ALBERT

All Library Books, journals and Electronic Records Telegrafenberg

feed icon rss

Your email was sent successfully. Check your inbox.

An error occurred while sending the email. Please try again.

Proceed reservation?

Export
Filter
  • American Physical Society  (22)
  • American Institute of Physics (AIP)  (10)
  • Blackwell Publishing Ltd  (5)
  • American Association for the Advancement of Science (AAAS)  (3)
  • Geological Society of London
  • 2000-2004  (19)
  • 1985-1989  (22)
  • 1980-1984
  • 1960-1964
  • 2002  (19)
  • 1988  (13)
  • 1987  (9)
Collection
Publisher
Years
  • 2000-2004  (19)
  • 1985-1989  (22)
  • 1980-1984
  • 1960-1964
Year
  • 1
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 89 (1988), S. 608-609 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: Excitation of the NH-stretch overtone transitions of HN3 to v1=5 and 6 resulted in predissociation to HN(X) and N2(X) with lifetimes of 80+60−30 and ≤3 ns, respectively. Following excitation of either overtone, the HN fragments were formed predominantly in the symmetric F1, F3 spin–rotation states, with less than 4% population in the antisymmetric F2 levels. Fragment Doppler profiles confirmed that most of the available energy (〉96%) went into translational motion.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 2
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 89 (1988), S. 5342-5343 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: Infrared pump–probe characterization of the excited state lifetimes reveals that CO bound to isolated metal sites (T1=140±20 ps) persists longer than the signal observed for CO bound to (approximate)35 A(ring) diameter metal particles (≤18 ps), suggesting paticipation of electron–hole excitations in the larger metal particles.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 3
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 89 (1988), S. 230-239 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: Tunable infrared picosecond pulses in the 5 μ region have been used for time-resolved pump–probe measurements of the population relaxation lifetime (T1) of CO(v=1) stretching vibrations in a series of metal–carbonyl cluster compounds in room temperature chloroform solution. T1 was the same for symmetric (ν=2084 cm−1, 90±10 ps) and antisymmetric (2014 cm−1, 87±10 ps) modes of the dicarbonyl Rh(CO)2(C5H7O2); T1 was the same for the B1 (2092 cm−1 , 710±130 ps) and B2 (2036 cm−1, 750±90 ps) modes of Rh2(CO)4Cl2. Similarly long T1 times were found for Rh4(CO)12 (2075 cm−1, 610±65 ps) and Rh6(CO)16 (2077 cm−1, 700±100 ps). The molecule Co4(CO)12 has also been compared to the corresponding rhodium analog and it exhibits an initially fast relaxation of 47±5 ps followed by a slower 396±70 ps decay. The transient response of the more complex systems to the single frequency experiment is found to be sensitive to frequency and can exhibit bleaching, absorption, and a combination of these effects. Such behavior is attributed to overlap of the IR pulse with v=1 to v=2 and higher transitions in the M4(CO)12 (M=Rh or Co) and Rh6(CO)16 molecules. The long CO(v=1) T1 values for the metal cluster molecules suggest relaxation via multiquantum transfer of vibrational energy to adjacent M–C stretch and M–C–O bend vibrations; energy transfer to vibrational or electronic states of the central metal core seems unimportant in determining T1 for these systems.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 4
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 89 (1988), S. 1378-1387 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: Multiphoton vibrational excitation of deuterated hydrazoic acid, DN3, by a CO2 laser (I=10 GW/cm2) leads to dissociation forming DN in both X 3Σ− (spin forbidden) and a 1Δ (spin allowed) electronic states. Under collisionless conditions, the nascent DN fragments were probed via laser induced fluorescence, to determine initial product state distributions. The DN(X 3Σ−) molecules are formed predominantly in the symmetric F1 and F3 spin–rotation states with little population (≤6%) in the antisymmetric F2 levels. There is no significant population (〈3%) in excited DN(3Σ−) vibrational levels. The distribution of rotational states is Boltzmann-like, characterized by a rotational "temperature'' of about 920 K for the F1, F3 states and 500 K for F2 levels. Doppler profiles showed a large kinetic energy release of about 10 100 cm−1 total in the triplet channel. The DN(1Δ) products are formed preferentially in the symmetric Δ(A'), e-labeled lambda doublet levels: Δ(A')/Δ(A‘)=1.44. The DN(1Δ) is formed with no vibrational excitation (〈2%); the rotational states are populated Boltzmann-like with a rotational "temperature'' of 425 K. Doppler profiles give a total kinetic energy of about 1500 cm−1 in this channel. These observations give information about the distribution of energy in the reactant, the location of the barriers to dissociation, and the geometry of the transition states. Alexander, Werner, and Dagdigian (accompanying article) show that the observed DN(3Σ−) spin- and DN(1Δ) Λ-doublet selectivities reflect the symmetry properties of a planar transition state and that the low degree of DN(3Σ−) rotational and vibrational excitation is also expected from the transition state geometry.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 5
