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  • Chemical Engineering  (78)
  • 1985-1989  (78)
  • 1960-1964
  • 1935-1939
  • 1988  (78)
  • 1
    Electronic Resource
    Electronic Resource
    Sorption and diffusion of benzene in HZSM-5 and silicalite crystals (1988)
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 34 (1988), S. 1713-1717 
    Details
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/aic.690341016
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  • 2
    Electronic Resource
    Electronic Resource
    Theoretical study of interfacial transport in gas-liquid flows (1988)
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 34 (1988), S. 1789-1802 
    Details
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Mass transfer in sheared, concurrent gas-liquid flows is investigated theoretically using solutions to the unaveraged advection-diffusion equation. For sufficiently thick films, the resistance to mass transfer is shown to be confined completely within a thin region in the liquid near the interface and mass transfer coefficients are accurately predicted by an improved numerical technique that uses a velocity field derived from an Orr-Sommerfeld equation with the time-varying velocity computed directly from measurements of interfacial waves. The mass transfer coefficients are shown to depend on the magnitude and frequency content of the velocity fluctuations normal to the interface. As the film thickness decreases, transfer resistance extends throughout the film and turbulent mixing in the middle of the film controls the transfer rates. For this region, limiting values of transfer coefficients are predicted well by analytical solutions to the advection-diffusion equation, which assume a laminar flow.
    Additional Material: 11 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/aic.690341105
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  • 3
    Electronic Resource
    Electronic Resource
    Acceleration of chlorination of alumina using supercritical CCl4 (1988)
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 34 (1988), S. 669-671 
    Details
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/aic.690340416
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  • 4
    Electronic Resource
    Electronic Resource
    Micellar-enhanced ultrafiltration of chromate anion from aqueous streams (1988)
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 34 (1988), S. 189-194 
    Details
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Micellar-enhanced ultrafiltration can be used to remove multivalent anions or cations from aqueous streams. In the removal of chromate ions (CrO42-), the cationic surfactant hexadecylpyridinium chloride is added to the solution, and the chromate ions preferentially adsorb at the surface of the highly charged surfactant micelles. The solution is processed by ultrafiltration, using a membrane with pore sizes small enough to block the passage of the micelles and adsorbed ions. The permeate solution has a chromate concentration less than 0.1% that in the original stream. A new equilibrium model, combining the simple two-phase polyelectrolyte theory of Oosawa with thermodynamic activity, material-balance, and charge-balance equations, successfully correlates ultrafiltration and equilibrium dialysis results for chromate solutions.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/aic.690340203
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  • 5
    Electronic Resource
    Electronic Resource
    A condition number scaling policy for stability robustness analysis (1988)
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 34 (1988), S. 1200-1206 
    Details
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The condition number of the process transfer function G(s) has been proposed and used as an indicator of the inherent controllability of a process even though it is a scale-dependent quantity. A rapid suboptimal scaling policy known as G-balancing is developed for the case of the l2 norm where the condition number is the ratio of the largest to the smallest singular value of G(s). For 2 × 2 systems, G-balancing gives the same optimal scaling as an available analytical solution. The higher order examples given compare the results of G-balancing with the known analytic results for l2 norm optimal scaling.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/aic.690340716
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  • 6
    Electronic Resource
    Electronic Resource
    Thermoplastic matrix sheet composites (1988)
    Brookfield, Conn. : Wiley-Blackwell
    Polymer Composites 9 (1988), S. 222-228 
    Details
    ISSN: 0272-8397
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Until recently, most high performance composites have been made with low-viscosity thermosetting polymers. These polymers are ideally suited for producing composites in low production quantities because a wide variety of custom shapes can be manufactured without a high degree of mechanization. As the demand for composites increases, there is a need to develop high-volume production techniques. Thermoplastic polymer-based composites are better suited to high-volume production than thermoset-based composites because only heat and pressure are needed to form parts; no chemical reaction is required. Thermoplastic matrix composites are not well suited for low-volume production runs because the need to handle high temperatures and pressures demands equipment that is best utilized for large production runs. In addition to processing advantages, thermoplastic matrix composites exhibit improved impact strength and chemical resistance over most thermoset-based composites. In the course of this work, composites reinforced with long and continuous glass fibers were produced that had tensile strengths as high as 270 MPa, tensile moduli of 16.2 GPa, and notched Izod impact strengths of 11.1 J/cm.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pc.750090309
