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  • 1985-1989  (22)
  • 1970-1974
  • 1987  (22)
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  • 1985-1989  (22)
  • 1970-1974
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  • 1
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 51 (1987), S. 1588-1590 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Localized epitaxial Co5Ge7 and CoGe2 have been grown in cobalt thin films on (111)Ge in the solid phase epitaxy regime. The orientation relationships between epitaxial germanides and the substrates as well as the configuration of the interfacial dislocations were analyzed by transmission electron microscopy (TEM) in detail. Surface morphology was examined by scanning electron microscopy. The results obtained from Read camera glancing angle x-ray diffraction and Rutherford backscattering channeling analysis were found to corroborate with those from TEM examinations.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 62 (1987), S. 2789-2792 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The influences of implantation impurities, such as BF2, B, F, As and P, as well as silicon substrate crystallinity on the formation of NiSi2 at 200–280 °C in nickel thin films on ion-implanted silicon, have been investigated by transmission electron microscopy. In implantation-amorphous samples no NiSi2 formation was detected at 200–280 °C. The presence of BF2, B, and F atoms was found to promote the epitaxial growth of NiSi2 in nickel thin films on crystalline silicon at low temperatures. Little or no effect on the formation of NiSi2 was found for As+- and P+-implanted samples. The results indicated that the influences of the implantation impurities are not likely to be chemical in origin. The presence of electrically active impurities in crystalline silicon alone was not sufficient to induce the formation of epitaxial NiSi2 at low temperatures. On the other hand, good correlation was found between the atomic size factor and resulting stress and NiSi2 epitaxy at low temperatures.
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  • 3
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 62 (1987), S. 3722-3725 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Both plan-view and cross-sectional transmission electron microscopy as well as sheet resistance measurement have been applied to study the effects of As+ ion-beam mixing on the epitaxial growth of MoSi2 on (111)Si. Significant improvement in the epitaxial growth of MoSi2 on (111)Si and lower electrical resistivity of the MoSi2 overlayer were found as a result of ion-beam mixing. Island formation was almost completely alleviated in samples implanted under suitable conditions and subsequently annealed up to 1100 °C. The dispersion of impurities near the Mo/Si interface and/or the generation of defects as a result of the ion-beam mixing are thought to be particularly beneficial to the growth of MoSi2 epitaxy on silicon. The ineffectiveness of the ion-beam mixing for the improvement of the silicon surface coverage in some instances is attributed to the more pronounced accumulation of As atoms at the MoSi2/Si interface to increase the interface energy so that island formation becomes energetically more favorable.
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  • 4
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The feasibility of studying dynamical changes in metal/silicon and ion-implanted silicon thin films by cross-sectional transmission electron microscopy with intermittent annealings in N2 ambient up to 900 °C is demonstrated. Interactions of nickel thin films with oxidation-induced stacking faults and fluorine bubbles, the evolution of microstructural defects and solid-phase epitaxial growth in BF+2 -implanted silicon are provided as examples. The technique may be applied to clarify a number of important issues encountered in the study of the reactions and diffusion of thin films and obtain information otherwise unattainable.
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  • 5
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 62 (1987), S. 461-465 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Epitaxial ReSi2 has been grown locally on (111) and (001)Si. The best epitaxy was obtained in samples after two-step annealing at 500–1100 °C. In (111) samples, the orientation relationships were analyzed to be [110]ReSi2//[111]Si and (002)ReSi2//(2¯02)Si. About 70% in areal fraction of the epitaxial regions were found to be pseudomorphic. In (001) samples, two different modes of epitaxial silicides were observed: [110]ReSi2//[001]Si and (1¯10)ReSi2//(22¯0)Si (mode A') and [110]ReSi2//[001]Si and (1¯12¯)ReSi2//(220)Si (mode B'). About 40% and 60% in areal fractions of the mode A' and mode B' epitaxial ReSi2 regions, respectively, were found to be pseudormorphic. The apparent insensitivity of the quality of the ReSi2 epitaxy to the lattice matches at silicide/silicon interfaces at room temperature may be explained in part by the considerable changes in lattice mismatches at the growth temperature arising from the substantial difference in thermal expansion coefficients between the ReSi2 overlayer and the substrate silicon. The results are in agreement with a theory which predicts that orientations with negative mismatches are favored for epitaxial growth over orientations with positive mismatches.
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  • 6
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 62 (1987), S. 4421-4425 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: A combined cross-sectional and plain-view transmission electron microscope study of residual defects in 110-keV 5×1015/cm2 BF+2 -implanted (111) Si has been carried out. The samples were annealed isothermally in N2 ambient at 600–1100 °C with 100 °C increments. The distribution, density, and size of point defect clusters, twins, equiaxial loops, elongated loops, and bubbles were analyzed in detail. The origin and evolution of the residual defects are discussed.
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  • 7
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 61 (1987), S. 2218-2223 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Cross-sectional transmission electron microscopy (XTEM) has been applied to the study of the growth kinetics of hexagonal MoSi2 on (001)Si. Growth rates, interface structures, and microstructures in the growth layers were determined for samples annealed at 560–580 °C for various periods of time. The silicide thickness was found to be proportional to the square root of annealing time. The activation energy and the rate constant of the growth were measured to be 2.3 eV and 14 cm2/s, respectively. Growth mechanisms are discussed. The results of the previous studies on the MoSi2 growth are summarized. Advantages of the present approach in the study of the growth kinetics of silicides on silicon, both in sample preparation and in the employment of XTEM technique, are outlined.
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  • 8
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 62 (1987), S. 879-884 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Localized epitaxial TaSi2 was grown on (111) and (001)Si by rapid thermal annealing in Ar ambient. The best epitaxy was obtained in samples annealed at 1300 °C for 300 s. Three major modes and one dominant mode of TaSi2 epitaxy were found to grow on (111) and (001)Si, respectively. The roles of lattice match in the growth of epitaxial TaSi2 are explored. The effects of gas ambient on the growth of TaSi2 epitaxy are discussed.
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  • 9
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 61 (1987), S. 2393-2395 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Epitaxial HfSi2 has been grown locally on (001)Si. In samples annealed in one step at 1100 °C or in two steps at 450–1100 °C, islands of HfSi2 of 0.8 μm in average grain size were found to cover about 40% of the surface area. About 70% of the disilicide in areal fraction was found to be epitaxial silicide, 0.6–1.2 μm in size. The orientation relationships between epitaxial HfSi2 and (001)Si substrate were analyzed to be [010]HfSi2(parallel)[001]Si and (002)HfSi2(parallel)(220)Si (with about 1° misorientation). Interfacial dislocations, 75 A(ring) in average spacing, were identified to be of edge type with 1/2〈110〉 Burgers vectors. No HfSi2 epitaxy was found to form on (111)Si.
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  • 10
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 61 (1987), S. 549-551 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The kinetics of the growth of epitaxial TiSi2 on (111)Si and accompanying microstructural changes have been investigated by examining the same region of a thin foil repeatedly in a transmission electron microscope with intermittent annealings in a diffusion furnace. The evolution of the different modes of C54-TiSi2 epitaxy was monitored. The dominance of the epitaxy with [101]TiSi2//[111]Si and (3¯13)TiSi2//(22¯0)Si (with about 1° deviation) was found to be due to a faster initial growth rate resulting in a much larger final size than that of the epitaxy with [100]TiSi2//[111]Si and (004)TiSi2//(022¯)Si. The difference in interface energy is conceived to be the dominant factor in affecting the epitaxial growth.
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