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  • Springer  (10)
  • Wiley  (7)
  • American Institute of Physics (AIP)  (4)
  • American Association for the Advancement of Science (AAAS)  (1)
  • Periodicals Archive Online (PAO)  (1)
  • 1985-1989  (23)
  • 1989  (23)
  • 1
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 90 (1989), S. 7482-7491 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: A molecular dynamical study of one methane molecule in a cavity of NaA zeolite is performed in order to compare calculated to experimental data obtained by infrared spectroscopy and neutron scattering experiments in the temperature range 300–30 K. The calculation shows the trajectory of the molecule in the cavity and then the occupied volume as a function of energy. It allows the calculation of average quantities and correlation functions: (i) the mean field felt by the molecule comparable to the field responsible for the induced infrared band ν1, (ii) the average of the potential energy (to be compared to the heat of adsorption) and of the velocity squared, (iii) the external frequency distribution, and (iv) the position autocorrelation function which is related to the dynamical structure factor seen by neutron scattering.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 91 (1989), S. 5097-5102 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: The diffusion of hydrogen in NaA zeolite was studied by incoherent neutron scattering. An experiment was carried out on samples loaded with 1.2 to 3.4 molecules per cavity and at several temperatures from 70 to 150 K. The angular (θ) dependence of the elastic and quasielastic intensities shows that the H2 molecule has a translational motion in a nonrestricted volume. A diffusion model where the molecule undergoes isotropic jumps of mean length l¯=3.9 A(ring) independent of temperature and is at rest for a time τ0 between two jumps accounts for the width of the quasielastic scattering in the entire (θ,T) range (τ0=10.8 ps at T=100 K). This leads to a diffusion coefficient D(cm2/s)=6×10−4 exp(E/RT) with E=2 kJ/mol for the less loaded samples. The diffusion coefficient increases slightly with the loading.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 54 (1989), S. 1466-1468 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Hg1−xCdxTe/Hg1−xZnxTe superlattices with constant Hg content have been grown by molecular beam epitaxy for x between 0.22 and 0.4. Films grown at 180 °C show x-ray satellite peaks to the fourteenth order. An annealing study conducted between 185 and 225 °C shows enhanced stability compared to HgTe/CdTe superlattices.
    Type of Medium: Electronic Resource
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  • 4
    ISSN: 1089-7623
    Source: AIP Digital Archive
    Topics: Physics , Electrical Engineering, Measurement and Control Technology
    Notes: We have developed at LURE a multiwire proportional chamber with a spherical drift space. The wire chamber consists of two cathode planes, comprising 512 wires with a spacing of 1 mm, set on both sides of the anodic plane. The drift space, a gas filled region bounded by two spherically curved electrodes 144 mm apart, offers several advantages: high quantum efficiency, no parallax effect, equivalent spatial resolution in both directions, and smoothing of the pulsed structure of the synchrotron radiation. The gaseous mixture of argon-xenon (58%), ethane (40%), and ethyl alcohol (2%) is circulated in a closed circuit and is continuously purified. Ethyl alcohol, which avoids electrical discharges and sparks, is essential to operate the instrument at high counting rates (〉300 000 events/s). The signal processing, which makes use of one amplifier per cathode wire and of fast priority encoders, determines both coordinates with a resolution of 1 mm and a dead time of 240 ns. Each encoded event is stored into a 512×512 16 bit CAMAC histogramming memory. The experiment is controlled by a PDP11/34 linked to a VAX by a direct memory access channel. A complete set of programs, which performs the data collection and an off line data reduction, is operational. The adaptation of madnes, a general software package which performs an on line data reduction, is under way. Data, collected on a lysozyme crystal to 3.4-A(ring) resolution, give a reliability factor based on intensities of equivalent reflections of 4.7% without absorption corrections; the variation of the detector efficiency is 〈2.7%. A new version of the instrument is under realization. The position encoder, which uses flash ADCs and signal processors, has a resolution of 0.5 mm. Data are stored into a 1024×1024 16 bit VME histogramming memory linked to a micro VAX.
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  • 5
    Electronic Resource
    Electronic Resource
    Springer
    Journal of theoretical probability 2 (1989), S. 121-128 
    ISSN: 1572-9230
    Keywords: Random walks ; cover times ; graphs ; infinite graphs ; trees
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mathematics
    Notes: Abstract This article deals with random walks on arbitrary graphs. We consider the cover time of finite graphs. That is, we study the expected time needed for a random walk on a finite graph to visit every vertex at least once. We establish an upper bound ofO(n 2) for the expectation of the cover time for regular (or nearly regular) graphs. We prove a lower bound of Ω(n logn) for the expected cover time for trees. We present examples showing all our bounds to be tight.
