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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    International journal of thermophysics 8 (1987), S. 335-350 
    ISSN: 1572-9567
    Keywords: carbon dioxide ; dilute gas ; mixtures ; virial coefficient ; viscosity
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract The SSR-MPA potential model is used to correlate and extrapolate the dilutegas properties of some systems containing CO2. With parameters determined from a consistent set of second virial and Joule-Thomson data, the third virial coefficient of CO2 as well as the second virial coefficients of various mixtures containing CO2 can be predicted very well. The Mason-Monchik approximation fails for a complicated molecule such as CO2, although at least a viscosity prediction of technical accuracy is obtained. If parameters fitted to the CO2 viscosity are used, excellent predictions can be made for the viscosity of gaseous mixtures containing CO2.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    International journal of thermophysics 7 (1986), S. 1007-1021 
    ISSN: 1572-9567
    Keywords: dilute gas ; mixtures ; pair potentials ; statistical mechanics
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract The three-parameter MSK potential is used to calculate the dilute-gas properties of the monatomic gases and their mixtures. The parameters are fitted to data of the second virial coefficient and the Joule-Thomson coefficient; the calculations of all other thermophysical properties are predictions. For mixtures, universal combination rules for the potential parameters are used. It is shown that a consistent representation of the gas data of the monatomic systems is possible.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Springer
    International journal of thermophysics 8 (1987), S. 1-11 
    ISSN: 1572-9567
    Keywords: binary diffusion coefficient ; dilute gas ; mixtures ; second virial coefficient ; viscosity
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract The second virial coefficient, dilute-gas viscosity, and binary diffusion coefficients of some binary-gas mixtures are predicted from potentials which have been fitted to the properties of the pure components. It has been noted that the SSR-MPA potential for polyatomic and the MSK potential for monatomic molecules together with a suitable set of universal combination rules are adequate to make predictions essentially within the inaccuracy of the data.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Springer
    International journal of thermophysics 7 (1986), S. 1135-1145 
    ISSN: 1572-9567
    Keywords: dilute-gas properties ; mixtures ; pair potentials ; statistical mechanics
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract A three-parameter angle-dependent pair potential referred to as the SSR-MPA is used to correlate and extrapolate the dilute-gas properties of the simple linear molecules nitrogen, oxygen, and ethane. The statistical mechanical equations are solved by direct numerical integrations. When the shape of the molecules and the anisotropic long-range forces are properly accounted for, all data are reproduced or predicted essentially within the experimental uncertainties.
    Type of Medium: Electronic Resource
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