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  • Chemistry  (17)
  • 42.75
  • 2010-2014
  • 1985-1989  (17)
  • 1980-1984
  • 1986  (17)
Collection
Publisher
Years
  • 2010-2014
  • 1985-1989  (17)
  • 1980-1984
Year
  • 1
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Journal für Praktische Chemie/Chemiker-Zeitung 328 (1986), S. 656-660 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: N.M.R.-Investigation of the Intramolecular Hydrogen-Bonds in 2-Hydroxy-nitronate-anions
    Additional Material: 4 Tab.
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  • 2
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Materialwissenschaft und Werkstofftechnik 17 (1986), S. 238-246 
    ISSN: 0933-5137
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Spannungshypothesen und Werkstoffanstrengung im Hertz'schen KontaktDer Spannungszustand im Halbraum des Hertz'schen Kontaktbereichs kann unter idealisierten Annahmen für verschiedene Geometrien in Abhängigkeit von der Flächenpressung (Normalkraft), der Reibung (Tangentialkraft an der Oberfläche) sowie den Eigenspannungen im Werkstoff berechnet werden.Aus den Koordinatenspannungen lassen sich Vergleichsspannungen nach verschiedenen Anstrengungshypothesen (Gestaltänderungsenergiehypothese, Schubspannungshypothese und Wechselschubspannungshypothese) bilden.Untersucht wird die Wirkung von Reibung, Eigenspannungen und Geometrie der Kontaktfläche auf die Vergleichsspannung nach den einzelnen Anstrengungshypothesen. Es erfolgt die Darstellung des Einflusses dieser Parameter auf Ort und Betrag des im Werkstoff auftretenden Vergleichsspannungsmaximums.Anhand dieser Untersuchungen wird deutlich, daß die Gestaltänderungsenergiehypothese bei dynamisch beanspruchten Wälzelementen die Werkstoffanstrengung am besten beschreibt. Die Schubspannungshypothese kann als gute Näherung aufgefaßt werden, während die Wechselschubspannungshypothese nur sehr eingeschränkt aussagefähig ist.
    Notes: Using idealised assumptions, the stress condition in the semi infinite body of the Hertzian contact region can be calculated for various geometries as a function of the surface pressure (normal force), the friction (tangential force at the surface) and the residual stresses in the material.Equivalent stresses can be formed from the coordinate stresses using various stress hypotheses (distortion energy hypothesis, shear stress hypothesis and alternating shear stress hypothesis).The effects of friction, residual stresses and contact geometry on the location and magnitude of the equivalent stresses appearing in the material have been investigated, the stress hypotheses being evaluated in terms of the extent to which they take account of these effects in an appropriate form.These investigations show clearly that the distortion energy hypothesis is the best representation of the extent of material stress in the case of dynamically loaded rolling elements. The shear stress hypothesis can be considered as a good approximation whereas the alternating shear stress hypothesis is only capable of providing useful conclusions to a limited extent.
    Additional Material: 12 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Journal of High Resolution Chromatography 9 (1986), S. 515-517 
    ISSN: 0935-6304
    Keywords: Gas chromatography, GC ; Fused silica capillary column ; Electron impact mass spectrometry ; Linear retention indices ; Dinitrofluoranthenes ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: This paper reports the retention indices of eighteen of the possible twenty-five dinitrofluoranthene isomers.
    Additional Material: 1 Ill.
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  • 4
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Materialwissenschaft und Werkstofftechnik 17 (1986), S. 370-378 
    ISSN: 0933-5137
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Fretting Fatigue Strength of Plasmanitrided 34 CrAlMo 5Fretting fatigue load here means oscillating sliding movements of very small amplitude (1-3 μm) and synchronous fatigue load. Characteristic of this is the appearance of frettings. These surface damages lead to the formation of microcracks, which spread and finally lead to the premature fatigue failure of the component. To simulate such processes of damage, which are known of the bearing surfaces of roller bearing races, of turbine blades and of shaft-hub-combinations, a fretting bridge apparatus is used.The plasmanitriding and plasmanitrocarburizing of metals are thermochemical heat treatments, which change the microstructure of near to surface areas. By means of this the mechanical and technological properties of components, e.g. wear and corrosive resistance as well as fatigue strength, are improved. Dur to the advantage sof the process, plasmanitriding is already used in many regions of production.Investigating the fretting fatigue strength of plasmanitrided respectively plasmanitrocarburized 34 CrAlMo 5 shows, that these treatments improve the fatigue strength values to a level 14% higher, the fretting fatigue strength increases about 50%.