    Type of Medium: Electronic Resource
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  • 6
    ISSN: 1572-879X
    Keywords: Electrochemical oxidation ; alkenoic acids on platinum
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract Studies of the electrochemical oxidation of a series of straight-chain terminal alkenoic acids adsorbed at a Pt(111) electrode surface are reported. Compounds adsorbed were: propenoic acid (acrylic acid, PPA); 3-butenoic acid (vinylacetic acid, 3BTA); 4-pentenoic acid (allylacetic acid, 4PTA); 6-heptenoic acid (6HPA); and 10-undecenoic acid (10UDA). Vibrational spectra of adsorbed layers were obtained by use of electron energy-loss spectroscopy (EELS). Molecular packing densities were measured by use of Auger spectroscopy. Electrochemical oxidation of each adsorbed layer was explored by means of cyclic voltammetry in aqueous inert electrolyte (KF/HF). As the analogous aliphatic acids are not chemisorbed at Pt under the same conditions, the alkenoic acids evidently adsorb at Pt(111) predominantly through the C=C double bond. Molecular packing densities indicate that the carboxylic acid moiety is in contact with the Pt surface only in the case of PPA. EELS spectra also indicate that the carboxylate groups (other than in PPA) are present as pendants. The carboxylic acid O-H stretching bands of most of the adsorbed acids are red-shifted and broadened, evidently due to extensive intermolecular hydrogen bonding; the exceptions are PPA, for which the interaction is primarily with the Pt surface, and 3BTA, for which intermolecular interaction between the carboxylic acid pendants is apparently prevented by steric considerations. The surface-attached carboxylic acid moieties react with KOH solution, leading to retention of K+ ions, detected by Auger spectroscopy, and to changes in the vibrational spectra indicative of carboxylate anions; reactivity toward KOH decreases with chain length. Adsorbed alkenoic acids at Pt(111) surfaces are stable in water and in vacuum. Oxidation of the adsorbed short-chain acids PPA and 3BTA proceeds to completion, forming CO2 as the principal product. Oxidation of the adsorbed long-chain acids converts the C=C moiety to 2CO2, and transforms the remainder of the molecule to an unadsorbed diacid (likely possibilities are malonic acid from 4PTA; glutaric acid from 6HPA; and heptane-1,7-dioic acid from 10UDA).
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  • 7
    Electronic Resource
    Electronic Resource
    Springer
    Mathematische Annalen 285 (1989), S. 141-160 
    ISSN: 1432-1807
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mathematics
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  • 8
    Electronic Resource
    Electronic Resource
    Springer
    Marketing letters 1 (1989), S. 55-69 
    ISSN: 1573-059X
    Source: Springer Online Journal Archives 1860-2000
    Topics: Economics
    Notes: Abstract The purpose of this article is to describe shopping trip behavior empirically using shopping trip data. A better understanding of this aspect of the purchase process can assist in generating testable hypotheses as to how the shopping trip decision may influence other choice decisions.
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  • 9
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    Ithaca, N.Y. : Periodicals Archive Online (PAO)
    Industrial and Labor Relations Review. 42:3 (1989:Apr.) 472 
    ISSN: 0019-7939
    Topics: Economics
    Description / Table of Contents: Human Resources, Personnel, and Organizational Behavior
    Notes: BOOK REVIEWS
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  • 10
    Electronic Resource
    Electronic Resource
    Springer
    Research in nondestructive evaluation 1 (1989), S. 167-179 
    ISSN: 1432-2110
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract A method for reconstructing radially varying conductivity profiles in cylindrical conductors is described. Solenoidal driving and sensing coils surround the cylindrical sample and an AC magnetic field applied by the driving solenoid induces axisymmetric eddy currents in the sample. It is shown how a radially varying conductivity profile can be recovered from measurements of the complex impedance recorded as a function of frequency, where impedance here is defined as the ratio of the induced electromotive force (EMF) in the sensing coil to the current in the driving coil. An iterative nonlinear least-squares algorithm is employed to reconstruct the profiles. Demonstrations of the reconstruction method are presented based on both simulated and experimentally recorded impedance data.
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