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  • GEOPHYSICS  (141)
  • Chemical Engineering  (108)
  • ENERGY PRODUCTION AND CONVERSION
  • Physics
  • 1985-1989  (263)
  • 1980-1984
  • 1975-1979
  • 1987  (263)
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  • 1985-1989  (263)
  • 1980-1984
  • 1975-1979
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  • 1
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 33 (1987), S. 480-487 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The facilitated transport of CO2 through ion exchange membranes containing organic amine counterions was studied. Steady state CO2 fluxes were measured from pure gas streams and mixtures with CH4. Facilitation factors for CO2 up to 26.7 were calculated from transport data. Transport measurements were binary mixtures of CO2 and CH4 yielded ratios of CO2 flux to CH4 flux ranging from 29.0 to 264. Conversion of flux ratios to permeabilities yielded separation factors up to 551 for CO2 over CH4, which are compared to literature data for polymeric membranes. The transport data support a mobile, reactive-carrier facilitated transport mechanism with a carbamate zwitterion complex. Effective diffusivities for CO2 and the carrier-gas complex were determined from transport data. A reaction equilibrium model predicted facilitation factors that were in very good agreement with experimental values. Potential applications are also discussed.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Publication Date: 2011-08-19
    Description: Examination of many individual event periods in the ISEE 3 deep-tail data set has suggested that magnetospheric substorms produce a characteristic pattern of effects in the distant magnetotail. During the growth, or tail-energy-storage phase of substorms, the magnetotail appears to grow diametrically in size, often by many earth radii. Subsequently, after the substorm expansive phase onset at earth, the distant tail undergoes a sequence of plasma, field, and energetic-particle variations as large-scale plasmoids move rapidly down the tail following their disconnection from the near-earth plasma sheet. ISEE 3 data are appropriate for the study of these effects since the spacecraft remained fixed within the nominal tail location for long periods. Using newly available auroral electrojet indices (AE and AL) and Geo particle data to time substorm onsets at earth, superposed epoch analyses of ISEE 3 and near-earth data prior to, and following, substorm expansive phase onsets have been performed. These analyses quantify and extend substantially the understanding of the deep-tail pattern of response to global substorm-induced dynamical effects.
    Keywords: GEOPHYSICS
    Format: text
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  • 3
    Publication Date: 2019-07-12
    Description: Reported in this paper are the Georgia Institute of Technology NO results from the fall 1983 NASA GTE/CITE 1 Airborne Field Sampling Program. These data were predominantly collected over a geographical area defined by the eastern and central North Pacific Ocean, spanning the latitude range of 15-42 deg N. These NO measurements were taken using the two-photon laser-induced fluorescence technique. The data show a general trend of increasing levels of NO from the boundary layer up to altitudes of nearly 10 km. The average midday value of NO at altitudes of less than or equal to 1.8 km was 4 parts per trillion by volume (pptv), and at about 6 km, 20 pptv, whereas that at about 9 km was 25-35 pptv, the higher value reflecting the inclusion of NO data collected from the outflow region of two electrically active cumulonimbus clouds. The high-altitude NO data strongly suggest that at least during the time of the GTE flight operation, the major sources of NO for remote regions of the Pacific Ocean were those resulting from lightning and the downward transport of stratospheric air.
    Keywords: GEOPHYSICS
    Type: Journal of Geophysical Research (ISSN 0148-0227); 92; 2049-207
    Format: text
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  • 4
    Publication Date: 2019-07-12
    Description: The current-voltage relation within narrow auroral current sheets is examined through the use of high-resolution data from the high altitude Dynamics Explorer 1 satellite. The north-south perpendicular electric field and the east-west magnetic field are shown for three cases in which there are large amplitude, oppositely directed paired electric fields and narrow current sheets. These data are shown to indicate that there is a linear Ohm's law relationship between the current density and the parallel potential drop within the narrow current sheets. This linear relationship had previously been verified for large-scale auroral formations greater than 20 km wide at the ionosphere. The evidence shown here extends our knowledge down to the scale size of discrete auroral arcs.
    Keywords: GEOPHYSICS
    Type: AD-A178407 , AFGL-TR-87-0085 , Journal of Geophysical Research (ISSN 0148-0227); 92; 187-194
    Format: text
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  • 5
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 33 (1987), S. 1496-1506 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A practical application of advanced, model-based, multivariable control to a pilot plant packed-bed reactor carrying out highly exothermic butane hydrogenolysis reactions is presented. The system is first stabilized by using butane flow rate to control the reactor hot-spot temperature. Propane production and butane conversion are then controlled using multivariable controllers that manipulate the hot-spot temperature set point and hydrogen flow rate. The controller designs are based on multivariable transfer function models developed using multivariable time series and process identification methods.Two types of multivariable controllers are applied. The first is an internal model controller (IMC) utilizing a stabilized approximation of the model inverse and a tunable exponential filter. The second is a linear-quadratic (LQ) controller design using pulse transfer function models to characterize the process dynamics and autoregressive-moving average models to characterize the disturbances. The optimal control solution was arrived at via a spectral factorization solution to the Wiener-Hopf equations. The results indicate that both designs, if well tuned, provide good performance and robustness over a wide range of operation.
    Additional Material: 10 Ill.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 33 (1987), S. 672-676 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 33 (1987), S. 19-25 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Numerical calculations of the velocity and temperature fields were conducted for unsteady flows over a single circular cylinder and a bundle of cylinders. Periodic disturbances, natural or externally imposed, were considered. Periodic and averaged heat transfer rates were examined. Results compare favorably with experimental data. Calculations were carried out to predict heat transfer rates in regimes of unsteady flows that have not been tested experimentally.
    Additional Material: 10 Ill.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 33 (1987), S. 336-340 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 33 (1987), S. 940-951 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Prior experimental study by Haldeman and Botty has demonstrated that catalyst regeneration rates vary with conversion, showing a nearly constant rate of reaction in the early stages of regeneration and falling off rapidly at higher conversion levels. This peculiar reaction behavior calls for explanation in terms of pore structural changes. In this work a mathematical model is developed based on the interaction between catalyst pore structure and coke distribution in the pores. The model is able to associate overall regeneration kinetics with alternative pore-distributed coke deposition patterns. Results exhibit a slight shallow rate maximum at an intermediate conversion level, in agreement with the prior experimental report. The model makes coke distribution in the pores accessible to experimental determination. The numerical results indicate that among pore structures with the same mean and overall pore volume, a larger variance offers a higher threshold for coke loading; for a given degree of dispersion, a smaller mean allows a higher coke loading.
    Additional Material: 14 Ill.
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 33 (1987), S. 1542-1549 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A dynamic response method was used to measure the volumetric mass transfer coefficient for oxygen in a mechanically agitated vessel containing an aqueous suspension of 66 μm glass beads. At constant stirring speed and superficial gas velocity the volumetric gas transfer coefficient kLa was found to decrease with solids loading. A generalized equation correlated the results in terms of the volume concentration of the solids, the total power input per slurry volume, and the superficial gas velocity.
    Additional Material: 10 Ill.
    Type of Medium: Electronic Resource
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