    Notes: Unter Schwingungsverschließbeanspruchung wird hier eine oszillierende Gleitbewegung von sehr kleiner Amplitude (1-3 μm) bei gleichzeitiger schwingender Werkstoffbelastung verstanden. Kennzeichnend ist das Auftreten von Scheuer- und Reibschweißstellen. Diese Oberflächenschäden bewirken die Bildung von Mikrorissen, welche sich ausbreiten und zum vorzeitigen Ermüdungsbruch des Bauteils führen. Zur Simulation solcher Schadensvorgänge, wie sie bei Paarverbindungen wie Wälzlagersitzen, Turbinenschaufeln und Wellen Naben-Verbindungen bekannt sind, wird eine Reibkufenapparatur benutzt.Das Plasmanitrieren und das Plasmanitrocarburiern metallischer Werkstoffe sind thermochemische Wärmebehandlungsverfahren, die den mikrostrukturellen Aufbau der oberflächennahen Bereiche Verändern. Dadurch werden die mechanisch-technologischen Eigenschaften von Werkstücken, wie z. B. der Verschleiß- und Korrosionswiderstand sowie die Dauerfestigkeit verbessert. Aufgrund seiner verfahrenstechnischen Vorteile wird das Plasmanitrieren inzwischen in vielen Fertigungsbereichen angewendet.Die Ermittlung der Schwingungsverschleißfestigkeit an vergütetem und plasmanitriertem bzw. -nitrocarburiertem 34 CrAlMo 5 zeigt, daß durch diese Behandlungsverfahren die Zugschwellfestigkeit um bis zu 14%, die Schwingungsverschleißfestigkeit um bis zu 50% angehoben werden kann.
    Additional Material: 14 Ill.
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  • 5
    ISSN: 0935-6304
    Keywords: Capillary gas chromatography ; Detection limits ; Trace analysis ; Narrow bore columns ; Wide bore columns ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The need for faster and more efficient separations of complex mixtures of organic compounds by gas chromatography has led to the development of small inner diameter open tubular columns. Owing to their decreased plate height, extremely narrow peaks are obtained. When differently sized columns with equal plate numbers are compared, injection of a fixed amount of a solute will give the highest detector signals for the smallest bore columns. When P is defined as the ratio of the column inlet and outlet pressures, it can be seen from theory that under normalized chromatographic conditions the minimum detectable amount (Qº) for a mass flow sensitive detector increases proportionally to the square of the column diameter for P = 1. In the situation of greater interest in the practice of open tubular gas chromatography where P is large, a linear relationship is derived between Qº and the column diameter.It is a widespread misunderstanding, however, that narrow bore capillary columns should be used for this reason in trace analysis. If a fixed relative contribution of the injection band width to the overall peak variance is allowed, a decreased plate height drastically restricts the maximum sample volume to be injected. It is shown that the minimum analyte concentration in the injected sample (Cº) is inversely proportional to the column inner diameter when a mass flow sensitive detector is used. For actual concentrations less than Cº, sample preconcentration is required. The effect of peak resolution and selectivity of the stationary phase in relation to Cº and Qº will be discussed as well. The validity of the given theory is experimentally investigated. Minimum analyte concentrations and minimum detectable amounts are compared using columns with different inner diameter.
    Additional Material: 8 Ill.
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  • 6
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Materialwissenschaft und Werkstofftechnik 17 (1986), S. 109-114 
    ISSN: 0933-5137
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: New Developments in Preparation of Hard Material Coatings by Plasma CVDIn this paper, the technique for the preparation of hard material coatings using a D.C. Plasma is described. Two methods are used: One is direct current (D.C.) non-pulsed glow discharge method and the other is pulsed D.C. glow discharge method. It has been shown that the temperature in chemical vapour deposition (CVD) of TiN can be reduced from about 1000°C in conventional CVD to about 500-600°C by the application of a D.C. non-equilibrium plasma. Emphasis is placed on the new design concept for industrial application by using a pulsed D.C. power source and auxiliary heating device. The structures of the TiN coatings obtained at 600 °C are analysed by means of electron microscope and X-ray diffraction methods. The film deposition rate is 1-3 μm/h. It is concluded that plasma assisted CVD of hard material coatings offers a superior alternative to the conventional CVD method.
