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  • Chemistry  (4)
  • 1985-1989  (4)
  • 1988  (4)
  • 1
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 36 (1988), S. 353-364 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: We present here a method for superposing creep measurements on polymer concrete (PC), taken at different temperatures, imposed stresses, and resin contents, onto master curves, which describe the respective responses of various PC systems and their resin binders, to compressive, tensile, and flexural loads. This treatment is extended to systems reinforced with chopped glass fiber and montmorillonite (MMT). The general applicability of this superposition is tested with creep measurements by other investigators under tensile, compressive, and flexural loads. The results make it possible to predict the long-term creep behavior of unfilled as well as reinforced glassy polymer systems at different temperatures and load conditions from limited, short-term data. Success of the multiple superposition suggests a generalized constitutive equation, which describes the creep compliance of these systems as a product of separable functions of each parameter in the form of shift factors for temperature (αT), stress (ασ), resin content (αυ), fiber reinforcement (αF), and MMT reinforcement (αM): J(PC) = JrαTασαυαFαMtm, where Jr is an appropriately chosen reference creep compliance. The time exponent m does not depend on the chemical nature of the polymer matrix.
    Additional Material: 10 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 34 (1988), S. 645-657 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The behavior of solute partial molar enthalpies in dilute supercritical mixtures gives rise to the well-known phenomenon of retrograde solubility (equilibrium solubility decreasing with increasing temperature at constant pressure). A mechanistic interpretation of this phenomenon in terms of the formation of large clusters of solvent molecules around solute molecules is consistent with experimentally observed retrograde behavior. Cluster formation occurs as a consequence of the unbounded increase in the solvent's compressibility arbitrarily close to the latter's critical point. At infinite dilution, the solute's partial molar volume and enthalpy grow linearly with cluster size. This means that the negative divergence of these quantities is simply a macroscopic manifestation of a “condensation” in which an increasing number of solvent molecules cluster around solute molecules. Arbitrarily close to the solvent's critical point, scaling relationships show that the decay of both solvent-solvent and solute-solvent correlation functions exhibits the same radial dependence. This functionality is thus solute-independent, and is determined exclusively by the proximity to the solvent's critical point. The locus along which thermal effects associated with cluster formation are maximized is arbitrarliy close to the solvent's critical isochore as the latter's critical point is approached.
    Additional Material: 6 Ill.
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  • 3
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Rapid Communications in Mass Spectrometry 2 (1988), S. 90-91 
    ISSN: 0951-4198
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Physics
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Cell Biochemistry and Function 6 (1988), S. 209-215 
    ISSN: 0263-6484
    Keywords: Endothelial cells ; Collagen synthesis ; Collagen matrix ; Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Medicine
    Notes: Cultured capillary endothelial cells, derived from bovine brain, and maintained on a plastic substratum synthesized predominantly interstitial collagens of which approximately 75 per cent were secreted into the medium. When grown on a native hydrated collagen type I gel, although no marked alteration in the ‘collagen synthetic pattern’ was observed, the overall level of collagen synthesis was increased by approximately 100 per cent. More dramatic, however, was the alteration in the distribution of these molecules between medium and cell layer. Interstitial collagens produced by cells grown on collagen gels were almost exclusively associated with the cell layer or collagenous gel. These studies, thus, demonstrate that an extracellular matrix may exert a considerable influence on the cellular synthetic activities and possibly cellular polarity of capillary endothelial cells.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
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