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  • 7
    Electronic Resource
    Electronic Resource
    Processing-morphology relationships of compatibilized polyolefin/polyamide blends. Part I: The effect of an lonomer compatibilizer on blend morphology (1988)
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 28 (1988), S. 1416-1426 
    Details
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The morphology of compatibilized polyolef in/polyamide blends was found to be significantly dependent on the concentration of an ionomer compatibilizer (polyethylene-methacrylic acid-isobutyl acrylate terpolymer) in the blend. For a dispersed phase content of 10% by weight, a maximum reduction in phase size was observed when only 0.5% by weight of ionomer was added to the blend, A more significant reduction of the dispersed phase size was observed when the minor phase was nylon, due to interactions which exist between the ionomer and the polyamide. These interactions have been confirmed by Fourier transform infrared spectroscopy. At high concentrations of the ionomer, flocculation of the nylon dispersed phase was observed. In comparison to one-step mixing, blends prepared by two-step or batch mixing were characterized by a smaller dispersed phase when nylon was the matrix, and a larger particle size when nylon was the minor phase. The results observed are explained in terms of a speculative model of the interactions occurring across the nylon-polvolefin interface.
    Additional Material: 14 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pen.760282111
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  • 8
    Electronic Resource
    Electronic Resource
    Wrong-way behavior of packed-bed reactors: II. Impact of thermal dispersion (1988)
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 34 (1988), S. 1663-1672 
    Details
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A sudden reduction in the feed temperature of a packed-bed reactor may lead to a transient temperature rise, referred to as a wrong-way behavior. As expected, the axial dispersion of heat decreases the magnitude of the temperature excursion and prolongs the transient shift to a new steady state. In addition, the thermal dispersion may enable the wrong-way behavior to ignite a low-temperature steady state leading to a disastrous runaway of the reactor. Moreover, it may create a transient high-temperature wave, which moves initially in the upstream direction. The axial dispersion of heat can lead to some behavioral features which are qualitatively different from those of a model which ignores it. The transient temperature excursion does not exceed a value, which can be estimated by a simple analytical expression.
    Additional Material: 19 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/aic.690341010
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  • 9
    Electronic Resource
    Electronic Resource
    Hydrogen transfer in slurries of carbon supported catalyst (HPO process) (1988)
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 34 (1988), S. 1691-1697 
    Details
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The effect of suspended activated carbon on gas/liquid mass transfer is studied for the Pd/C-catalyzed hydrogenation of nitrate to hydroxylamine (HPO process). In a bubble column and in a stirred autoclave, physical mass transfer (kLa) in the concentrated salt solution is improved by more than a factor of three by the catalyst. Chemical absorption enhancement by the zero-order catalytic reaction is insignificant at the employed catalyst diameter (40 μm), but hydroxylamine selectivity depends on the absorption regime.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/aic.690341013
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  • 10
    Electronic Resource
    Electronic Resource
    A network model for deep bed filtration of solid particles and emulsion drops (1988)
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 34 (1988), S. 1761-1772 
    Details
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A network model has been developed to simulate the flow of emulsions and solid particles through porous media. Particle deposition due to direct interception, as well pore plugging by straining are accounted for in the model. The effects of two important factors - the ratio of particle size to pore size, and the fluid velocity - on particle deposition are also investigated. The strength of the model lies in its ability to predict accurately effluent concentration profiles, permeability changes occurring during deep bed filtration, and the evolution of the filter coefficient with time. Model predictions for different particle and pore size distributions of both solid and emulsion particles are in agreement with experimental data.
    Additional Material: 16 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/aic.690341102
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