    Notes: Es wird über eine neue Anlagen- und Verfahrensentwicklung für die Herstellung von Hartstoffschichten im Plasma einer Glimmentladung berichtet. Dabei werden zwei Varianten, die mit pulsierender und mit nicht pulsierender Gleichstromglimmentladung arbeiten, erläutert. Die Temperatur der chemischen Gasphasenabscheidung (CVD) von Titannitrid kann durch die Verwendung eines Gleichstromplasmas von etwa 1000°C, die beim konventionellen thermischen CVD notwendig ist, auf etwa 500-600°C abgesenkt werden. Die vorgestellte Anlagenkonzeption mit gepulster Gleichstromversorgung und separater Zusatzheizung ist für den industriellen Einsatz geeignet. Der Aufbau von auf verschiedenen Stählen bei 600 °C hergestellten Titannitridschichten wurde mittels Elektronenmikroskopie und Röntgenbeugung untersucht. Die Schichtwachstumsgeschwindigkeit beträgt zwischen 1 und 3 μm/h. Die Herstellung von Hartstoffschichten mittels Plasma-CVD bietet eine überlegene Alternative zum konventionellen CVD-Verfahren.
    Additional Material: 8 Ill.
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  • 7
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Chemie in unserer Zeit 20 (1986), S. 104-104 
    ISSN: 0009-2851
    Keywords: Chemistry ; Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
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  • 8
    ISSN: 0021-9304
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Medicine , Technology
    Notes: Macroporous hydroxyapatite was implanted submucosally in the rat middle ear and studied after intratympanic injection of a Staphylococcus aureus suspension. The middle ear infection was induced 1 week after the implantation, and the effects of infection on the middle ear and the implant material were evaluated after 1, 3, 7, and 14 days by light and electron microscopy. The findings in the infected middle ear with an implant corresponded well with those described for the infected middle ear cavity without an implant. The reactions of the tissue over the implant were similar to those of the original mucosa of the middle ear.Bone was deposited on the implant and in its pores in relatively large quantities. Biodegradation, due at least partially to phagocytic activity of macrophages and multinucleated cells, was more prominent than previously found. This higher degree of biodegradation may be attributed to the use of the mucosal implantation technique, because this was the only point of divergence with respect to material or methods from earlier work reported by our group.The present results, together with those published earlier, suggest that this material has promising features for use as a bone substitute in reconstructive middle ear surgery. Definitive conclusions on biological performance and biofunctionality will, however, have to await long term clinical trials.
    Additional Material: 8 Ill.
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  • 9
    ISSN: 0021-9304
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Medicine , Technology
    Notes: In the present study the biological performance of macroporous and dense hydroxyapatite after implantation in the rat middle ear was evaluated during an induced Staphylococcus aureus middle ear infection. The course of the infection was similar to that in the absence of an implant. Hydroxyapatite was frequently integrated with fibrous ingrowths in the middle ear lumen, originating solely from the infection. Good epithelial covering of the implant with all types of epithelial cells of importance for middle ear defence, was found. Increase of the exudate in the pores due to the infection was relatively small, and most of the exudate was restricted to pores on the implant surface. The bony tissue in the pores was not influenced significantly by the induced infection. Degradation of hydroxyapatite was consistent with earlier results obtained in the noninfected middle ear. The results obtained so far suggest that hydroxyapatite is highly suitable for middle ear implantation.
    Additional Material: 9 Ill.
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  • 10
    ISSN: 0323-7648
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: Interruption of the monomer feed during the polymerization of ethylene with catalysts produced by reaction of tetrabenzylzirconium with γ-alumina shows that deactivation of the catalyst is not caused by the polyethylene being formed. Catalysts obtained from alumina with different thermal pretreatment and, therefore, different contents of hydroxyl groups on the surface show different deactivation rate.
    Notes: Unterbrechung der Monomerzufuhr bei der Ethylen-Polymerisation mit Katalysatoren, hergestellt aus Tetrabenzylzikonium und γ-Aluminiumoxid, zeigt, daß die Katalysatordesaktivierung nicht durch das gebildete Polyethylen bewirkt wird. Katalysatoren aus Aluminiumoxid mit unterschiedlicher thermischer Vorbehandlung und daher mit unterschiedlichem Gehalt an freien Hydroxylgruppen auf der Oberfläche haben unterschiedliche Desaktivierungsgeschwindigkeit.
    Additional Material: 3 Ill.
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