Abstract
The SSR-MPA potential model is used to correlate and extrapolate the dilutegas properties of some systems containing CO2. With parameters determined from a consistent set of second virial and Joule-Thomson data, the third virial coefficient of CO2 as well as the second virial coefficients of various mixtures containing CO2 can be predicted very well. The Mason-Monchik approximation fails for a complicated molecule such as CO2, although at least a viscosity prediction of technical accuracy is obtained. If parameters fitted to the CO2 viscosity are used, excellent predictions can be made for the viscosity of gaseous mixtures containing CO2.
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Ameling, W., Lucas, K. The dilute-gas properties of some systems containing CO2 . Int J Thermophys 8, 335–350 (1987). https://doi.org/10.1007/BF00503946
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DOI: https://doi.org/10.1007/BF00503946