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  • American Institute of Physics (AIP)  (6)
  • Cambridge University Press  (5)
  • 1985-1989  (11)
  • 1988  (11)
  • 1
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 89 (1988), S. 608-609 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: Excitation of the NH-stretch overtone transitions of HN3 to v1=5 and 6 resulted in predissociation to HN(X) and N2(X) with lifetimes of 80+60−30 and ≤3 ns, respectively. Following excitation of either overtone, the HN fragments were formed predominantly in the symmetric F1, F3 spin–rotation states, with less than 4% population in the antisymmetric F2 levels. Fragment Doppler profiles confirmed that most of the available energy (〉96%) went into translational motion.
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  • 2
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 89 (1988), S. 5342-5343 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: Infrared pump–probe characterization of the excited state lifetimes reveals that CO bound to isolated metal sites (T1=140±20 ps) persists longer than the signal observed for CO bound to (approximate)35 A(ring) diameter metal particles (≤18 ps), suggesting paticipation of electron–hole excitations in the larger metal particles.
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  • 3
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 89 (1988), S. 230-239 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: Tunable infrared picosecond pulses in the 5 μ region have been used for time-resolved pump–probe measurements of the population relaxation lifetime (T1) of CO(v=1) stretching vibrations in a series of metal–carbonyl cluster compounds in room temperature chloroform solution. T1 was the same for symmetric (ν=2084 cm−1, 90±10 ps) and antisymmetric (2014 cm−1, 87±10 ps) modes of the dicarbonyl Rh(CO)2(C5H7O2); T1 was the same for the B1 (2092 cm−1 , 710±130 ps) and B2 (2036 cm−1, 750±90 ps) modes of Rh2(CO)4Cl2. Similarly long T1 times were found for Rh4(CO)12 (2075 cm−1, 610±65 ps) and Rh6(CO)16 (2077 cm−1, 700±100 ps). The molecule Co4(CO)12 has also been compared to the corresponding rhodium analog and it exhibits an initially fast relaxation of 47±5 ps followed by a slower 396±70 ps decay. The transient response of the more complex systems to the single frequency experiment is found to be sensitive to frequency and can exhibit bleaching, absorption, and a combination of these effects. Such behavior is attributed to overlap of the IR pulse with v=1 to v=2 and higher transitions in the M4(CO)12 (M=Rh or Co) and Rh6(CO)16 molecules. The long CO(v=1) T1 values for the metal cluster molecules suggest relaxation via multiquantum transfer of vibrational energy to adjacent M–C stretch and M–C–O bend vibrations; energy transfer to vibrational or electronic states of the central metal core seems unimportant in determining T1 for these systems.
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  • 4
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 89 (1988), S. 1378-1387 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: Multiphoton vibrational excitation of deuterated hydrazoic acid, DN3, by a CO2 laser (I=10 GW/cm2) leads to dissociation forming DN in both X 3Σ− (spin forbidden) and a 1Δ (spin allowed) electronic states. Under collisionless conditions, the nascent DN fragments were probed via laser induced fluorescence, to determine initial product state distributions. The DN(X 3Σ−) molecules are formed predominantly in the symmetric F1 and F3 spin–rotation states with little population (≤6%) in the antisymmetric F2 levels. There is no significant population (〈3%) in excited DN(3Σ−) vibrational levels. The distribution of rotational states is Boltzmann-like, characterized by a rotational "temperature'' of about 920 K for the F1, F3 states and 500 K for F2 levels. Doppler profiles showed a large kinetic energy release of about 10 100 cm−1 total in the triplet channel. The DN(1Δ) products are formed preferentially in the symmetric Δ(A'), e-labeled lambda doublet levels: Δ(A')/Δ(A‘)=1.44. The DN(1Δ) is formed with no vibrational excitation (〈2%); the rotational states are populated Boltzmann-like with a rotational "temperature'' of 425 K. Doppler profiles give a total kinetic energy of about 1500 cm−1 in this channel. These observations give information about the distribution of energy in the reactant, the location of the barriers to dissociation, and the geometry of the transition states. Alexander, Werner, and Dagdigian (accompanying article) show that the observed DN(3Σ−) spin- and DN(1Δ) Λ-doublet selectivities reflect the symmetry properties of a planar transition state and that the low degree of DN(3Σ−) rotational and vibrational excitation is also expected from the transition state geometry.
