorption band) results in the wavelength-sequence (nm): OH- (≍ 510) « N3- (≍ 625) 〈 tBu—C≡C- (664) 〈 NH3 (666) 〈 Ph—C≡C- (692) 〈 Ph—NH2 (695) 〈 Me3Si—C≡C- (698) 〈 SCN- (713) 〈 Ph3Si—C ≡ C- (716) 〈 CN- (739) 〈 4-picoline (759) 〈 pyridine (765) 〈 nicotinamide (776) 〈 methylnicotinat (788) 〈 pyrazine (798) and points to a significant π-acceptor ability of the silyl substituents.
    Additional Material: 2 Tab.
    Type of Medium: Electronic Resource
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