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 89 (1988), S. 1966-1976 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: Picosecond and nanosecond lasers and pulsed molecular beam techniques have been used to measure the infrared photodissociation spectra, the product state distributions, and the predissociation lifetimes of vibrationally excited nitric oxide dimer (NO)2 . Results for the ν1 (v=1) symmetric NO stretching mode and the ν4 (v=1) antisymmetric NO stretching mode are presented. Predissociation lifetimes are determined by time-resolved laser induced fluorescence probing of the NO monomer product appearance rate. A dramatic mode dependence of the predissociation lifetimes is observed with the higher energy ν1 mode decaying in approximately 1 ns, and the lower energy ν4 mode decaying in approximately 40 ps. The mode dependence is independent of which product state is probed. The product state distributions show that 75% to 80% of the available energy is channeled into relative translational energy of the fragments for both modes. Rotational state distributions are Boltzmann-like with temperatures ranging from 71 to 112 K depending on both the initially excited mode and on the NO product spin–orbit state. Predissociation from ν1 produces NO fragments in the 2Π1/2 and 2 Π3/2 states with equal probability. Predissociation from ν4 exhibits a propensity for producing the lower energy 2 Π1/2 spin–orbit state. The observations are discussed in terms of various vibrational predissociation mechanisms, including vibrational potential coupling and electronically nonadiabatic predissociation.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 6
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Review of Scientific Instruments 73 (2002), S. 1367-1367 
    ISSN: 1089-7623
    Source: AIP Digital Archive
    Topics: Physics , Electrical Engineering, Measurement and Control Technology
    Notes: This talk will describe proposed studies of atomic- and nanoscale dynamics in condensed matter which take advantage of the high coherent x-ray flux to be produced by future x-ray free-electron laser (FEL) sources, such as the Linac Coherent Light Source at Stanford. In particular, I will focus on the current status and future prospects for photon correlation spectroscopy using coherent x-rays (XPCS), and the use of the ultrashort pulse structure of the x-ray FEL to observe dynamics into the femtosecond range. © 2002 American Institute of Physics.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 7
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Grass and forage science 43 (1988), S. 0 
    ISSN: 1365-2494
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: The influence of tall fescue (Festuca arundinacea Schreb.) on germination and seedling growth of birdsfoot trefoil (Lotus corniculatus L.) was evaluated during 1983-85 at Manhattan, Kansas. Studies were designed to evaluate tall fescue cv. Kentucky-31 for possible allelopathic compounds, determine the effects of tall fescue on the germination, seedling growth and yield of birdsfoot trefoil, and to characterize the chemical properties of tall fescue. Fescue produced allelopathic compounds, particularly during the spring and autumn months when it was actively growing. The greatest trefoil inhibition occurred with fescue plant extracts prepared during the autumn (September and October). The concentration of fescue extracts influenced trefoil germination, with greater inhibition as fescue concentration increased. In a sand medium under greenhouse conditions, fescue extracts prepared in spring and autumn reduced trefoil growth by 50 and 56%, respectively, with no inhibition during the summer months. Under field conditions, full strength fescue extracts reduced trefoil plant populations by 14 and 57% with spring and autumn prepared extracts, respectively. Fescue competition reduced sod-seeded trefoil plants per unit area by 17 and 31% for spring and autumn seeding, respectively. Full strength fescue extracts reduced trefoil seedling growth by an average of 37%, and trefoil dry matter yields by 53%.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 8
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 63 (1988), S. 1691-1693 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The application of an alternating field (AF) of 60-mT peak to an isotropic sample containing dilutely dispersed particles of γFe2O3 from magnetic tape causes it to become magnetically anisotropic. The anisotropy of initial susceptibility so produced can be described by an oblate ellipsoid of revolution with the unique axis aligned with the AF direction. A consequence of this effect is that an isothermal remanent magnetization (IRM) is then more easily acquired if the direct field is applied perpendicular to the previously applied AF direction than if it is applied parallel to this direction. The anisotropy of IRM acquisition at direct fields between 20 and 40 mT is an order of magnitude greater than the anisotropy of initial susceptibility and is 40% of the maximum possible value.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 9
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 80 (2002), S. 1809-1811 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: We present in situ surface x-ray scattering measurements of PbTiO3 epitaxy by metal–organic chemical-vapor deposition. Oscillations in crystal truncation rod intensity corresponding to layer-by-layer growth are observed under a variety of growth conditions. At lower PbO overpressures, we observe a transition to step-flow growth and an increased rate of recovery after growth, indicating a higher surface mobility. © 2002 American Institute of Physics.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 10
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: A technique for selective characterization of the structure of free and buried thin-film interfaces by vibrationally resonant sum frequency generation spectroscopy is described. Manipulation of Fresnel coefficients by choice of film thickness on a reflecting substrate allows simultaneous optimization of the signal from the desired interface and minimization of the signal from other interfacial sources. This technique is demonstrated for the free polystyrene (PS)/air and the buried PS/spin-on glass interfaces. Our spectra show that the pendant phenyl group orientation is similar at the buried and free interfaces, with the phenyls pointing away from the bulk PS at each interface.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
Close ⊗
This website uses cookies and the analysis tool Matomo. More information can be found here...