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  • 5
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 89 (1988), S. 1966-1976 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: Picosecond and nanosecond lasers and pulsed molecular beam techniques have been used to measure the infrared photodissociation spectra, the product state distributions, and the predissociation lifetimes of vibrationally excited nitric oxide dimer (NO)2 . Results for the ν1 (v=1) symmetric NO stretching mode and the ν4 (v=1) antisymmetric NO stretching mode are presented. Predissociation lifetimes are determined by time-resolved laser induced fluorescence probing of the NO monomer product appearance rate. A dramatic mode dependence of the predissociation lifetimes is observed with the higher energy ν1 mode decaying in approximately 1 ns, and the lower energy ν4 mode decaying in approximately 40 ps. The mode dependence is independent of which product state is probed. The product state distributions show that 75% to 80% of the available energy is channeled into relative translational energy of the fragments for both modes. Rotational state distributions are Boltzmann-like with temperatures ranging from 71 to 112 K depending on both the initially excited mode and on the NO product spin–orbit state. Predissociation from ν1 produces NO fragments in the 2Π1/2 and 2 Π3/2 states with equal probability. Predissociation from ν4 exhibits a propensity for producing the lower energy 2 Π1/2 spin–orbit state. The observations are discussed in terms of various vibrational predissociation mechanisms, including vibrational potential coupling and electronically nonadiabatic predissociation.
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  • 6
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 63 (1988), S. 1691-1693 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The application of an alternating field (AF) of 60-mT peak to an isotropic sample containing dilutely dispersed particles of γFe2O3 from magnetic tape causes it to become magnetically anisotropic. The anisotropy of initial susceptibility so produced can be described by an oblate ellipsoid of revolution with the unique axis aligned with the AF direction. A consequence of this effect is that an isothermal remanent magnetization (IRM) is then more easily acquired if the direct field is applied perpendicular to the previously applied AF direction than if it is applied parallel to this direction. The anisotropy of IRM acquisition at direct fields between 20 and 40 mT is an order of magnitude greater than the anisotropy of initial susceptibility and is 40% of the maximum possible value.
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  • 7
    Publication Date: 1988-04-01
    Description: SummaryFaecal output of 287 beef cows consisting of Hereford (H × H), Simmental × Hereford (S × H), Friesian × Hereford (F × H) and Brahman × Hereford (B × H) breeding was estimated using controlled release of chromic oxide (Cr2O3). All cows were from 6 to 10 years of age and had grazed on one of three pasture systems in the subtropics of New South Wales since they were 7–8 months of age. These pastures were designated as being of high, medium and low nutritive value. Faecal organic matter output (FOMO) was estimated in each of four periods (early lactation, mid lactation, late lactation, and non-lactating) during one annual production cycle.Herbage mass exceeded 2 t/ha on all pasture systems, but estimates of organic-matter digestibility, nitrogen content and pasture composition indicated large differences in pasture quality (high 〉 medium 〉 low). Live weight of cows averaged 604, 488 and 393 kg live weight on the high, medium and low pastures, respectively. There were significant differences in live weight between genotypes on the medium (B × H 〉 F × H and H × H) and low (S × H ≡ F × H ≡ B × H 〉 H × H) pastures but not on the high pasture).FOMO and dry-matter intake (DMI) differed significantly between genotypes among lactating cows on all pasture systems. Rankings on high pastures were reasonably consistent in all periods: S × H ≡ F × H ≥ B × H ≥ H × H, as were those on low pastures, B × H ≥ S × H ≡ F × H ≥ H × H. Differences on medium pastures were significant only during mid-lactation when B × H ≡ S × H ≡ F × H 〉 H × H. Significant differences between genotypes were observed among non-lactating cows on high pastures only, where H × H ≡ S × H ≡ F × H 〉 B × H. Lactating females had significantly higher FOMO and DMI than non-lactating females when compared across genotypes during early lactation on all pastures.
