ISSN:
0749-1581
Keywords:
Chemistry
;
Analytical Chemistry and Spectroscopy
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
2-Dimethoxyphosphoryl-1,3-dithiane was obtained by the reaction of 2-chloro-1,3-dithiane with trimethyl phosphite. Studies at 200, 360 and 400 MHz using 1H, 13C and 31P nuclei and 1D- and 2D NMR techniques are described. Long-range coupling constants were extracted by iterative treatment of [AB]2CDMR6X spin systems. A rigid dithiane structure with axial phosphorus is consistent with the NMR results. Analogous dithianes and solid-state structures are discussed.
Additional Material:
2 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/mrc.1260230108
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