    Print ISSN: 0021-8596
    Electronic ISSN: 1469-5146
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
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  • 8
    Publication Date: 1988-01-01
    Description: Detailed measurements of surface topography, ice motion, snow accumulation, and ice thickness were made in January 1974 and again in December 1984, along an 8 km stake network extending from the ice sheet, across the grounding line, and on to floating ice shelf in the mouth of slow-moving Ice Stream C, which flows into the eastern side of Ross Ice Shelf, Antarctica. During the 11 years between surveys, the grounding line retreated by approximately 300 m. This was caused by net thinning of the ice shelf, which we believe to be a response to the comparatively recent, major decrease in ice discharge from Ice Stream C. Farther inland, snow accumulation is not balanced by ice discharge, and the ice stream is growing progressively thicker. There is evidence that the adjacent Ice Stream B has slowed significantly over the last decade, and this may be an early indication that this fast-moving ice stream is about to enter a period of stagnation similar to that of Ice Stream C. Indeed, these large ice streams flowing from West Antarctica into Ross Ice Shelf may oscillate between periods of relative stagnation and major activity. During active periods, large areas of ice shelf thicken and run aground on seabed to form extensive “ice plains” in the mouth of the ice stream. Ultimately, these become too large to be pushed seaward by the ice stream, which then slows down and enters a period of stagnation. During this period, the grounding line of the ice plain retreats, as we observe today in the mouth of Ice Stream C, because nearby ice shelf, no longer compressed by ice-stream motion, progressively thins. At the same time, water within the deformable till beneath the ice starts to freeze on to the base of the ice stream, and snow accumulation progressively increases the ice thickness. A new phase of activity would be initiated when the increasing gravity potential of the ice stream exceeds the total resistance of the shrinking ice plain and the thinning layer of deformable till at the bed. This could occur rapidly if the effects of the shrinking ice plain outweigh those of the thinning (and therefore stiffening) till. Otherwise, the till layer would finally become completely frozen, and the ice stream would have to thicken sufficiently to initiate significant heating by internal deformation, followed by basal melting and finally saturation of an adequate thickness of till; this could take some thousands of years.
    Print ISSN: 0260-3055
    Electronic ISSN: 1727-5644
    Topics: Geography , Geosciences
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  • 9
    Publication Date: 1988-01-01
    Description: Surface velocity and deformation, radar sounding, and aerial photography data are used to describe the flow of Ross Ice Shelf around Crary Ice Rise. A continuous band of crevasses around the ice rise now allows the complete boundary to be mapped for the first time. The dynamics of three distinctly different areas of ice flow are studied. Just up-stream of the ice rise, there is a region of ice rumples dominated by intense longitudinal compression (0.01 a−1) and lateral tension. On the south-west side of the ice rise, intense shear (0.03 a−1) dominates, with the boundary layer of affected ice-shelf motion extending over 20 km from the ice-rise edge into the ice shelf. North-west of the ice rise, a crevasse-free block of ice, 40 km × 7 km, appears to have separated from the main ice rise and is now moving with the ice shelf. We refer to such moving blocks of ice as rafts. The separation of this raft is calculated to have occurred 20 ± 10 years ago. Other possible rafts are identified, including one on the south-west side of the ice rise which appears to be in the process of separating. Mechanisms for the formation of rafts are discussed.
    Print ISSN: 0260-3055
    Electronic ISSN: 1727-5644
    Topics: Geography , Geosciences
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  • 10
    Publication Date: 1988-01-01
    Description: Detailed measurements of surface topography, ice motion, snow accumulation, and ice thickness were made in January 1974 and again in December 1984, along an 8 km stake network extending from the ice sheet, across the grounding line, and on to floating ice shelf in the mouth of slow-moving Ice Stream C, which flows into the eastern side of Ross Ice Shelf, Antarctica. During the 11 years between surveys, the grounding line retreated by approximately 300 m. This was caused by net thinning of the ice shelf, which we believe to be a response to the comparatively recent, major decrease in ice discharge from Ice Stream C. Farther inland, snow accumulation is not balanced by ice discharge, and the ice stream is growing progressively thicker.There is evidence that the adjacent Ice Stream B has slowed significantly over the last decade, and this may be an early indication that this fast-moving ice stream is about to enter a period of stagnation similar to that of Ice Stream C. Indeed, these large ice streams flowing from West Antarctica into Ross Ice Shelf may oscillate between periods of relative stagnation and major activity. During active periods, large areas of ice shelf thicken and run aground on seabed to form extensive “ice plains” in the mouth of the ice stream. Ultimately, these become too large to be pushed seaward by the ice stream, which then slows down and enters a period of stagnation. During this period, the grounding line of the ice plain retreats, as we observe today in the mouth of Ice Stream C, because nearby ice shelf, no longer compressed by ice-stream motion, progressively thins. At the same time, water within the deformable till beneath the ice starts to freeze on to the base of the ice stream, and snow accumulation progressively increases the ice thickness. A new phase of activity would be initiated when the increasing gravity potential of the ice stream exceeds the total resistance of the shrinking ice plain and the thinning layer of deformable till at the bed. This could occur rapidly if the effects of the shrinking ice plain outweigh those of the thinning (and therefore stiffening) till. Otherwise, the till layer would finally become completely frozen, and the ice stream would have to thicken sufficiently to initiate significant heating by internal deformation, followed by basal melting and finally saturation of an adequate thickness of till; this could take some thousands of years.
    Print ISSN: 0260-3055
    Electronic ISSN: 1727-5644
    Topics: Geography , Geosciences
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